bromodiethylaluminium
- Formula: C4H10AlBr
- Molecular weight: 165.008
- CAS Registry Number: 760-19-0
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Condensed phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°liquid | -325.8 ± 3.5 | kJ/mol | Review | Martinho Simões | The enthalpy of formation relies on -187.3 ± 5.1 kJ/mol for the enthalpy of formation of Al(Et)3(l). |
Reaction thermochemistry data
Go To: Top, Condensed phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
AlBr3 (cr) + 2 (l) = 3C4H10AlBr (l)
By formula: AlBr3 (cr) + 2C6H15Al (l) = 3C4H10AlBr (l)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | -91.4 ± 1.8 | kJ/mol | RSC | Smith, 1974 | Please also see Pedley and Rylance, 1977. |
C2H5AlBr2 (l) + (l) = 2C4H10AlBr (l)
By formula: C2H5AlBr2 (l) + C6H15Al (l) = 2C4H10AlBr (l)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | -39.7 ± 0.8 | kJ/mol | RSC | Smith, 1974 | Please also see Pedley and Rylance, 1977. |
C2H5AlBr2 (l) + C4H10AlBr (l) = C6H15Al2Br3 (l)
By formula: C2H5AlBr2 (l) + C4H10AlBr (l) = C6H15Al2Br3 (l)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | -2.5 ± 0.2 | kJ/mol | RSC | Smith, 1974 | Please also see Pedley and Rylance, 1977. |
References
Go To: Top, Condensed phase thermochemistry data, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Martinho Simões
Martinho Simões, J.A.,
Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]
Smith, 1974
Smith, M.B.,
J. Organometal. Chem., 1974, 76, 171. [all data]
Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J.,
Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]
Notes
Go To: Top, Condensed phase thermochemistry data, Reaction thermochemistry data, References
- Symbols used in this document:
ΔfH°liquid Enthalpy of formation of liquid at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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