Endo-2-methylnorbornane

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfliquid-122.1 ± 1.3kJ/molCcbKozina, 1976ALS
Quantity Value Units Method Reference Comment
Δcliquid-5026.8 ± 1.2kJ/molCcbKozina, 1976Corresponding Δfliquid = -122.1 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Quantity Value Units Method Reference Comment
liquid238.2J/mol*KN/ASeregin, Goroshko, et al., 1964DH

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
184.3298.15Seregin, Goroshko, et al., 1964T = 12 to 310 K.; DH

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing

Enthalpy of fusion

ΔfusH (kJ/mol) Temperature (K) Reference Comment
1.62278.3Domalski and Hearing, 1996AC

Enthalpy of phase transition

ΔHtrs (kJ/mol) Temperature (K) Initial Phase Final Phase Reference Comment
4.7070152.42crystaline, IIcrystaline, ISeregin, Goroshko, et al., 1964DH
1.6205278.25crystaline, IliquidSeregin, Goroshko, et al., 1964DH

Entropy of phase transition

ΔStrs (J/mol*K) Temperature (K) Initial Phase Final Phase Reference Comment
30.88152.42crystaline, IIcrystaline, ISeregin, Goroshko, et al., 1964DH
5.8278.25crystaline, IliquidSeregin, Goroshko, et al., 1964DH

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

2Hydrogen + Tricyclo[3.2.1.0(2,4)]oct-6-ene,(1α,2α,4α,5α)- = Endo-2-methylnorbornane

By formula: 2H2 + C8H10 = C8H14

Quantity Value Units Method Reference Comment
Δr-318. ± 0.8kJ/molChydRoth, Adamczak, et al., 1991liquid phase

References

Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kozina, 1976
Kozina, M.P., Enthalpies of combustion and formation of bicyclic and polycyclic hydrocarbons, Sovrem. Probl. Fiz. Khim., 1976, 9, 198-225. [all data]

Seregin, Goroshko, et al., 1964
Seregin, E.A.; Goroshko, N.N.; Kolesov, V.P.; Belikova, N.A.; Skuratov, S.M.; Plate, A.F., Low temperature heat capacity and thermodynamic functions for endo- and exo-2-methylbicyclo[2,2,1]heptane, Dokl. Akad. Nauk, 1964, SSR 159, 1381-1384. [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]

Roth, Adamczak, et al., 1991
Roth, W.R.; Adamczak, O.; Breuckmann, R.; Lennartz, H.-W.; Boese, R., Die Berechnung von Resonanzenergien; das MM2ERW-Kraftfeld, Chem. Ber., 1991, 124, 2499-2521. [all data]


Notes

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