Dichlorodifluoromethane
- Formula: CCl2F2
- Molecular weight: 120.914
- IUPAC Standard InChIKey: PXBRQCKWGAHEHS-UHFFFAOYSA-N
- CAS Registry Number: 75-71-8
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Methane, dichlorodifluoro-; Algofrene Type 2; Arcton 12; Arcton 6; Chlorofluoromethane (CCl2F2); Difluorodichloromethane; Electro-CF 12; F 12; Freon 12; Frigen 12; FC 12; Genetron 12; Isceon 122; Isotron 12; Ledon 12; R 12; R 12, Refrigerant; Refrigerant 12; CF2Cl2; Fluorocarbon 12; Propellant 12; Dwuchlorodwufluorometan; Eskimon 12; Freon F-12; Kaiser chemicals 12; Rcra waste number U075; Ucon 12; Ucon 12/halocarbon 12; UN 1028; CCl2F2; Halon 122; CFC-12; Halocarbon 12; Isotron 2; Propellent 12; Refrigerant R12; Chlorofluorocarbon 12; Dymel 12; FCC 12; FKW 12; Forane 12
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Phase change data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tboil | 243.3 | K | N/A | PCR Inc., 1990 | BS |
Tboil | 243. | K | N/A | Krauss and Stephan, 1989 | Uncertainty assigned by TRC = 1.5 K; TRC |
Tboil | 243.4 | K | N/A | Streng, 1971 | Uncertainty assigned by TRC = 0.3 K; TRC |
Tboil | 242. | K | N/A | Awbery and Griffiths, 1936 | Uncertainty assigned by TRC = 5. K; TRC |
Tboil | 245.35 | K | N/A | Thornton, Burg, et al., 1933 | Uncertainty assigned by TRC = 0.5 K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
Tfus | 115.2 | K | N/A | Streng, 1971 | Uncertainty assigned by TRC = 0.3 K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
Ttriple | 116.100 | K | N/A | Blanke and Weiss, 1991 | Uncertainty assigned by TRC = 0.01 K; on ITS-90; TRC |
Ttriple | 115.15 | K | N/A | Krauss and Stephan, 1989 | Uncertainty assigned by TRC = 0.1 K; TRC |
Ttriple | 390.35 | K | N/A | Altunin, Geller, et al., 1987 | Uncertainty assigned by TRC = 0.05 K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
Ptriple | 0.00010 | bar | N/A | Blanke and Weiss, 1991 | Uncertainty assigned by TRC = 0.00006 bar; TRC |
Quantity | Value | Units | Method | Reference | Comment |
Tc | 385.15 | K | N/A | Krauss and Stephan, 1989 | Uncertainty assigned by TRC = 0.3 K; TRC |
Tc | 385.15 | K | N/A | Altunin, Geller, et al., 1987 | Uncertainty assigned by TRC = 0.2 K; TRC |
Tc | 385.01 | K | N/A | Okada, Uematsu, et al., 1986 | Uncertainty assigned by TRC = 0.03 K; Tc selected from literature to correlate density meas.; TRC |
Tc | 385.01 | K | N/A | Higashi, Okazaki, et al., 1984 | Uncertainty assigned by TRC = 0.05 K; TRC |
Tc | 302.3 | K | N/A | Michels, Wassenaar, et al., 1966 | Uncertainty assigned by TRC = 0.06 K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
Pc | 41.31 | bar | N/A | Krauss and Stephan, 1989 | Uncertainty assigned by TRC = 0.05 bar; TRC |
Pc | 41.19 | bar | N/A | Altunin, Geller, et al., 1987 | Uncertainty assigned by TRC = 0.20 bar; TRC |
Pc | 41.29 | bar | N/A | Higashi, Okazaki, et al., 1984 | Uncertainty assigned by TRC = 0.15 bar; TRC |
Pc | 39.1115 | bar | N/A | Michels, Wassenaar, et al., 1966 | Uncertainty assigned by TRC = 0.0607 bar; TRC |
Quantity | Value | Units | Method | Reference | Comment |
ρc | 4.789 | mol/l | N/A | Altunin, Geller, et al., 1987 | Uncertainty assigned by TRC = 0.004 mol/l; TRC |
ρc | 4.70 | mol/l | N/A | Okada, Uematsu, et al., 1986 | Uncertainty assigned by TRC = 0.0469 mol/l; Density measured with magnetic densimeter. Tc, Dc selected from literature to correlate density measurements. R12; TRC |
ρc | 4.70 | mol/l | N/A | Higashi, Okazaki, et al., 1984 | Uncertainty assigned by TRC = 0.04 mol/l; TRC |
ρc | 5.54 | mol/l | N/A | Michels, Wassenaar, et al., 1966 | Uncertainty assigned by TRC = 0.07 mol/l; TRC |
Enthalpy of vaporization
ΔvapH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
20.0 | 297. | A | Stephenson and Malanowski, 1987 | Based on data from 282. to 345. K.; AC |
21.4 | 229. | A | Stephenson and Malanowski, 1987 | Based on data from 173. to 244. K.; AC |
21.6 | 225. | A | Stephenson and Malanowski, 1987 | Based on data from 173. to 240. K.; AC |
20.4 | 270. | A | Stephenson and Malanowski, 1987 | Based on data from 236. to 285. K.; AC |
20.5 | 356. | A | Stephenson and Malanowski, 1987 | Based on data from 341. to 385. K.; AC |
22.9 | 187. | N/A | Kudchadker, Kudchadker, et al., 1979 | Based on data from 172. to 279. K.; AC |
21.5 | 228. | N/A | Stull, 1947 | Based on data from 154. to 243. K.; AC |
20.4 | 243. | N/A | Buffington and Fleischer, 1931 | AC |
Antoine Equation Parameters
log10(P) = A − (B / (T + C))
P = vapor pressure (bar)
T = temperature (K)
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Temperature (K) | A | B | C | Reference | Comment |
---|---|---|---|---|---|
154.7 to 243.4 | 3.81109 | 782.072 | -37.773 | Stull, 1947 | Coefficents calculated by NIST from author's data. |
References
Go To: Top, Phase change data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
PCR Inc., 1990
PCR Inc.,
Research Chemicals Catalog 1990-1991, PCR Inc., Gainesville, FL, 1990, 1. [all data]
Krauss and Stephan, 1989
Krauss, R.; Stephan, K.,
Thermal Conductivity of Refrigerants in a Wide Range of Temperature and Pressure,
J. Phys. Chem. Ref. Data, 1989, 18, 43. [all data]
Streng, 1971
Streng, A.G.,
Miscibility and Compatibility of Some Liquid and Solidified Gases at Low Temperature,
J. Chem. Eng. Data, 1971, 16, 357. [all data]
Awbery and Griffiths, 1936
Awbery, J.H.; Griffiths, E.,
The Viscosities of Some Liquid Refrigerants,
Proc. Phys. Soc. London, 1936, 48, 372-80. [all data]
Thornton, Burg, et al., 1933
Thornton, N.V.; Burg, A.B.; Schlesinger, H.I.,
The Behaviour of Dichlorodifluoromethane and of Chlorotrifluoromethane in the Electric Discharge,
J. Am. Chem. Soc., 1933, 55, 3177. [all data]
Blanke and Weiss, 1991
Blanke, W.; Weiss, R.,
Thermodynamic properties of refrigerants. Part I: the triple points of the refrigerants R11, R12, R22, R142b, and 152a,
PTB-Mitt., 1991, 101, 337-9. [all data]
Altunin, Geller, et al., 1987
Altunin, V.V.; Geller, V.Z.; Kremenvskaya, E.A.; Perel'shtein, I.I.; Petrov, E.K.,
Thermophysical Properties of Freons, Methane Ser. Part 2, Vol. 9, NSRDS-USSR, Selover, T. B., Ed., Hemisphere, New York, 1987. [all data]
Okada, Uematsu, et al., 1986
Okada, M.; Uematsu, M.; Watanabe, K.,
Orthobaric liquid densities of trichloro-fluoromethane, dichlorodi-fluoromethane, chlorodifluoromethane, 1,1,2-trichlorotrifluoroethane, 1,2-dichlorotetrafluoroethane, and of the azeotropic mixtur,
J. Chem. Thermodyn., 1986, 18, 527. [all data]
Higashi, Okazaki, et al., 1984
Higashi, Y.; Okazaki, S.; Takaishi, Y.; Uematsu, M.; Watanabe, K.,
Measurements of the Vapor-Liquid Coexistence Curve for the Binary R12 + R22 System in the Critical Region,
J. Chem. Eng. Data, 1984, 29, 31-6. [all data]
Michels, Wassenaar, et al., 1966
Michels, A.; Wassenaar, T.; Wolkers, G.J.; Prins, Chr.; van de Klundert, L.,
P-v-t data and thermodynamical properties of freon-12 (ccl(2)f(2)) and freon-13 (cclf(3)) fluorocarbons at temperatures between 0 and 150c and at pressures up to 400 atm,
J. Chem. Eng. Data, 1966, 11, 449. [all data]
Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw,
Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2
. [all data]
Kudchadker, Kudchadker, et al., 1979
Kudchadker, A.P.; Kudchadker, S.A.; Shukla, R.P.; Patnaik, P.R.,
Vapor pressures and boiling points of selected halomethanes,
J. Phys. Chem. Ref. Data, 1979, 8, 2, 499, https://doi.org/10.1063/1.555600
. [all data]
Stull, 1947
Stull, Daniel R.,
Vapor Pressure of Pure Substances. Organic and Inorganic Compounds,
Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022
. [all data]
Buffington and Fleischer, 1931
Buffington, R.M.; Fleischer, J.,
Thermodynamic properties of dichlorodifluoromethane, a new refrigerant. IV. Specific heat of liquid and vapor and latent heat of vaporization,
Ind. Eng. Chem., 1931, 23, 1290-1292. [all data]
Notes
Go To: Top, Phase change data, References
- Symbols used in this document:
Pc Critical pressure Ptriple Triple point pressure Tboil Boiling point Tc Critical temperature Tfus Fusion (melting) point Ttriple Triple point temperature ΔvapH Enthalpy of vaporization ρc Critical density - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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