sodium fluoride
- Formula: FNa
- Molecular weight: 41.9881725
- IUPAC Standard InChI: InChI=1S/FH.Na/h1H;/q;+1/p-1
- IUPAC Standard InChIKey: PUZPDOWCWNUUKD-UHFFFAOYSA-M
- CAS Registry Number: 7681-49-4
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
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Gas phase thermochemistry data
Go To: Top, Condensed phase thermochemistry data, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°gas | -69.419 | kcal/mol | Review | Chase, 1998 | Data last reviewed in December, 1968 |
| Quantity | Value | Units | Method | Reference | Comment |
| S°gas,1 bar | 52.005 | cal/mol*K | Review | Chase, 1998 | Data last reviewed in December, 1968 |
Gas Phase Heat Capacity (Shomate Equation)
Cp° = A + B*t + C*t2 + D*t3 +
E/t2
H° − H°298.15= A*t + B*t2/2 +
C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 −
E/(2*t2) + G
Cp = heat capacity (cal/mol*K)
H° = standard enthalpy (kcal/mol)
S° = standard entropy (cal/mol*K)
t = temperature (K) / 1000.
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| Temperature (K) | 3500. to 6000. |
|---|---|
| A | 8.832601 |
| B | 0.256658 |
| C | -0.025239 |
| D | 0.002151 |
| E | -0.066425 |
| F | -72.28740 |
| G | 62.24589 |
| H | -69.42001 |
| Reference | Chase, 1998 |
| Comment | Data last reviewed in December, 1968 |
Condensed phase thermochemistry data
Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°liquid | -130.54 | kcal/mol | Review | Chase, 1998 | Data last reviewed in December, 1968 |
| Quantity | Value | Units | Method | Reference | Comment |
| S°liquid,1 bar | 17.56 | cal/mol*K | Review | Chase, 1998 | Data last reviewed in December, 1968 |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔfH°solid | -137.52 | kcal/mol | Review | Chase, 1998 | Data last reviewed in December, 1968 |
| Quantity | Value | Units | Method | Reference | Comment |
| S°solid | 12.24 | cal/mol*K | Review | Chase, 1998 | Data last reviewed in December, 1968 |
Liquid Phase Heat Capacity (Shomate Equation)
Cp° = A + B*t + C*t2 + D*t3 +
E/t2
H° − H°298.15= A*t + B*t2/2 +
C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 −
E/(2*t2) + G
Cp = heat capacity (cal/mol*K)
H° = standard enthalpy (kcal/mol)
S° = standard entropy (cal/mol*K)
t = temperature (K) / 1000.
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| Temperature (K) | 1269. to 3500. |
|---|---|
| A | 15.87799 |
| B | -0.542658 |
| C | 0.167616 |
| D | -0.017733 |
| E | 2.159434 |
| F | -134.6692 |
| G | 34.66468 |
| H | -130.5459 |
| Reference | Chase, 1998 |
| Comment | Data last reviewed in December, 1968 |
Solid Phase Heat Capacity (Shomate Equation)
Cp° = A + B*t + C*t2 + D*t3 +
E/t2
H° − H°298.15= A*t + B*t2/2 +
C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 −
E/(2*t2) + G
Cp = heat capacity (cal/mol*K)
H° = standard enthalpy (kcal/mol)
S° = standard entropy (cal/mol*K)
t = temperature (K) / 1000.
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| Temperature (K) | 298. to 1269. |
|---|---|
| A | 12.66783 |
| B | -1.422598 |
| C | 3.002749 |
| D | 0.090398 |
| E | -0.116901 |
| F | -141.6525 |
| G | 27.20220 |
| H | -137.5201 |
| Reference | Chase, 1998 |
| Comment | Data last reviewed in December, 1968 |
Reaction thermochemistry data
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
4 +
= 2
+
+ 3
By formula: 4Na + C2ClF3 = 2C + ClNa + 3FNa
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | -376.7 ± 1.3 | kcal/mol | Cm | Kolesov, Zenkov, et al., 1963 | gas phase; Reanalyzed by Cox and Pilcher, 1970, Original value = -368.8 ± 1.3 kcal/mol; ALS |
2 +
=
+
+
By formula: 2HNaO + C2H3FO = C2H3NaO2 + FNa + H2O
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | -13.42 ± 0.02 | kcal/mol | Cm | Pritchard and Skinner, 1950 | liquid phase; Corrected for CODATA value of ΔfH; HF(100); ALS |
| ΔrH° | -42.4 | kcal/mol | Cm | Carson and Skinner, 1949 | liquid phase; ALS |
By formula: Be2F5- + FNa = (Be2F5- • FNa)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 65.2 ± 2.5 | kcal/mol | N/A | Nikitin, Sorokin, et al., 1980 | gas phase; value altered from reference due to conversion from electron convention to ion convention; B |
+ 4
= 4
+ 8
By formula: C4F8 + 4Na = 4C + 8FNa
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | -714.5 ± 2.2 | kcal/mol | Ccb | Kolesov, Talakin, et al., 1968 | gas phase; Correction of Kolesov, Talakin, et al., 1964; ALS |
By formula: (F2Sc+ • 2FNa) + FNa = (F2Sc+ • 3FNa)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 72. | kcal/mol | MS | Tsirlina, Gusarov, et al., 1986 | gas phase; Knudsen cell; M |
By formula: (F2Sc+ • 3FNa) + FNa = (F2Sc+ • 4FNa)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 67. | kcal/mol | MS | Tsirlina, Gusarov, et al., 1986 | gas phase; Knudsen cell; M |
( •
) +
= (
• 2
)
By formula: (Na+ • FNa) + FNa = (Na+ • 2FNa)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 47. | kcal/mol | MS | Tsirlina, Gusarov, et al., 1986 | gas phase; Knudsen cell; M |
By formula: (F2Sc+ • FNa) + FNa = (F2Sc+ • 2FNa)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 83. | kcal/mol | MS | Tsirlina, Gusarov, et al., 1986 | gas phase; Knudsen cell; M |
+
= (
•
)
By formula: Na+ + FNa = (Na+ • FNa)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 62.7 | kcal/mol | MS | Tsirlina, Gusarov, et al., 1986 | gas phase; Knudsen cell; M |
4 +
=
+ 4
By formula: 4Na + CF4 = C + 4FNa
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | -325.5 ± 2.2 | kcal/mol | Ccb | Vorob'ev and Skuratov, 1960 | gas phase; ALS |
+ 4
= 4
+ 2
By formula: C2F4 + 4Na = 4FNa + 2C
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | -385.0 ± 1.1 | kcal/mol | Cm | Kolesov, Zenkov, et al., 1962 | gas phase; ALS |
8 +
= 3
+ 8
By formula: 8Na + C3F8 = 3C + 8FNa
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | -660.0 ± 1.7 | kcal/mol | Ccb | Kolesov, Talakin, et al., 1967 | gas phase; ALS |
References
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Chase, 1998
Chase, M.W., Jr.,
NIST-JANAF Themochemical Tables, Fourth Edition,
J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]
Kolesov, Zenkov, et al., 1963
Kolesov, V.P.; Zenkov, I.D.; Skuratov, S.M.,
Standard enthalpy of formation of chlorotrifluoroethylene,
Russ. J. Phys. Chem. (Engl. Transl.), 1963, 37, 115-116. [all data]
Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G.,
Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]
Pritchard and Skinner, 1950
Pritchard, H.O.; Skinner, H.A.,
The heat of hydrolysis of acetyl fluoride,
J. Chem. Soc., 1950, 1099. [all data]
Carson and Skinner, 1949
Carson, A.S.; Skinner, H.A.,
201. Carbon-halogen bond energies in the acetyl halides,
J. Chem. Soc., 1949, 936-939. [all data]
Nikitin, Sorokin, et al., 1980
Nikitin, M.I.; Sorokin, I.D.; Skokan, E.V.; Sidorov, L.N.,
Negative Ions in the Saturated Vapors of the Potassium Fluoride - Hafnium Tetrafluoride and Potassium Fluoride - Beryllium Difluoride Systems,
Russ. J. Phys. Chem., 1980, 54, page]. [all data]
Kolesov, Talakin, et al., 1968
Kolesov, V.P.; Talakin, O.G.; Skuratov, S.M.,
Enthalpy of formation of some specimens of amorphous carbon,
Russ. J. Phys. Chem. (Engl. Transl.), 1968, 42, 1218-1220. [all data]
Kolesov, Talakin, et al., 1964
Kolesov, V.P.; Talakin, O.G.; Skuratov, S.M.,
Standard enthalpy of formation of perfluorocyclobutane,
Russ. J. Phys. Chem. (Engl. Transl.), 1964, 38, 930-931. [all data]
Tsirlina, Gusarov, et al., 1986
Tsirlina, E.A.; Gusarov, A.V.; Gorokhov, L.N.,
High Temp., 1986, 14, 1064. [all data]
Vorob'ev and Skuratov, 1960
Vorob'ev, A.F.; Skuratov, S.M.,
Standard enthalpies of formation of CF4,
Zh. Neorg. Khim., 1960, 5, 1398-1401. [all data]
Kolesov, Zenkov, et al., 1962
Kolesov, V.P.; Zenkov, I.D.; Skuratov, S.M.,
The standard enthalpy of formation of tetrafluoroethylene,
Russ. J. Phys. Chem. (Engl. Transl.), 1962, 36, 45-47. [all data]
Kolesov, Talakin, et al., 1967
Kolesov, V.P.; Talakin, O.G.; Skuratov, S.M.,
Standard enthalpy of formation of perfluoropropane and enthalpies of formation of normal perfluoroalkanes,
Vestn. Mosk. Univ. Khim., 1967, 22, 38-42. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, References
- Symbols used in this document:
S°gas,1 bar Entropy of gas at standard conditions (1 bar) S°liquid,1 bar Entropy of liquid at standard conditions (1 bar) S°solid Entropy of solid at standard conditions ΔfH°gas Enthalpy of formation of gas at standard conditions ΔfH°liquid Enthalpy of formation of liquid at standard conditions ΔfH°solid Enthalpy of formation of solid at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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