Methane, bromotrichloro-
- Formula: CBrCl3
- Molecular weight: 198.274
- IUPAC Standard InChI: InChI=1S/CBrCl3/c2-1(3,4)5
- IUPAC Standard InChIKey: XNNQFQFUQLJSQT-UHFFFAOYSA-N
- CAS Registry Number: 75-62-7
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Bromotrichloromethane; Carbon bromotrichloride; Monobromotrichloromethane; Trichlorobromomethane; CCl3Br; Carbon trichlorobromide; Trichloromethyl bromide
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Condensed phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Eugene S. Domalski and Elizabeth D. Hearing
Constant pressure heat capacity of liquid
| Cp,liquid (J/mol*K) | Temperature (K) | Reference | Comment |
|---|---|---|---|
| 149.4 | 298. | Bengough and Thomson, 1959 | Mean value 25 to 50°C. |
Phase change data
Go To: Top, Condensed phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
CAL - James S. Chickos, William E. Acree, Jr., Joel F. Liebman, Students of Chem 202 (Introduction to the Literature of Chemistry), University of Missouri -- St. Louis
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| Tboil | 376.65 | K | N/A | Zakharkin, 1952 | Uncertainty assigned by TRC = 2. K; TRC |
| Quantity | Value | Units | Method | Reference | Comment |
| Tfus | 268. | K | N/A | Dreisbach, 1955 | Uncertainty assigned by TRC = 0.02 K; TRC |
Enthalpy of vaporization
| ΔvapH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 35.0 | 288. | N/A | Kudchadker, Kudchadker, et al., 1979 | Based on data from 273. to 387. K.; AC |
| 36.1 | 309. | A | Dykyj, 1970 | Based on data from 294. to 443. K. See also Stephenson and Malanowski, 1987.; AC |
Enthalpy of fusion
| ΔfusH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 2.54 | 267.5 | AC | Acree, 1991 | See also Ohta, Yamamuro, et al., 1995.; AC |
Entropy of fusion
| ΔfusS (J/mol*K) | Temperature (K) | Reference | Comment |
|---|---|---|---|
| 19.4 | 238.2 | Cypcar, Johnson, et al., 1995 | CAL |
| 2.03 | 259.3 | ||
| 7.58 | 267.9 |
References
Go To: Top, Condensed phase thermochemistry data, Phase change data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Bengough and Thomson, 1959
Bengough, W.I.; Thomson, R.A.M.,
A dilatometric method of measuring the heats of radiation-induced reactions. Part 2.- The heat of photochemical addition of bromotrichloromethane to vinyl acetate,
Trans. Faraday Soc., 1959, 55, 268-271. [all data]
Zakharkin, 1952
Zakharkin, L.I.,
Bromotrichloromethane,
Sint. Org. Soedin., 1950-52, 1952, 2, 18. [all data]
Dreisbach, 1955
Dreisbach, R.R.,
Physical Properties of Chemical Compounds, Advances in Chemistry Series No. 15, Am. Chem. Soc.: Washington, D. C., 1955. [all data]
Kudchadker, Kudchadker, et al., 1979
Kudchadker, A.P.; Kudchadker, S.A.; Shukla, R.P.; Patnaik, P.R.,
Vapor pressures and boiling points of selected halomethanes,
J. Phys. Chem. Ref. Data, 1979, 8, 2, 499, https://doi.org/10.1063/1.555600
. [all data]
Dykyj, 1970
Dykyj, J.,
Petrochemica, 1970, 10, 2, 51. [all data]
Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw,
Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2
. [all data]
Acree, 1991
Acree, William E.,
Thermodynamic properties of organic compounds: enthalpy of fusion and melting point temperature compilation,
Thermochimica Acta, 1991, 189, 1, 37-56, https://doi.org/10.1016/0040-6031(91)87098-H
. [all data]
Ohta, Yamamuro, et al., 1995
Ohta, Tomoko; Yamamuro, Osamu; Matsuo, Takasuke,
Heat Capacities and Phase Transitions of CBrCl3 and CBr2Cl2,
J. Phys. Chem., 1995, 99, 8, 2403-2407, https://doi.org/10.1021/j100008a024
. [all data]
Cypcar, Johnson, et al., 1995
Cypcar, C.C.; Johnson, G.; Mathias, L.J.,
Molecular motions in low molar-mass alkyl amides: models for thermal transitions in polyamides,
Polym. Prepr. (Am. Chem. Soc. Div. Polym. Chem.), 1995, 36, 2, 402. [all data]
Notes
Go To: Top, Condensed phase thermochemistry data, Phase change data, References
- Symbols used in this document:
Cp,liquid Constant pressure heat capacity of liquid Tboil Boiling point Tfus Fusion (melting) point ΔfusH Enthalpy of fusion ΔfusS Entropy of fusion ΔvapH Enthalpy of vaporization - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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