O2C(CH2)4CO2 dianion


Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

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Clustering reactions

C6H8O4-2 + Hydrogen cation = C6H9O4-2

By formula: C6H8O4-2 + H+ = C6H9O4-2

Quantity Value Units Method Reference Comment
Δr403.3 ± 3.7kcal/molD-EADing, Wang, et al., 1998gas phase; B

C6H8O4-2 + Water = (C6H8O4-2 • Water)

By formula: C6H8O4-2 + H2O = (C6H8O4-2 • H2O)

Quantity Value Units Method Reference Comment
Δr7.1 ± 4.2kcal/molN/ADing, Wang, et al., 1998gas phase; Affinity is EA difference from next lower solvated ion.; B

(C6H8O4-2 • Water) + Water = (C6H8O4-2 • 2Water)

By formula: (C6H8O4-2 • H2O) + H2O = (C6H8O4-2 • 2H2O)

Quantity Value Units Method Reference Comment
Δr13.4 ± 4.2kcal/molN/ADing, Wang, et al., 1998gas phase; Affinity is EA difference from next lower solvated ion.; B

(C6H8O4-2 • 2Water) + Water = (C6H8O4-2 • 3Water)

By formula: (C6H8O4-2 • 2H2O) + H2O = (C6H8O4-2 • 3H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr8.40 ± 0.30kcal/molTDAsBlades, Klassen, et al., 1995gas phase; B,M

(C6H8O4-2 • 3Water) + Water = (C6H8O4-2 • 4Water)

By formula: (C6H8O4-2 • 3H2O) + H2O = (C6H8O4-2 • 4H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr7.50 ± 0.30kcal/molTDAsBlades, Klassen, et al., 1995gas phase; B,M

(C6H8O4-2 • 4Water) + Water = (C6H8O4-2 • 5Water)

By formula: (C6H8O4-2 • 4H2O) + H2O = (C6H8O4-2 • 5H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr6.40 ± 0.30kcal/molTDAsBlades, Klassen, et al., 1995gas phase; B,M

(C6H8O4-2 • 5Water) + Water = (C6H8O4-2 • 6Water)

By formula: (C6H8O4-2 • 5H2O) + H2O = (C6H8O4-2 • 6H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr5.80 ± 0.30kcal/molTDAsBlades, Klassen, et al., 1995gas phase; B,M

References

Go To: Top, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ding, Wang, et al., 1998
Ding, C.F.; Wang, X.B.; Wang, L.S., Photoelectron spectroscopy of doubly charged anions: Intramolecular Coulomb repulsion and solvent stabilization, J. Phys. Chem. A, 1998, 102, 45, 8633-8636, https://doi.org/10.1021/jp982698x . [all data]

Blades, Klassen, et al., 1995
Blades, A.T.; Klassen, J.S.; Kebarle, P., Free Energies of Hydration in the Gas Phase on the Anions of Some Oxo Acids of C, N, S, P, Cl and I, J. Am. Chem. Soc., 1995, 117, 42, 10563, https://doi.org/10.1021/ja00147a019 . [all data]


Notes

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