sodium sulphate

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Δfliquid-1356.38kJ/molReviewChase, 1998Data last reviewed in June, 1978
Quantity Value Units Method Reference Comment
liquid,1 bar181.18J/mol*KReviewChase, 1998Data last reviewed in June, 1978
Quantity Value Units Method Reference Comment
Δfsolid-1387.56kJ/molReviewChase, 1998v phase; Data last reviewed in June, 1978

Liquid Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 1157. to 3000.
A 197.0330
B -0.000028
C 0.000011
D -0.000001
E -0.000006
F -1427.260
G 393.5810
H -1356.380
ReferenceChase, 1998
Comment Data last reviewed in June, 1978

Solid Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 298. to 1000.298. to 1000.298. to 1157.298. to 1157.298. to 1000.
A 96.9746652.33891154.1365252.941697.09767
B 149.5454184.869212.24966-309.0830149.0676
C -44.51148129.462249.39296381.0595-43.87886
D 14.24313-60.06174-15.42553-113.814013.96711
E -0.8749001.055407-0.190212-3.192919-0.877515
F -1425.698-1406.155-1428.447-1454.865-1425.987
G 219.8286163.8793339.8772527.4518219.5177
H -1387.561-1384.854-1380.900-1379.293-1387.816
ReferenceChase, 1998Chase, 1998Chase, 1998Chase, 1998Chase, 1998
Comment v phase; Data last reviewed in June, 1978 iii phase; Data last reviewed in June, 1978 i phase; Data last reviewed in June, 1978 δ phase; Data last reviewed in June, 1978 iv phase; Data last reviewed in June, 1978

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
1073. to 1223.1.933347517.522-375.044Fryxell, Trythall, et al., 1973Coefficents calculated by NIST from author's data.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Fryxell, Trythall, et al., 1973
Fryxell, R.E.; Trythall, C.A.; Perkins, R.J., Vapor Pressure of Liquid Sodium Sulfate from 954 to 1204 C, Corros. Abstr., 1973, 29, 11, 423-428, https://doi.org/10.5006/0010-9312-29.11.423 . [all data]


Notes

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