bromodiethylaluminium


Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfliquid-325.8 ± 3.5kJ/molReviewMartinho SimõesThe enthalpy of formation relies on -187.3 ± 5.1 kJ/mol for the enthalpy of formation of Al(Et)3(l).

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

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Individual Reactions

AlBr3 (cr) + 2Aluminum, triethyl- (l) = 3C4H10AlBr (l)

By formula: AlBr3 (cr) + 2C6H15Al (l) = 3C4H10AlBr (l)

Quantity Value Units Method Reference Comment
Δr-91.4 ± 1.8kJ/molRSCSmith, 1974Please also see Pedley and Rylance, 1977.

C2H5AlBr2 (l) + Aluminum, triethyl- (l) = 2C4H10AlBr (l)

By formula: C2H5AlBr2 (l) + C6H15Al (l) = 2C4H10AlBr (l)

Quantity Value Units Method Reference Comment
Δr-39.7 ± 0.8kJ/molRSCSmith, 1974Please also see Pedley and Rylance, 1977.

C2H5AlBr2 (l) + C4H10AlBr (l) = C6H15Al2Br3 (l)

By formula: C2H5AlBr2 (l) + C4H10AlBr (l) = C6H15Al2Br3 (l)

Quantity Value Units Method Reference Comment
Δr-2.5 ± 0.2kJ/molRSCSmith, 1974Please also see Pedley and Rylance, 1977.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Smith, 1974
Smith, M.B., J. Organometal. Chem., 1974, 76, 171. [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]


Notes

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