Nitric acid

• Formula: HNO₃
• Molecular weight: 63.0128
• IUPAC Standard InChI: InChI=1S/HNO3/c2-1(3)4/h(H,2,3,4) Copy

  
• IUPAC Standard InChIKey: GRYLNZFGIOXLOG-UHFFFAOYSA-N Copy
• CAS Registry Number: 7697-37-2
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
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• Information on this page:
  • Gas phase thermochemistry data
  • Phase change data
  • Reaction thermochemistry data
  • Henry's Law data
  • References
  • Notes
• Other data available:
  • Gas phase ion energetics data
  • Ion clustering data
  • IR Spectrum
  • Vibrational and/or electronic energy levels
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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Gas Phase Heat Capacity (Shomate Equation)

C_p° = A + B*t + C*t² + D*t³ + E/t²
H° − H°_298.15= A*t + B*t²/2 + C*t³/3 + D*t⁴/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t²/2 + D*t³/3 − E/(2*t²) + G
    C_p = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Enthalpy of vaporization

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

( • ) +  = ( • 2)

By formula: (NO₃^- • HNO₃) + HNO₃ = (NO₃^- • 2HNO₃)

Free energy of reaction

( • 2) +  = ( • 3)

By formula: (NO₃^- • 2HNO₃) + HNO₃ = (NO₃^- • 3HNO₃)

Free energy of reaction

 +  =

By formula: NO₃^- + H⁺ = HNO₃

( • ) +  = ( • 2)

By formula: (Br^- • HNO₃) + HNO₃ = (Br^- • 2HNO₃)

 +  = ( • )

By formula: Br^- + HNO₃ = (Br^- • HNO₃)

Free energy of reaction

( • ) +  = ( •  • )

By formula: (NO₃^- • HNO₃) + H₂O = (NO₃^- • H₂O • HNO₃)

Free energy of reaction

(HO₄S^- • 2) +  = (HO₄S^- •  • 2)

By formula: (HO₄S^- • 2H₂O₄S) + HNO₃ = (HO₄S^- • HNO₃ • 2H₂O₄S)

Free energy of reaction

(HO₄S^- • 3) +  = (HO₄S^- •  • 3)

By formula: (HO₄S^- • 3H₂O₄S) + HNO₃ = (HO₄S^- • HNO₃ • 3H₂O₄S)

Free energy of reaction

(HO₄S^- • ) + HO₃S = (HO₄S^- • HO₃S • )

By formula: (HO₄S^- • HNO₃) + HO₃S = (HO₄S^- • HO₃S • HNO₃)

Free energy of reaction

(HO₄S^- • ) +  = (HO₄S^- •  • )

By formula: (HO₄S^- • HNO₃) + H₂O = (HO₄S^- • H₂O • HNO₃)

Free energy of reaction

(HO₄S^- • ) +  = (HO₄S^- • 2)

By formula: (HO₄S^- • HNO₃) + HNO₃ = (HO₄S^- • 2HNO₃)

Free energy of reaction

( • 3) +  = ( • 4)

By formula: (NO₃^- • 3HNO₃) + HNO₃ = (NO₃^- • 4HNO₃)

( • ) +  = ( •  • )

By formula: (NO₃^- • HNO₃) + HBr = (NO₃^- • HBr • HNO₃)

( • 5) +  = ( • 6)

By formula: (NO₃^- • 5HNO₃) + HNO₃ = (NO₃^- • 6HNO₃)

( • 4) +  = ( • 5)

By formula: (NO₃^- • 4HNO₃) + HNO₃ = (NO₃^- • 5HNO₃)

( • ) +  = ( •  • )

By formula: (NO₃^- • HBr) + HNO₃ = (NO₃^- • HNO₃ • HBr)

 +  =  + 

By formula: C₃H₆N₂O₇ + HNO₃ = C₃H₅N₃O₉ + H₂O

 +  =  + 

By formula: C₃H₈O₃ + HNO₃ = C₃H₇NO₅ + H₂O

 +  = ( • )

By formula: NO₃^- + HNO₃ = (NO₃^- • HNO₃)

 +  = ( • )

By formula: Na⁺ + HNO₃ = (Na⁺ • HNO₃)

 +  =  + 

By formula: C₃H₇NO₅ + HNO₃ = C₃H₆N₂O₇ + H₂O

 +  =  + 

By formula: C₃H₈O₃ + HNO₃ = C₃H₇NO₅ + H₂O

 +  =  + 

By formula: C₃H₆N₂O₇ + H₂O = C₃H₇NO₅ + HNO₃

 +  =  + 

By formula: C₃H₆N₂O₇ + HNO₃ = C₃H₅N₃O₉ + H₂O

 + 2 =  + 2

By formula: C₃H₇NO₅ + 2HNO₃ = C₃H₅N₃O₉ + 2H₂O

 + 3 =  + 3

By formula: C₃H₈O₃ + 3HNO₃ = C₃H₅N₃O₉ + 3H₂O

 +  =  + 

By formula: C₄H₁₀O₃ + HNO₃ = C₄H₉NO₅ + H₂O

 +  = 2 + 

By formula: CH₃NO₂ + HNO₃ = 2NO₂ + CH₄O

 +  = C₂F₃NO₄ + 

By formula: C₄F₆O₃ + HNO₃ = C₂F₃NO₄ + C₂HF₃O₂

 +  = C₅H₁₁NO₆ + 

By formula: C₅H₁₂O₄ + HNO₃ = C₅H₁₁NO₆ + H₂O

 +  =  + 

By formula: C₂H₆O₂ + HNO₃ = C₂H₅NO₄ + H₂O

 +  =  + 

By formula: C₄H₁₀O₃ + HNO₃ = C₄H₉NO₅ + H₂O

 +  =  + 

By formula: C₂H₃NO₄ + C₂H₄O₂ = C₄H₆O₃ + HNO₃

 +  =  + 

By formula: C₃H₈O + HNO₃ = C₃H₇NO₃ + H₂O

 +  =  + 

By formula: CH₄O + HNO₃ = CH₃NO₃ + H₂O

 +  =  + 

By formula: C₂H₆O + HNO₃ = C₂H₅NO₃ + H₂O

 +  =  + 

By formula: C₃H₈O + HNO₃ = C₃H₇NO₃ + H₂O

Henry's Law data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Rolf Sander

Henry's Law constant (water solution)

k_H(T) = k°_H exp(d(ln(k_H))/d(1/T) ((1/T) - 1/(298.15 K)))
k°_H = Henry's law constant for solubility in water at 298.15 K (mol/(kg*bar))
d(ln(k_H))/d(1/T) = Temperature dependence constant (K)

References

Go To: Top, Gas phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Holeci, 1966
Holeci, I., Chem. Prum., 1966, 16, 5, 267. [all data]

Davidson, Fehsenfeld, et al., 1977
Davidson, J.A.; Fehsenfeld, F.C.; Howard, C.J., The heats of formation of NO₃- and NO₃- association complexes with HNO₃ and HBr, Int. J. Chem. Kinet., 1977, 9, 17. [all data]

Wlodek, Luczynski, et al., 1980
Wlodek, S.; Luczynski, Z.; Wincel, H., Stabilities of gas-phase NO₃-.(HNO₃)n,n ≤ 6, clusters, Int. J. Mass Spectrom. Ion Phys., 1980, 35, 39. [all data]

Arnold, Viggiano, et al., 1982
Arnold, F.; Viggiano, A.A.; Schlager, H., Implications for Trace Gases and Aerosols of Large Negative Ions Clusters in the Stratosphere, Nature, 1982, 297, 5865, 371, https://doi.org/10.1038/297371a0 . [all data]

Lee, Keesee, et al., 1980
Lee, N.; Keesee, R.G.; Castleman, A.W., Jr., The properties of clusters in the gas phase. IV. Complexes of H₂O and HNO_x clustering on NO_x-, J. Chem. Phys., 1980, 72, 1089. [all data]

Arnold and Qiu, 1984
Arnold, F.; Qiu, S., Upper Stratosphere Negative Ion Composition Measurements and Infrared Trace Gas Abundances, Planet. Space Sci., 1984, 32, 2, 169, https://doi.org/10.1016/0032-0633(84)90151-X . [all data]

Fehsenfeld, Howard, et al., 1975
Fehsenfeld, F.C.; Howard, C.J.; Schmeltkopf, A.L., Gas Phase Ion Chemistry of HNO3, J. Chem. Phys., 1975, 63, 7, 2835, https://doi.org/10.1063/1.431722 . [all data]

Mathur, Rothe, et al., 1976
Mathur, B.P.; Rothe, E.W.; Tang, S.Y.; Mahajan, K.; Reck, G.P., Negative gaseous ions from nitric acid, J. Chem. Phys., 1976, 64, 1247. [all data]

Refaey and Franklin, 1976
Refaey, K.M.A.; Franklin, J.L., Endoergic ion-molecule-collision processes of negative ions. V. Collision of I- on HNO₃. The electron affinity of NO₃, J. Chem. Phys., 1976, 64, 4810. [all data]

Ferguson, Dunkin, et al., 1972
Ferguson, E.E.; Dunkin, D.B.; Fehsenfeld, F.C., Reactions of NO₂^- and NO₃^- with HCl and HBr, J. Chem. Phys., 1972, 57, 1459. [all data]

Berkowitz, Chupka, et al., 1971
Berkowitz, J.; Chupka, W.A.; Gutman, D., Electron Affinities of O₂, O₃, NO, NO₂, and NO₃ by Endothermic Charge Transfer, J. Chem. Phys., 1971, 55, 6, 2733, https://doi.org/10.1063/1.1676488 . [all data]

Kazakov, Kirpichev, et al., 1990
Kazakov, A.I.; Kirpichev, E.P.; Lagodzinskaya, G.V.; Andrienko, L.P.; Yunda, N.G.; Korolev, A.M.; Rubstov, Yu.I.; Manelis, G.B.; Eremenko, L.T., Study of nitration equilibrium in the glycerin-aqueous nitric acid system. 2. Changes in ΔH and ΔS in the nitration reaction, Bull. Acad. Sci. USSR, Div. Chem. Sci., 1990, 1565-1570. [all data]

Kazakov, Lagodzinskaya, et al., 1989
Kazakov, A.I.; Lagodzinskaya, E.P.; Kirpichev, E.P.; Andrienko, L.P.; Yunda, N.G.; Korolev, A.M.; Robtsov, Yu.I.; Manelis, G.V.; Eremenko, L.T., Thermodynamics of nitration of glycerol, Dokl. Phys. Chem. (Engl. Transl.), 1989, 305, 287-291. [all data]

Tsvetkov, Sopin, et al., 1986
Tsvetkov, V.G.; Sopin, V.P.; Tsvetkova, L.Ya.; Marchenko, G.N., Enthalpy of reaction of nitric acid with some organic compounds, J. Gen. Chem. USSR, 1986, 56, 471-474. [all data]

Perry, Rowe, et al., 1980
Perry, R.A.; Rowe, B.R.; Viggiano, A.A.; Albritton, D.L.; Ferguson, E.E.; Fehsenfeld, F.C., Laboratory Measurements of Stratospheric Sodium Ion Measurements, Geophys. Res. Lett., 1980, 7, 9, 693, https://doi.org/10.1029/GL007i009p00693 . [all data]

Silverwood and Thomas, 1967
Silverwood, R.; Thomas, J.H., Reaction between methanol and nitrogen dioxide. Part 1.-Low-temperature reaction and the thermodynamic constants of methyl nitrite, J. Chem. Soc. Faraday Trans., 1967, 63, 2476-2479. [all data]

Tsvetkov, Shmakov, et al., 1989
Tsvetkov, V.G.; Shmakov, V.A.; Sopin, V.F.; Ivanov, A.V.; Ikonnikov, A.A.; Marchenko, G.N., Enthalpies of reaction of nitric acid with acetic and trifluoroacetic anhydrides, J. Gen. Chem. USSR, 1989, 59, 1220-1222. [all data]

Rubtsov, 1986
Rubtsov, Yu.I., Thermodynamic calculation of equilibrium in nitration of alcohols, Bull. Acad. Sci. USSR, Div. Chem. Sci., 1986, 19-22. [all data]

Notes

Go To: Top, Gas phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, References

• Symbols used in this document:
  

  S°gas,1 bar	Entropy of gas at standard conditions (1 bar)
  T	Temperature
  d(ln(kH))/d(1/T)	Temperature dependence parameter for Henry's Law constant
  k°H	Henry's Law constant at 298.15K
  ΔfH°gas	Enthalpy of formation of gas at standard conditions
  ΔrG°	Free energy of reaction at standard conditions
  ΔrH°	Enthalpy of reaction at standard conditions
  ΔrS°	Entropy of reaction at standard conditions
  ΔvapH	Enthalpy of vaporization

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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