magnesium dihydride


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

HMg- + Hydrogen cation = magnesium dihydride

By formula: HMg- + H+ = H2Mg

Quantity Value Units Method Reference Comment
Δr359.3 ± 2.4kcal/molD-EARackwitz, Feldman, et al., 1977gas phase; Caln: ΔHacid=363.8 Hinde, 2000

Gas phase ion energetics data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

De-protonation reactions

HMg- + Hydrogen cation = magnesium dihydride

By formula: HMg- + H+ = H2Mg

Quantity Value Units Method Reference Comment
Δr359.3 ± 2.4kcal/molD-EARackwitz, Feldman, et al., 1977gas phase; Caln: ΔHacid=363.8 Hinde, 2000

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Rackwitz, Feldman, et al., 1977
Rackwitz, R.; Feldman, D.; Kaiser, H.J.; Heincke, E., Photodetachment bei einigen zweiatomigen negativen hydridionen: BeH-, MgH-, CaH-, ZnH-, PH-, AsH-, Z. Naturforsch. A:, 1977, 32, 594. [all data]

Hinde, 2000
Hinde, R.J., Ab initio gas-phase acidities of NaH, MgH2, and AlH3, J. Phys. Chem. A, 2000, 104, 32, 7580-7585, https://doi.org/10.1021/jp994138j . [all data]


Notes

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