Camphor

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfgas-267. ± 3.kJ/molCcbSteele, 1977 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfsolid-319. ± 3.kJ/molCcbSteele, 1977ALS
Δfsolid-399. ± 66.kJ/molCcbDelafontaine, Sabbah, et al., 1973%hf298 calculated possible error by the authors; ALS
Quantity Value Units Method Reference Comment
Δcsolid-5902. ± 3.kJ/molCcbSteele, 1977Corresponding Δfsolid = -319. kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Δcsolid-5822. ± 66.kJ/molCcbDelafontaine, Sabbah, et al., 1973%hf298 calculated possible error by the authors; Corresponding Δfsolid = -400. kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Δcsolid-5891.2kJ/molCcbShchukarev and Shchukareva, 1932Corresponding Δfsolid = -330.5 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Δcsolid-5898.6 ± 3.8kJ/molCcbSwietoslawski and Bobinska, 1929Corresponding Δfsolid = -323. kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Δcsolid-5910.7kJ/molCcbRoth and Ostling, 1913Corresponding Δfsolid = -311. kJ/mol (simple calculation by NIST; no Washburn corrections); ALS

Constant pressure heat capacity of solid

Cp,solid (J/mol*K) Temperature (K) Reference Comment
271.2298.1Frandsen, 1931T = 307 to 483 K.; DH

Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

1,7,7-Trimethyl-2-norbornanone dimethyl ketal + Water = 2Methyl Alcohol + Camphor

By formula: C12H22O2 + H2O = 2CH4O + C10H16O

Quantity Value Units Method Reference Comment
Δr7.73 ± 0.36kJ/molCmWiberg and Cunningham, 1990liquid phase; Heat of hydrolysis

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Steele, 1977
Steele, W.V., The standard enthalpies of formation of bicyclic compounds. III. 1,7,7-trimethylbicyclo[2.2.1]heptan-2-one, J. Chem. Thermodyn., 1977, 9, 311-314. [all data]

Delafontaine, Sabbah, et al., 1973
Delafontaine, J.; Sabbah, R.; Laffitte, M., Mesures microcalorimetriques des enthalpies de reference de formation (a l'etat condense) de composes volatils - mise au point de la technique, Z. Phys. Chem. (Neue Folge), 1973, 84, 157-172. [all data]

Shchukarev and Shchukareva, 1932
Shchukarev, A.N.; Shchukareva, L.A., Heat standards, Russ. J. Phys. Chem. (Engl. Transl.), 1932, 3, 169-174. [all data]

Swietoslawski and Bobinska, 1929
Swietoslawski, M.W.; Bobinska, M.J., O cieple spalania kamfory, azobenzenu i hydrazobenzenu - Sur la chaleur de combustion du comphre, de l'hydrazobenzene, Rocz. Chem., 1929, 9, 723-730. [all data]

Roth and Ostling, 1913
Roth, W.A.; Ostling, G.J., Thermochemische Untersuchungen in der alicyclischen Reihe, Ber., 1913, 46, 309-327. [all data]

Frandsen, 1931
Frandsen, M., Cryoscopic constant, heat of fusion, and heat capacity of camphor, Bur. Stand. J. Res., 1931, 7, 477-483. [all data]

Wiberg and Cunningham, 1990
Wiberg, K.B.; Cunningham, W.C., Jr., Thermochemical studies of carbonyl reactions. 4. Enthalpies of hydrolysis of norbornyl ketals, J. Org. Chem., 1990, 55, 679-684. [all data]


Notes

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