Amylene hydrate
- Formula: C5H12O
- Molecular weight: 88.1482
- IUPAC Standard InChI: InChI=1S/C5H12O/c1-4-5(2,3)6/h6H,4H2,1-3H3
- IUPAC Standard InChIKey: MSXVEPNJUHWQHW-UHFFFAOYSA-N
- CAS Registry Number: 75-85-4
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: 2-Butanol, 2-methyl-; tert-Pentyl alcohol; tert-Amyl alcohol; tert-Pentanol; Dimethyl ethyl carbinol; Ethyl dimethyl carbinol; 1,1-Dimethyl-1-propanol; 2-Methyl-2-butanol; C2H5C(CH3)2OH; 2-Methyl butanol-2; 3-Methylbutan-3-ol; t-Amyl alcohol; 2-Methylbutan-2-ol; tert-Isoamyl alcohol; 3-Methyl-butanol-(3); Methyl-2 butanol-2; Methyl-3 butanol-3; NSC 25498; 2-methyl-2-butanol (tert-amyl alcohol)
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Condensed phase thermochemistry data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°liquid | -90.71 ± 0.13 | kcal/mol | Ccb | Chao and Rossini, 1965 | ALS |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔcH°liquid | -789.45 ± 0.11 | kcal/mol | Ccb | Chao and Rossini, 1965 | Corresponding ΔfHºliquid = -90.70 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS |
| Quantity | Value | Units | Method | Reference | Comment |
| S°liquid | 54.80 | cal/mol*K | N/A | Parks, Huffman, et al., 1933 | Extrapolation below 90 K, 46.78 J/mol*K.; DH |
Constant pressure heat capacity of liquid
| Cp,liquid (cal/mol*K) | Temperature (K) | Reference | Comment |
|---|---|---|---|
| 59.070 | 298.15 | Piekarski and Somsen, 1988 | DH |
| 59.479 | 298.15 | Benson and D'Arcy, 1986 | DH |
| 59.479 | 298.15 | Benson and D'Arcy, 1986, 2 | DH |
| 59.11 | 298.15 | D'Aprano, DeLisi, et al., 1983 | Data given at 288 and 298 K.; DH |
| 58.351 | 294.4 | Parks, Huffman, et al., 1933 | T = 92 to 294 K. Value is unsmoothed experimental datum.; DH |
References
Go To: Top, Condensed phase thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Chao and Rossini, 1965
Chao, J.; Rossini, F.D.,
Heats of combustion, formation, and isomerization of nineteen alkanols,
J. Chem. Eng. Data, 1965, 10, 374-379. [all data]
Parks, Huffman, et al., 1933
Parks, G.S.; Huffman, H.M.; Barmore, M.,
Thermal data on organic compounds. XI. The heat capacities,
entropies and free energies of ten compounds containing oxygen or nitrogen. J. Am. Chem. Soc., 1933, 55, 2733-2740. [all data]
Piekarski and Somsen, 1988
Piekarski, H.; Somsen, G.,
Heat capacities and volumes of mixtures of N,N-dimethylformamide with isobutanol, sec-butanol and t-pentanol, J. Chem. Soc.,
Faraday Trans. 1, 1988, 84(2), 529-537. [all data]
Benson and D'Arcy, 1986
Benson, G.C.; D'Arcy, P.J.,
Excess isobaric heat capacities of some binary mixtures: (a C5-alkanol + n-heptane) at 298.15 K,
J. Chem. Thermodynam., 1986, 18, 493-498. [all data]
Benson and D'Arcy, 1986, 2
Benson, G.C.; D'Arcy, P.J.,
Heat capacities of binary mixtures of n-dodecane with hexane isomers,
Thermochim. Acta, 1986, 102, 75-81. [all data]
D'Aprano, DeLisi, et al., 1983
D'Aprano, A.; DeLisi, R.; Donato, D.I.,
Thermodynamics of binary mixtures: volumes, heat capacities, and dilution enthalpies for the n-pentanol + 2-methyl-2-butanol system,
J. Solution Chem., 1983, 12, 383-400. [all data]
Notes
Go To: Top, Condensed phase thermochemistry data, References
- Symbols used in this document:
Cp,liquid Constant pressure heat capacity of liquid S°liquid Entropy of liquid at standard conditions ΔcH°liquid Enthalpy of combustion of liquid at standard conditions ΔfH°liquid Enthalpy of formation of liquid at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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