Formic acid, 1,1-dimethylethyl ester

• Formula: C₅H₁₀O₂
• Molecular weight: 102.1317
• IUPAC Standard InChI: InChI=1S/C5H10O2/c1-5(2,3)7-4-6/h4H,1-3H3 Copy

  
• IUPAC Standard InChIKey: RUPAXCPQAAOIPB-UHFFFAOYSA-N Copy
• CAS Registry Number: 762-75-4
• Chemical structure:
  This structure is also available as a 2d Mol file
• Other names: Formic acid, tert-butyl ester; tert-Butyl Formate
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• Information on this page:
  • Phase change data
  • References
  • Notes
• Other data available:
  • Gas phase thermochemistry data
  • Condensed phase thermochemistry data
  • Gas phase ion energetics data
  • Mass spectrum (electron ionization)
  • Gas Chromatography
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  • Gas Phase Kinetics Database
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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc., Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]

Young and Pare, 1958
Young, D.; Pare, E., J. Org. Chem., 1958, 23, 1772. [all data]

Barkenbus, Naff, et al., 1954
Barkenbus, C.; Naff, M.B.; Rapp, K.E., The Preparation and Properties of Some tert-Alkyl Formates, J. Org. Chem., 1954, 19, 1316. [all data]

Guthrie, 1977
Guthrie, J.P., Cyclization of glycol monoesters to give hemiorthoesters: a test of the thermochemical method for determining free energies of tetrahedral intermediates, Can. J. Chem., 1977, 55, 3562-3574. [all data]

Notes

Go To: Top, Phase change data, References

• Symbols used in this document:
  

  Tboil	Boiling point
  ΔvapH°	Enthalpy of vaporization at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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