selenium

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director

Quantity Value Units Method Reference Comment
Tc1766.KN/ARau, 1974Uncertainty assigned by TRC = 1.76 K; TRC
Quantity Value Units Method Reference Comment
Pc271.551barN/ARau, 1974Uncertainty assigned by TRC = 2.7133 bar; TRC
Quantity Value Units Method Reference Comment
ρc15.64mol/lN/ARau, 1974Uncertainty assigned by TRC = 0.0156 mol/l; TRC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
629. to 953.6.337146588.12586.633Stull, 1947Coefficents calculated by NIST from author's data.

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

(CAS Reg. No. 16661-43-1 • 4294967295selenium) + selenium = CAS Reg. No. 16661-43-1

By formula: (CAS Reg. No. 16661-43-1 • 4294967295Se) + Se = CAS Reg. No. 16661-43-1

Quantity Value Units Method Reference Comment
Δr445.7 ± 3.6kJ/molN/AStoneman and Larson, 1986gas phase; Wagman, Evans, et al., 1982 ΔHf(AH) = 7.1 kcal/mol

(CAS Reg. No. 101021-48-1 • 4294967295selenium) + selenium = CAS Reg. No. 101021-48-1

By formula: (CAS Reg. No. 101021-48-1 • 4294967295Se) + Se = CAS Reg. No. 101021-48-1

Quantity Value Units Method Reference Comment
Δr468. ± 21.kJ/molN/ACoe, Snodgrass, et al., 1986gas phase

(Se2- • 4294967295selenium) + selenium = Se2-

By formula: (Se2- • 4294967295Se) + Se = Se2-

Quantity Value Units Method Reference Comment
Δr300. ± 13.kJ/molN/ASnodgrass, Coe, et al., 1989gas phase

References

Go To: Top, Phase change data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Rau, 1974
Rau, H., Vapour composition and critical constants of selenium, J. Chem. Thermodyn., 1974, 6, 525. [all data]

Stull, 1947
Stull, Daniel R., Vapor Pressure of Pure Substances. Organic and Inorganic Compounds, Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022 . [all data]

Stoneman and Larson, 1986
Stoneman, R.C.; Larson, D.J., Photodetachment spectroscopy of SeH- in a magnetic field, J. Phys. B:, 1986, 19, 405. [all data]

Wagman, Evans, et al., 1982
Wagman, D.D.; Evans, W.H.; Parker, V.B.; Schumm, R.H.; Halow, I.; Bailey, S.M.; Churney, K.L.; Nuttall, R.L., The NBS Tables of Chemical Thermodynamic Properties (NBS Tech Note 270), J. Phys. Chem. Ref. Data, Supl. 1, 1982, 11. [all data]

Coe, Snodgrass, et al., 1986
Coe, J.V.; Snodgrass, J.T.; Freidhoff, C.B.; McHugh, K.M.; Bowen, K.H., Photoelectron spectroscopy of the negative ion SeO-, J. Chem. Phys., 1986, 84, 618. [all data]

Snodgrass, Coe, et al., 1989
Snodgrass, J.T.; Coe, J.V.; McHugh, K.M.; Freidhoff, C.B.; Bowen, K.H., Photoelectron Spectroscopy of the Selenium and Tellurium Containing Negative Ions: SeO2-, Se2- and Te2-, J. Phys. Chem., 1989, 93, 4, 1249, https://doi.org/10.1021/j100341a016 . [all data]


Notes

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