titanium tetraiodide
- Formula: I4Ti
- Molecular weight: 555.485
- CAS Registry Number: 7720-83-4
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Condensed phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°liquid | -83.248 | kcal/mol | Review | Chase, 1998 | Data last reviewed in December, 1968 |
| Quantity | Value | Units | Method | Reference | Comment |
| S°liquid,1 bar | 74.532 | cal/mol*K | Review | Chase, 1998 | Data last reviewed in December, 1968 |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔfH°solid | -89.799 | kcal/mol | Review | Chase, 1998 | Data last reviewed in December, 1968 |
| Quantity | Value | Units | Method | Reference | Comment |
| S°solid | 58.831 | cal/mol*K | Review | Chase, 1998 | Data last reviewed in December, 1968 |
Liquid Phase Heat Capacity (Shomate Equation)
Cp° = A + B*t + C*t2 + D*t3 +
E/t2
H° − H°298.15= A*t + B*t2/2 +
C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 −
E/(2*t2) + G
Cp = heat capacity (cal/mol*K)
H° = standard enthalpy (kcal/mol)
S° = standard entropy (cal/mol*K)
t = temperature (K) / 1000.
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| Temperature (K) | 428. to 1500. |
|---|---|
| A | 37.40010 |
| B | -6.847469×10-10 |
| C | 7.483631×10-10 |
| D | -2.582959×10-10 |
| E | -5.192840×10-12 |
| F | -94.40000 |
| G | 119.7920 |
| H | -83.24909 |
| Reference | Chase, 1998 |
| Comment | Data last reviewed in December, 1968 |
Solid Phase Heat Capacity (Shomate Equation)
Cp° = A + B*t + C*t2 + D*t3 +
E/t2
H° − H°298.15= A*t + B*t2/2 +
C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 −
E/(2*t2) + G
Cp = heat capacity (cal/mol*K)
H° = standard enthalpy (kcal/mol)
S° = standard entropy (cal/mol*K)
t = temperature (K) / 1000.
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| Temperature (K) | 298. to 379. | 379. to 428. |
|---|---|---|
| A | 17.40490 | 35.40010 |
| B | 41.91281 | -3.318201×10-12 |
| C | 0.000000 | 0.000000 |
| D | 0.000000 | 0.000000 |
| E | 0.011098 | -7.673860×10-13 |
| F | -96.81489 | -98.28411 |
| G | 67.46049 | 107.0200 |
| H | -89.80000 | -89.80000 |
| Reference | Chase, 1998 | Chase, 1998 |
| Comment | Data last reviewed in December, 1968 | Data last reviewed in December, 1968 |
Phase change data
Go To: Top, Condensed phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: William E. Acree, Jr., James S. Chickos
Enthalpy of vaporization
| ΔvapH (kcal/mol) | Temperature (K) | Reference | Comment |
|---|---|---|---|
| 14.0 | 538. | Blocher and Campbell, 1947 | Based on data from 433. to 643. K. |
References
Go To: Top, Condensed phase thermochemistry data, Phase change data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Chase, 1998
Chase, M.W., Jr.,
NIST-JANAF Themochemical Tables, Fourth Edition,
J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]
Blocher and Campbell, 1947
Blocher, John M.; Campbell, Ivor E.,
The Vapor Pressure of Liquid Titanium Tetraiodide,
J. Am. Chem. Soc., 1947, 69, 9, 2100-2101, https://doi.org/10.1021/ja01201a006
. [all data]
Notes
Go To: Top, Condensed phase thermochemistry data, Phase change data, References
- Symbols used in this document:
S°liquid,1 bar Entropy of liquid at standard conditions (1 bar) S°solid Entropy of solid at standard conditions ΔfH°liquid Enthalpy of formation of liquid at standard conditions ΔfH°solid Enthalpy of formation of solid at standard conditions ΔvapH Enthalpy of vaporization - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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