Tin(IV) chloride

• Formula: Cl₄Sn
• Molecular weight: 260.522
• IUPAC Standard InChI: InChI=1S/4ClH.Sn/h4*1H;/q;;;;+4/p-4 Copy

  
• IUPAC Standard InChIKey: HPGGPRDJHPYFRM-UHFFFAOYSA-J Copy
• CAS Registry Number: 7646-78-8
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
  The 3d structure may be viewed using Java or Javascript.
• Other names: Stannic chloride; SnCl4; Stannane, tetrachloro-; Etain (tetrachlorure d'); Libavius Fuming spirit; Stagno (tetracloruro di); Stannic chloride, anhydrous; Stannic tetrachloride; Tetrachlorostannane; Tetrachlorotin; Tin chloride (SnCl4); Tin chloride, fuming; Tin perchloride; Tin tetrachloride; Tin tetrachloride, anhydrous; Tin(iv) chloride (1:4); Tin(IV) tetrachloride; Tin chloride; UN 1827; Zinntetrachlorid; Anhydrous tin tetrachloride; Fascat 4400; Libavius' fuming spirit; Tin (IV) chloride anhydrous; NSC 209802
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• Information on this page:
  • Reaction thermochemistry data
  • References
  • Notes
• Other data available:
  • Phase change data
  • Gas phase ion energetics data
  • Ion clustering data
  • Mass spectrum (electron ionization)
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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
B - John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

3 (l) +  (l) = 4 (l)

By formula: 3C₄H₁₂Sn (l) + Cl₄Sn (l) = 4C₃H₉ClSn (l)

 (l) + 3 (l) = 4 (l)

By formula: C₄H₁₂Sn (l) + 3Cl₄Sn (l) = 4CH₃Cl₃Sn (l)

 (l) +  (l) = 2 (l)

By formula: C₄H₁₂Sn (l) + Cl₄Sn (l) = 2C₂H₆Cl₂Sn (l)

 (l) +  (l) = C₂H₅Cl₃Sn (l) +  (l)

By formula: C₈H₂₀Sn (l) + Cl₄Sn (l) = C₂H₅Cl₃Sn (l) + C₆H₁₅ClSn (l)

 +  = Cl₅Sn^-

By formula: Cl^- + Cl₄Sn = Cl₅Sn^-

3 (l) +  (l) = 4 (l)

By formula: 3C₈H₂₀Sn (l) + Cl₄Sn (l) = 4C₆H₁₅ClSn (l)

3 (l) +  (l) = 4C₆H₉ClSn (l)

By formula: 3C₈H₁₂Sn (l) + Cl₄Sn (l) = 4C₆H₉ClSn (l)

 (l) + 3 (l) = 4C₂H₃Cl₃Sn (l)

By formula: C₈H₁₂Sn (l) + 3Cl₄Sn (l) = 4C₂H₃Cl₃Sn (l)

 (l) +  (l) = 2C₄H₆Cl₂Sn (l)

By formula: C₈H₁₂Sn (l) + Cl₄Sn (l) = 2C₄H₆Cl₂Sn (l)

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Nash, Skinner, et al., 1965
Nash, G.A.; Skinner, H.A.; Stack, W.F., Trans. Faraday Soc., 1965, 61, 640. [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds in Academic Press, New York, 1970. [all data]

Hao, Kaspar, et al., 2005
Hao, C.T.; Kaspar, J.D.; Check, C.E.; Lobring, K.C.; Gilbert, T.M.; Sunderlin, L.S., Effect of substituents on the strength of A-Cl- (A = Si, Ge, and Sn) bonds in hypervalent systems: ACl(5)(-), ACl(4)F(-), and A(CH3)(3)Cl-2(-), J. Phys. Chem. A, 2005, 109, 9, 2026-2034, https://doi.org/10.1021/jp040743x . [all data]

Notes

Go To: Top, Reaction thermochemistry data, References

• Symbols used in this document:
  

  ΔrH°	Enthalpy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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