Hydrochloric acid-d

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Δfgas-22.31kcal/molReviewChase, 1998Data last reviewed in June, 1977
Quantity Value Units Method Reference Comment
gas,1 bar46.066cal/mol*KReviewChase, 1998Data last reviewed in June, 1977

Gas Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 298. to 1300.1300. to 6000.
A 6.0644708.513970
B 1.6396910.307687
C 0.896536-0.041890
D -0.6340160.002762
E 0.031941-0.863706
F -24.09039-26.60631
G 53.0626054.21260
H -22.31000-22.31000
ReferenceChase, 1998Chase, 1998
Comment Data last reviewed in June, 1977 Data last reviewed in June, 1977

Phase change data

Go To: Top, Gas phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director

Quantity Value Units Method Reference Comment
Ptriple0.12346atmN/AHenderson, Lewis, et al., 1986Uncertainty assigned by TRC = 0.00007 atm
Ptriple0.12366atmN/AHenderson, Lewis, et al., 1986Uncertainty assigned by TRC = 0.00007 atm
Ptriple0.12356atmN/AHenderson, Lewis, et al., 1986Uncertainty assigned by TRC = 0.00005 atm; estimated for pure DCl, based on amount of H in samples
Quantity Value Units Method Reference Comment
Tc323.5KN/AHenderson, Lewis, et al., 1986Uncertainty assigned by TRC = 0.32 K
Quantity Value Units Method Reference Comment
Pc79.15atmN/AHenderson, Lewis, et al., 1986Uncertainty assigned by TRC = 0.0791 atm; Vapor Pressure measured up to 226 K and Pc determined from fitted Wagner equation

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References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Henderson, Lewis, et al., 1986
Henderson, C.; Lewis, D.G.; Prichard, P.C.; Staveley, L.A.K.; Fonseca, I.M.A.; Lobo, L.Q., Some thermodynamic properties of hydrogen chloride and deuterium chloride, J. Chem. Thermodyn., 1986, 18, 1077. [all data]


Notes

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