Silane, trimethyl-2-propenyl-
- Formula: C6H14Si
- Molecular weight: 114.2609
- IUPAC Standard InChIKey: HYWCXWRMUZYRPH-UHFFFAOYSA-N
- CAS Registry Number: 762-72-1
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Silane, allyltrimethyl-; Allyltrimethylsilane; Trimethylallylsilane; 3-(Trimethylsilyl)-1-propene; 3-(Trimethylsilyl)propene; CA0570; Trimethyl-2-propenylsilane
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Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Robert L. Brown and Stephen E. Stein
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tboil | 358. to 359. | K | N/A | PCR Inc., 1990 |
Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
C6H13Si- + =
By formula: C6H13Si- + H+ = C6H14Si
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | <1592.3 ± 3.8 | kJ/mol | G+TS | DePuy, Bierbaum, et al., 1980 | gas phase; More acidic than MeOH. Computations indicate dGacid ca. 367 kcal/mol |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | <1564.8 | kJ/mol | IMRB | DePuy, Bierbaum, et al., 1980 | gas phase; More acidic than MeOH. Computations indicate dGacid ca. 367 kcal/mol |
Gas Chromatography
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Normal alkane RI, non-polar column, temperature ramp
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | OV-101 | 650. | Zenkevich, 2005 | 25. m/0.20 mm/0.10 μm, N2/He, 6. K/min; Tstart: 50. C; Tend: 250. C |
References
Go To: Top, Phase change data, Reaction thermochemistry data, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
PCR Inc., 1990
PCR Inc.,
Research Chemicals Catalog 1990-1991, PCR Inc., Gainesville, FL, 1990, 1. [all data]
DePuy, Bierbaum, et al., 1980
DePuy, C.H.; Bierbaum, V.M.; Flippin, L.A.; Brabowski, J.J.; King, G.K.; Schmidt, R.J.; Sullivan, S.A.,
Gas phase reactions of anions with substituted silanes,
J. Am. Chem. Soc., 1980, 102, 5012. [all data]
Zenkevich, 2005
Zenkevich, I.G.,
Experimentally measured retention indices., 2005. [all data]
Notes
Go To: Top, Phase change data, Reaction thermochemistry data, Gas Chromatography, References
- Symbols used in this document:
Tboil Boiling point ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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