Silane, trimethyl-2-propenyl-
- Formula: C6H14Si
- Molecular weight: 114.2609
- IUPAC Standard InChI: InChI=1S/C6H14Si/c1-5-6-7(2,3)4/h5H,1,6H2,2-4H3
- IUPAC Standard InChIKey: HYWCXWRMUZYRPH-UHFFFAOYSA-N
- CAS Registry Number: 762-72-1
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Silane, allyltrimethyl-; Allyltrimethylsilane; Trimethylallylsilane; 3-(Trimethylsilyl)-1-propene; 3-(Trimethylsilyl)propene; CA0570; Trimethyl-2-propenylsilane
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Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Robert L. Brown and Stephen E. Stein
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| Tboil | 358. to 359. | K | N/A | PCR Inc., 1990 |
Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
C6H13Si- + =
By formula: C6H13Si- + H+ = C6H14Si
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | <380.56 ± 0.90 | kcal/mol | G+TS | DePuy, Bierbaum, et al., 1980 | gas phase; More acidic than MeOH. Computations indicate dGacid ca. 367 kcal/mol |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | <374.00 | kcal/mol | IMRB | DePuy, Bierbaum, et al., 1980 | gas phase; More acidic than MeOH. Computations indicate dGacid ca. 367 kcal/mol |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
PCR Inc., 1990
PCR Inc.,
Research Chemicals Catalog 1990-1991, PCR Inc., Gainesville, FL, 1990, 1. [all data]
DePuy, Bierbaum, et al., 1980
DePuy, C.H.; Bierbaum, V.M.; Flippin, L.A.; Brabowski, J.J.; King, G.K.; Schmidt, R.J.; Sullivan, S.A.,
Gas phase reactions of anions with substituted silanes,
J. Am. Chem. Soc., 1980, 102, 5012. [all data]
Notes
Go To: Top, Phase change data, Reaction thermochemistry data, References
- Symbols used in this document:
Tboil Boiling point ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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