Tetramethylammonium chloride

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Eugene S. Domalski and Elizabeth D. Hearing

Enthalpy of phase transition

ΔHtrs (kJ/mol) Temperature (K) Initial Phase Final Phase Reference Comment
9.905536.crystaline, IIcrystaline, IMurrill and Breed, 1970 
0.116375.76crystaline Chang and Westrum, 1962 
0.1084184.85crystaline, IIcrystaline, IChang and Westrum, 1962Transition over range 180 to 190 K.

Entropy of phase transition

ΔStrs (J/mol*K) Temperature (K) Initial Phase Final Phase Reference Comment
18.4536.crystaline, IIcrystaline, IMurrill and Breed, 1970 
1.5475.76crystaline Chang and Westrum, 1962 
0.59184.85crystaline, IIcrystaline, IChang and Westrum, 1962Transition

IR Spectrum

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Coblentz Society, Inc.

Condensed Phase Spectrum

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IR spectrum
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Notice: Except where noted, spectra from this collection were measured on dispersive instruments, often in carefully selected solvents, and hence may differ in detail from measurements on FTIR instruments or in other chemical environments. More information on the manner in which spectra in this collection were collected can be found here.

Notice: Concentration information is not available for this spectrum and, therefore, molar absorptivity values cannot be derived.

Additional Data

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Owner COBLENTZ SOCIETY
Collection (C) 2018 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin WYANDOTTE CHEMICALS CORP., WYANDOTTE, MICHIGAN, USA
Source reference COBLENTZ NO. 432
Date Not specified, most likely prior to 1970
Name(s) tetramethyl-.lambda.<5>-azane hydrochloride
State SOLID (MULLS, KEL-F OIL FOR 2-7.5 AND MINERAL OIL FOR 7.5-16 MICRONS)
Instrument Not specified, most likely a prism, grating, or hybrid spectrometer.
Resolution 4
Sampling procedure TRANSMISSION
Data processing DIGITIZED BY NIST FROM HARD COPY
Melting point 150-152 C DECOMPOSES

This IR spectrum is from the Coblentz Society's evaluated infrared reference spectra collection.


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Murrill and Breed, 1970
Murrill, E.; Breed, L., Solid-solid phase transitions determined by differential scanning calorimetry, Thermochim. Acta, 1970, 1, 239-246. [all data]

Chang and Westrum, 1962
Chang, S.-S.; Westrum, E.F., Jr., Heat capacities and thermodynamic properties of two tetramethylammonium halides, J. Chem. Phys., 1962, 36, 2420-2423. [all data]


Notes

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