Sulfuric Acid
- Formula: H2O4S
- Molecular weight: 98.078
- IUPAC Standard InChIKey: QAOWNCQODCNURD-UHFFFAOYSA-N
- CAS Registry Number: 7664-93-9
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: H2SO4; Dipping acid; Hydrogen sulfate; Oil of vitriol; Sulphuric acid; Acide sulfurique; Acido solforico; BOV; Matting acid; Nordhausen acid; Schwefelsaeureloesungen; Vitriol brown oil; Vitriol, oil of; Zwavelzuuroplossingen; O2S(OH)2; Battery acid; Electrolyte acid; Spirit of alum; Spirit of vitriol; Dihydrogen sulfate; Mattling acid; UN 1830 (Salt/Mix); UN 1832 (Salt/Mix); UN 2796 (Salt/Mix)
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Ion clustering data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.
Clustering reactions
By formula: (HO4S- • H2O4S) + H2O4S = (HO4S- • 2H2O4S)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 92.0 | kJ/mol | ATM | Arnold and Qiu, 1984 | gas phase; Entropy change calculated or estimated |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 100. | J/mol*K | N/A | Arnold and Qiu, 1984 | gas phase; Entropy change calculated or estimated |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
66.1 | 250. | ATM | Arnold and Qiu, 1984 | gas phase; Entropy change calculated or estimated |
By formula: (HO4S- • 2H2O4S) + H2O4S = (HO4S- • 3H2O4S)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 87.0 | kJ/mol | ATM | Arnold and Qiu, 1984 | gas phase; Entropy change calculated or estimated |
ΔrH° | 82.8 | kJ/mol | ATM | Arnold, Viggiano, et al., 1982 | gas phase; Entropy change calculated or estimated |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 100. | J/mol*K | N/A | Arnold and Qiu, 1984 | gas phase; Entropy change calculated or estimated |
ΔrS° | 100. | J/mol*K | N/A | Arnold, Viggiano, et al., 1982 | gas phase; Entropy change calculated or estimated |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
61.1 | 250. | ATM | Arnold and Qiu, 1984 | gas phase; Entropy change calculated or estimated |
59. | 233. | ATM | Arnold, Viggiano, et al., 1982 | gas phase; Entropy change calculated or estimated |
By formula: (HO4S- • 3H2O4S) + H2O4S = (HO4S- • 4H2O4S)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 77.4 | kJ/mol | ATM | Arnold, Viggiano, et al., 1982 | gas phase; Entropy change calculated or estimated |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 100. | J/mol*K | N/A | Arnold, Viggiano, et al., 1982 | gas phase; Entropy change calculated or estimated |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
54. | 233. | ATM | Arnold, Viggiano, et al., 1982 | gas phase; Entropy change calculated or estimated |
By formula: (HO4S- • 4H2O4S) + H2O4S = (HO4S- • 5H2O4S)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 79.1 | kJ/mol | ATM | Arnold, Viggiano, et al., 1982 | gas phase; Entropy change calculated or estimated |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 100. | J/mol*K | N/A | Arnold, Viggiano, et al., 1982 | gas phase; Entropy change calculated or estimated |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
54. | 233. | ATM | Arnold, Viggiano, et al., 1982 | gas phase; Entropy change calculated or estimated |
References
Go To: Top, Ion clustering data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Arnold and Qiu, 1984
Arnold, F.; Qiu, S.,
Upper Stratosphere Negative Ion Composition Measurements and Infrared Trace Gas Abundances,
Planet. Space Sci., 1984, 32, 2, 169, https://doi.org/10.1016/0032-0633(84)90151-X
. [all data]
Arnold, Viggiano, et al., 1982
Arnold, F.; Viggiano, A.A.; Schlager, H.,
Implications for Trace Gases and Aerosols of Large Negative Ions Clusters in the Stratosphere,
Nature, 1982, 297, 5865, 371, https://doi.org/10.1038/297371a0
. [all data]
Notes
Go To: Top, Ion clustering data, References
- Symbols used in this document:
T Temperature ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions ΔrS° Entropy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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