Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

Thionyl fluoride


Vibrational and/or electronic energy levels

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Takehiko Shimanouchi

Symmetry:   Cs     Symmetry Number sigma = 1


 Sym.   No   Approximate   Selected Freq.  Infrared   Raman   Comments 
 Species   type of mode   Value   Rating   Value  Phase  Value  Phase

a' 1 SO str 1333  D 1340.8 S gas 1339.3 VS gas
a' 1 SO str 1333  D 1330.9 S gas 1329.9 VS gas FR(«nu»2+«nu»3)
a' 2 SF2 s-str 808  B 808.2 VS gas 808.3 VS gas
a' 3 OSF deform 530  B 530.4 M gas 529.6 S gas
a' 4 SF2 scis 378  D 377.8 W gas 379.5 W liq.
a 5 SF2 a-str 747  C 747.0 VS gas 746.8 W gas
a 6 OSF deform 393  D 392.5 W gas 398.6 M liq.

Source: Shimanouchi, 1972

Notes

VSVery strong
SStrong
MMedium
WWeak
FRFermi resonance with an overtone or a combination tone indicated in the parentheses.
B1~3 cm-1 uncertainty
C3~6 cm-1 uncertainty
D6~15 cm-1 uncertainty

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Shimanouchi, 1972
Shimanouchi, T., Tables of Molecular Vibrational Frequencies Consolidated Volume II, J. Phys. Chem. Ref. Data, 1972, 6, 3, 993-1102. [all data]


Notes

Go To: Top, Vibrational and/or electronic energy levels, References