sodium sulphate

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Δfliquid-324.183kcal/molReviewChase, 1998Data last reviewed in June, 1978
Quantity Value Units Method Reference Comment
liquid,1 bar43.303cal/mol*KReviewChase, 1998Data last reviewed in June, 1978
Quantity Value Units Method Reference Comment
Δfsolid-331.635kcal/molReviewChase, 1998v phase; Data last reviewed in June, 1978

Liquid Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 1157. to 3000.
A 47.09202
B -0.000007
C 0.000003
D -3.091635×10-7
E -0.000001
F -341.1233
G 94.06812
H -324.1826
ReferenceChase, 1998
Comment Data last reviewed in June, 1978

Solid Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 298. to 1000.298. to 1000.298. to 1157.298. to 1157.298. to 1000.
A 23.1775012.5093036.8395160.4544923.20690
B 35.7422144.184802.927740-73.8726135.62801
C -10.6385030.9422111.8052091.07541-10.48730
D 3.404190-14.35510-3.686791-27.202203.338220
E -0.2091060.252248-0.045462-0.763126-0.209731
F -340.7500-336.0791-341.4070-347.7211-340.8191
G 52.5403039.1680981.23260126.064052.46599
H -331.6350-330.9881-330.0430-329.6589-331.6960
ReferenceChase, 1998Chase, 1998Chase, 1998Chase, 1998Chase, 1998
Comment v phase; Data last reviewed in June, 1978 iii phase; Data last reviewed in June, 1978 i phase; Data last reviewed in June, 1978 δ phase; Data last reviewed in June, 1978 iv phase; Data last reviewed in June, 1978

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (atm)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
1073. to 1223.1.927637517.522-375.044Fryxell, Trythall, et al., 1973Coefficents calculated by NIST from author's data.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Fryxell, Trythall, et al., 1973
Fryxell, R.E.; Trythall, C.A.; Perkins, R.J., Vapor Pressure of Liquid Sodium Sulfate from 954 to 1204 C, Corros. Abstr., 1973, 29, 11, 423-428, https://doi.org/10.5006/0010-9312-29.11.423 . [all data]


Notes

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