molybdic acid


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Δfgas-203.40kcal/molReviewChase, 1998Data last reviewed in June, 1970
Quantity Value Units Method Reference Comment
gas,1 bar84.993cal/mol*KReviewChase, 1998Data last reviewed in June, 1970

Gas Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 298. to 1200.1200. to 6000.
A 19.7984035.13210
B 30.989101.337631
C -23.83300-0.253240
D 6.9744200.016691
E -0.197441-2.676501
F -211.1470-220.2400
G 99.59931118.5540
H -203.4000-203.4000
ReferenceChase, 1998Chase, 1998
Comment Data last reviewed in June, 1970 Data last reviewed in June, 1970

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

HMoO4- + Hydrogen cation = molybdic acid

By formula: HMoO4- + H+ = H2MoO4

Quantity Value Units Method Reference Comment
Δr325.6 ± 9.6kcal/molTDEqMiller, 1979gas phase; e- + H2MoO4 <=> HMoO4- + H

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

De-protonation reactions

HMoO4- + Hydrogen cation = molybdic acid

By formula: HMoO4- + H+ = H2MoO4

Quantity Value Units Method Reference Comment
Δr325.6 ± 9.6kcal/molTDEqMiller, 1979gas phase; e- + H2MoO4 <=> HMoO4- + H

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Miller, 1979
Miller, W.J., The use of flames as media for the study of in-molecule thermochemistry in characterization of high temperature vapors and gases, NBS Spec. Publ. U.S., 1979, 561, 443. [all data]


Notes

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