Iodine

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Reaction thermochemistry data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
MS - José A. Martinho Simões
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Reactions 1 to 50

Iodide + Iodine = I3-

By formula: I- + I2 = I3-

Quantity Value Units Method Reference Comment
Δr136. ± 10.kJ/molN/ATaylor, Asmis, et al., 1999gas phase; B
Δr126. ± 5.9kJ/molCIDTDo, Klein, et al., 1997gas phase; B
Δr356.1kJ/molTherFinch, Gates, et al., 1977gas phase; This value is far more bound than expected from other studies; B
Δr136.4kJ/molN/ACheck, Faust, et al., 2001gas phase; FeF3-(t); ; ΔS(EA)=2.8; B
Quantity Value Units Method Reference Comment
Δr94.14kJ/molN/ACheck, Faust, et al., 2001gas phase; FeF3-(t); ; ΔS(EA)=2.8; B

Dimanganese decacarbonyl (cr) + Iodine (cr) = 2Manganese, pentacarbonyliodo- (cr)

By formula: C10Mn2O10 (cr) + I2 (cr) = 2C5IMnO5 (cr)

Quantity Value Units Method Reference Comment
Δr-185.0 ± 8.7kJ/molPCHarel and Adamson, 1986The reaction enthalpy was calculated from the enthalpy of the same reaction in cyclohexane, -187.9 ± 8.4 kJ/mol Harel and Adamson, 1986, and from the solution enthalpies of Mn2(CO)10(cr), 36.0 ± 2.1 kJ/mol, I2(cr), 20.5 ± 0.4 kJ/mol, and Mn(CO)5(I)(cr), 26.8 ± 0.5 kJ/mol Harel and Adamson, 1986. The latter value refers to the solution in benzene and is therefore taken as an approximation; MS

Dirhenium decacarbonyl (cr) + Iodine (cr) = 2Rhenium, pentacarbonyliodo- (cr)

By formula: C10O10Re2 (cr) + I2 (cr) = 2C5IO5Re (cr)

Quantity Value Units Method Reference Comment
Δr-172. ± 18.kJ/molPCHarel and Adamson, 1986The reaction enthalpy was calculated from the enthalpy of the same reaction in cyclohexane, -157. ± 16. kJ/mol, and from the solution enthalpies of Re2(CO)10(cr), 34.3 ± 2.1 kJ/mol, I2(cr), 20.5 ± 0.4 kJ/mol, and Re(CO)5(I)(cr), 34.7 ± 4.2 kJ/mol Harel and Adamson, 1986; MS

Hydrogen iodide + 1-Propene, 3-iodo- = Propene + Iodine

By formula: HI + C3H5I = C3H6 + I2

Quantity Value Units Method Reference Comment
Δr-33.3 ± 1.4kJ/molEqkRodgers, Golden, et al., 1966gas phase; ALS
Δr-39.7 ± 4.2kJ/molEqkRodgers, Golden, et al., 1966gas phase; Reanalyzed by Cox and Pilcher, 1970, Original value = -34.9 ± 0.96 kJ/mol; At 527 K; ALS

Hydrogen iodide + Methane, iodo- = Methane + Iodine

By formula: HI + CH3I = CH4 + I2

Quantity Value Units Method Reference Comment
Δr-52.55 ± 0.54kJ/molEqkGolden, Walsh, et al., 1965gas phase; ALS
Δr-53.0 ± 0.2kJ/molEqkGoy and Pritchard, 1965gas phase; ALS
Δr-46.2 ± 5.6kJ/molCmNichol and Ubbelohde, 1952gas phase; ALS

C12H16Nb (cr) + 2Iodine (cr) = C10H10I2Nb (cr) + 2Methane, iodo- (l)

By formula: C12H16Nb (cr) + 2I2 (cr) = C10H10I2Nb (cr) + 2CH3I (l)

Quantity Value Units Method Reference Comment
Δr-242.3 ± 2.4kJ/molRSCDiogo, Simoni, et al., 1993The difference between the enthalpies of formation of Nb(Cp)2(I)2 and Nb(Cp)2(Me)2 is calculated as -215.1 ± 2.6 kJ/mol; MS

C20H26CoN5O4 (solution) + Iodine (solution) = C13H19CoIN5O4 (solution) + Benzene, (iodomethyl)- (solution)

By formula: C20H26CoN5O4 (solution) + I2 (solution) = C13H19CoIN5O4 (solution) + C7H7I (solution)

Quantity Value Units Method Reference Comment
Δr-63.2 ± 3.8kJ/molRSCToscano, Seligson, et al., 1989solvent: Bromoform; The enthalpy of solution of Co(py)(dmg)2(Bz)(cr) was measured as 11.3 kJ/mol Toscano, Seligson, et al., 1989; MS

C14H22CoN5O4 (solution) + Iodine (solution) = C13H19CoIN5O4 (solution) + Methane, iodo- (solution)

By formula: C14H22CoN5O4 (solution) + I2 (solution) = C13H19CoIN5O4 (solution) + CH3I (solution)

Quantity Value Units Method Reference Comment
Δr-92.9 ± 2.5kJ/molRSCToscano, Seligson, et al., 1989solvent: Bromoform; The enthalpy of solution of Co(py)(dmg)2(Me)(cr) was measured as 10.9 kJ/mol Toscano, Seligson, et al., 1989; MS

Hydromanganese pentacarbonyl (l) + Iodine (cr) = Hydrogen iodide (g) + Manganese, pentacarbonyliodo- (cr)

By formula: C5HMnO5 (l) + I2 (cr) = HI (g) + C5IMnO5 (cr)

Quantity Value Units Method Reference Comment
Δr-108. ± 8.kJ/molRSCConnor, Zafarani-Moattar, et al., 1982The reaction enthalpy relies on -25. ± 5. kJ/mol for the enthalpy of solution of HI(g) in benzene Connor, Zafarani-Moattar, et al., 1982.; MS

Ethylene + Iodine = Ethane, 1,2-diiodo-

By formula: C2H4 + I2 = C2H4I2

Quantity Value Units Method Reference Comment
Δr-48.1 ± 0.8kJ/molEqkAbrams and Davis, 1954gas phase; ALS
Δr-56. ± 2.kJ/molEqkCutherbertson and Kistiakowsky, 1935gas phase; Heat of dissociation; ALS

Iodine + Chlorotrifluoromethane = Methane, trifluoroiodo- + Iodine monochloride

By formula: I2 + CClF3 = CF3I + ClI

Quantity Value Units Method Reference Comment
Δr72.3 ± 1.1kJ/molEqkLord, Goy, et al., 1967gas phase; Reanalyzed by Cox and Pilcher, 1970, Original value = 71.55 ± 0.71 kJ/mol; ALS

Hydrogen iodide + Cyclohexane, iodo- = Cyclohexane + Iodine

By formula: HI + C6H11I = C6H12 + I2

Quantity Value Units Method Reference Comment
Δr-32.6 ± 8.4kJ/molCmBrennan and Ubbelohde, 1956gas phase; Reanalyzed by Cox and Pilcher, 1970, Original value = -28. ± 4.2 kJ/mol; ALS

Ethane, 1,1,1-trifluoro- + Iodine = Hydrogen iodide + 1,1,1-Trifluoro-2-iodoethane

By formula: C2H3F3 + I2 = HI + C2H2F3I

Quantity Value Units Method Reference Comment
Δr-64. ± 2.kJ/molEqkWu and Rodgers, 1974gas phase; Heat of formation Unpublished results by B.J. Zwolinski; ALS

2-Bromo-1,1,1-trifluoroethane + Iodine = 1,1,1-Trifluoro-2-iodoethane + iodine bromide

By formula: C2H2BrF3 + I2 = C2H2F3I + BrI

Quantity Value Units Method Reference Comment
Δr28. ± 2.kJ/molEqkBuckley, Ford, et al., 1980gas phase; GLC;hf298_gas[kcal/mol]=-166.8±1.1; Kolesov and Papina, 1983; ALS

Mercury, dimethyl- (l) + 2Iodine (cr) = 2Methane, iodo- (l) + Mercury diiodide (cr)

By formula: C2H6Hg (l) + 2I2 (cr) = 2CH3I (l) + HgI2 (cr)

Quantity Value Units Method Reference Comment
Δr-184.5 ± 0.8kJ/molRSCHartley, Pritchard, et al., 1950Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970, 2.; MS

Dirhenium decacarbonyl (solution) + Iodine (solution) = 2Rhenium, pentacarbonyliodo- (solution)

By formula: C10O10Re2 (solution) + I2 (solution) = 2C5IO5Re (solution)

Quantity Value Units Method Reference Comment
Δr-157. ± 16.kJ/molPCHarel and Adamson, 1986solvent: Cyclohexane; Please also see Adamson, Vogler, et al., 1978.; MS

Gallium trimethyl (l) + 3Iodine (cr) = GaI3 (cr) + 3Methane, iodo- (l)

By formula: C3H9Ga (l) + 3I2 (cr) = GaI3 (cr) + 3CH3I (l)

Quantity Value Units Method Reference Comment
Δr-200.0 ± 8.4kJ/molRSCFowell and Mortimer, 1958Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970, 2.; MS

Gallium trimethyl (l) + 2Iodine (cr) = CH3GaI2 (cr) + 2Methane, iodo- (l)

By formula: C3H9Ga (l) + 2I2 (cr) = CH3GaI2 (cr) + 2CH3I (l)

Quantity Value Units Method Reference Comment
Δr-158.6 ± 4.2kJ/molRSCFowell and Mortimer, 1958Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970, 2.; MS

Hexamethylditin (l) + Iodine (cr) = 2C3H9ISn (l)

By formula: C6H18Sn2 (l) + I2 (cr) = 2C3H9ISn (l)

Quantity Value Units Method Reference Comment
Δr-184.1 ± 2.9kJ/molRSCPedley, Skinner, et al., 1957Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970, 2.; MS

1,2-Diiodobutane = 1-Butene + Iodine

By formula: C4H8I2 = C4H8 + I2

Quantity Value Units Method Reference Comment
Δr50.2 ± 6.3kJ/molCmCline and Kistiakowsky, 1937gas phase; Heat of formation derived by Cox and Pilcher, 1970; ALS

Tungsten, tricarbonyl(η5-2,4-cyclopentadien-1-yl)hydro- (cr) + Iodine (solution) = Hydrogen iodide (solution) + C8H5IO3W (solution)

By formula: C8H6O3W (cr) + I2 (solution) = HI (solution) + C8H5IO3W (solution)

Quantity Value Units Method Reference Comment
Δr-67.4 ± 3.8kJ/molRSCLandrum and Hoff, 1985solvent: Dichloromethane; MS

C15H12MoO3 (solution) + Iodine (solution) = C8H5IMoO3 (solution) + Benzene, (iodomethyl)- (solution)

By formula: C15H12MoO3 (solution) + I2 (solution) = C8H5IMoO3 (solution) + C7H7I (solution)

Quantity Value Units Method Reference Comment
Δr-120.5 ± 4.2kJ/molRSCNolan, de la Vega, et al., 1988solvent: Tetrahydrofuran; MS

C8H6MoO3 (cr) + Iodine (solution) = C8H5IMoO3 (solution) + Hydrogen iodide (solution)

By formula: C8H6MoO3 (cr) + I2 (solution) = C8H5IMoO3 (solution) + HI (solution)

Quantity Value Units Method Reference Comment
Δr-75.3 ± 2.5kJ/molRSCLandrum and Hoff, 1985solvent: Dichloromethane; MS

C10MnO10Re (solution) + Iodine (solution) = Rhenium, pentacarbonyliodo- (solution) + Manganese, pentacarbonyliodo- (solution)

By formula: C10MnO10Re (solution) + I2 (solution) = C5IO5Re (solution) + C5IMnO5 (solution)

Quantity Value Units Method Reference Comment
Δr-233. ± 13.kJ/molPCHarel and Adamson, 1986solvent: Cyclohexane; MS

C8H5MoNaO3 (solution) + Iodine (cr) = C8H5IMoO3 (solution) + Sodium iodide (cr)

By formula: C8H5MoNaO3 (solution) + I2 (cr) = C8H5IMoO3 (solution) + INa (cr)

Quantity Value Units Method Reference Comment
Δr-133.1 ± 5.4kJ/molRSCNolan, López de la Vega, et al., 1986solvent: Tetrahydrofuran; MS

1,2-Diiodotetrafluoroethane = Ethene, tetrafluoro- + Iodine

By formula: C2F4I2 = C2F4 + I2

Quantity Value Units Method Reference Comment
Δr69. ± 2.kJ/molEqkWu, Pickard, et al., 1975gas phase; Spectrophotometery at 298.15°K; ALS

2Propyl mercaptan + Iodine = 2Hydrogen iodide + Disulfide, dipropyl

By formula: 2C3H8S + I2 = 2HI + C6H14S2

Quantity Value Units Method Reference Comment
Δr-124.9kJ/molCmSunner, 1955liquid phase; solvent: Ethanol/water(90/10); ALS

21-Pentanethiol + Iodine = 2Hydrogen iodide + Disulfide, dipentyl

By formula: 2C5H12S + I2 = 2HI + C10H22S2

Quantity Value Units Method Reference Comment
Δr-124.9kJ/molCmSunner, 1955liquid phase; solvent: Ethanol/water(90/10); ALS

1,4-Butanedithiol + Iodine = 2Hydrogen iodide + 1,2-Dithiane

By formula: C4H10S2 + I2 = 2HI + C4H8S2

Quantity Value Units Method Reference Comment
Δr-123.2kJ/molCmSunner, 1955liquid phase; solvent: Ethanol/water(90/10); ALS

Octanoic acid, 6,8-dimercapto- + Iodine = 2Hydrogen iodide + Thioctic acid

By formula: C8H16O2S2 + I2 = 2HI + C8H14O2S2

Quantity Value Units Method Reference Comment
Δr-109.6kJ/molCmSunner, 1955liquid phase; solvent: Ethanol/water(90/10); ALS

C22H36Zr (solution) + 2Iodine (solution) = C20H30I2Zr (solution) + 2Methane, iodo- (solution)

By formula: C22H36Zr (solution) + 2I2 (solution) = C20H30I2Zr (solution) + 2CH3I (solution)

Quantity Value Units Method Reference Comment
Δr-292.9 ± 2.5kJ/molRSCSchock and Marks, 1988solvent: Toluene; MS

1,3-Propanedithiol + Iodine = 2Hydrogen iodide + 1,2-Dithiolane

By formula: C3H8S2 + I2 = 2HI + C3H6S2

Quantity Value Units Method Reference Comment
Δr-107.7kJ/molCmSunner, 1955liquid phase; solvent: Ethanol/water(90/10); ALS

C12H16Zr (solution) + 2Iodine (solution) = C10H10I2Zr (solution) + 2Methane, iodo- (solution)

By formula: C12H16Zr (solution) + 2I2 (solution) = C10H10I2Zr (solution) + 2CH3I (solution)

Quantity Value Units Method Reference Comment
Δr-291.2 ± 2.5kJ/molRSCSchock and Marks, 1988solvent: Toluene; MS

C22H30O2Zr (solution) + Iodine (solution) = C20H30I2Zr (solution) + 2Carbon monoxide (solution)

By formula: C22H30O2Zr (solution) + I2 (solution) = C20H30I2Zr (solution) + 2CO (solution)

Quantity Value Units Method Reference Comment
Δr-191.6 ± 1.7kJ/molRSCSchock and Marks, 1988solvent: Toluene; MS

C22H36Hf (solution) + 2Iodine (solution) = C20H30HfI2 (solution) + 2Methane, iodo- (solution)

By formula: C22H36Hf (solution) + 2I2 (solution) = C20H30HfI2 (solution) + 2CH3I (solution)

Quantity Value Units Method Reference Comment
Δr-265.3 ± 3.3kJ/molRSCSchock and Marks, 1988solvent: Toluene; MS

C37H30ClIrO3P2S (solution) + Iodine (solution) = C37H30ClI2IrOP2 (solution) + Sulfur dioxide (solution)

By formula: C37H30ClIrO3P2S (solution) + I2 (solution) = C37H30ClI2IrOP2 (solution) + O2S (solution)

Quantity Value Units Method Reference Comment
Δr-102.9 ± 0.4kJ/molRSCDrago, Nozari, et al., 1979solvent: Benzene; MS

Hydrogen iodide + Benzene, (iodomethyl)- = Toluene + Iodine

By formula: HI + C7H7I = C7H8 + I2

Quantity Value Units Method Reference Comment
Δr-33. ± 4.6kJ/molCmGraham, Nichol, et al., 1955liquid phase; solvent: p-Xylene; ALS

Hydrogen + 2Methane, iodo- = 2Methane + Iodine

By formula: H2 + 2CH3I = 2CH4 + I2

Quantity Value Units Method Reference Comment
Δr-126. ± 3.kJ/molChydCarson, Carter, et al., 1961liquid phase; solvent: Ether; ALS

C20H32Zr (solution) + Iodine (solution) = C20H30I2Zr (solution) + Hydrogen (g)

By formula: C20H32Zr (solution) + I2 (solution) = C20H30I2Zr (solution) + H2 (g)

Quantity Value Units Method Reference Comment
Δr-309.2 ± 3.3kJ/molRSCSchock and Marks, 1988solvent: Toluene; MS

C20H32Hf (solution) + Iodine (solution) = C20H30HfI2 (solution) + Hydrogen (g)

By formula: C20H32Hf (solution) + I2 (solution) = C20H30HfI2 (solution) + H2 (g)

Quantity Value Units Method Reference Comment
Δr-296.6 ± 2.9kJ/molRSCSchock and Marks, 1988solvent: Toluene; MS

C16H10O6W2 (cr) + Iodine (solution) = 2C8H5IO3W (solution)

By formula: C16H10O6W2 (cr) + I2 (solution) = 2C8H5IO3W (solution)

Quantity Value Units Method Reference Comment
Δr-146.4 ± 3.8kJ/molRSCLandrum and Hoff, 1985solvent: Dichloromethane; MS

C16H10Mo2O6 (cr) + Iodine (solution) = 2C8H5IMoO3 (solution)

By formula: C16H10Mo2O6 (cr) + I2 (solution) = 2C8H5IMoO3 (solution)

Quantity Value Units Method Reference Comment
Δr-133.1 ± 4.2kJ/molRSCLandrum and Hoff, 1985solvent: Dichloromethane; MS

Dimanganese decacarbonyl (solution) + Iodine (solution) = 2Manganese, pentacarbonyliodo- (solution)

By formula: C10Mn2O10 (solution) + I2 (solution) = 2C5IMnO5 (solution)

Quantity Value Units Method Reference Comment
Δr-187.9 ± 8.4kJ/molPCHarel and Adamson, 1986solvent: Cyclohexane; MS

Iodide + Iodine = (Iodide • Iodine)

By formula: I- + I2 = (I- • I2)

Quantity Value Units Method Reference Comment
Δr100.kJ/molN/ADowns and Adams, 1973gas phase; from ΔrH(f); M

Hydrogen + 2Ethane, iodo- = 2Ethane + Iodine

By formula: H2 + 2C2H5I = 2C2H6 + I2

Quantity Value Units Method Reference Comment
Δr-88.7 ± 3.3kJ/molChydAshcroft, Carson, et al., 1965liquid phase; ALS

2Propane, 2-iodo- + Mercury diiodide = C6H14Hg + 2Iodine

By formula: 2C3H7I + HgI2 = C6H14Hg + 2I2

Quantity Value Units Method Reference Comment
Δr242.3 ± 1.9kJ/molCmMortimer, Pritchard, et al., 1952liquid phase; ALS

2Propane, 1-iodo- + Mercury diiodide = C6H14Hg + 2Iodine

By formula: 2C3H7I + HgI2 = C6H14Hg + 2I2

Quantity Value Units Method Reference Comment
Δr215.7 ± 2.4kJ/molCmMortimer, Pritchard, et al., 1952liquid phase; ALS

Hydrogen iodide + Methylsulfenyliodide = Methanethiol + Iodine

By formula: HI + CH3IS = CH4S + I2

Quantity Value Units Method Reference Comment
Δr-12.0 ± 2.3kJ/molEqkShum and Benson, 1983gas phase; ALS

Acetone + Iodine = Hydrogen iodide + 1-iodoacetone

By formula: C3H6O + I2 = HI + C3H5IO

Quantity Value Units Method Reference Comment
Δr50.6 ± 5.0kJ/molEqkSolly, Golden, et al., 1970gas phase; ALS

Iodine + Bromotrifluoromethane = Methane, trifluoroiodo- + iodine bromide

By formula: I2 + CBrF3 = CF3I + BrI

Quantity Value Units Method Reference Comment
Δr40.0 ± 0.1kJ/molEqkLord, Goy, et al., 1967gas phase; ALS

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Taylor, Asmis, et al., 1999
Taylor, T.R.; Asmis, K.R.; Zanni, M.T.; Neumark, D.M., Characterization of the I-3 radical by anion photoelectron spectroscopy, J. Chem. Phys., 1999, 110, 16, 7607-7609, https://doi.org/10.1063/1.478672 . [all data]

Do, Klein, et al., 1997
Do, K.; Klein, T.P.; Pommerening, C.A.; Sunderlin, L.S., A New Flowing Afterglow-Guided Ion Beam Tandem Mass Spectrometer. Applications to the Thermochemistry of Polyiodide Ions, J. Am. Soc. Mass Spectrom., 1997, 8, 7, 688, https://doi.org/10.1016/S1044-0305(97)00116-5 . [all data]

Finch, Gates, et al., 1977
Finch, A.; Gates, P.N.; Peake, S.J., Thermochemistry of polyhalides. III. Cesium and rubidium tetrachloroiodates, J. Inorg. Nucl. Chem., 1977, 39, 2135. [all data]

Check, Faust, et al., 2001
Check, C.E.; Faust, T.O.; Bailey, J.M.; Wright, B.J.; Gilbert, T.M.; Sunderlin, L.S., Addition of Polarization and Diffuse Functions to the LANL2DZ Basis Set for P-Block Elements, J. Phys. Chem. A,, 2001, 105, 34, 8111, https://doi.org/10.1021/jp011945l . [all data]

Harel and Adamson, 1986
Harel, Y.; Adamson, A.W., J. Phys. Chem., 1986, 90, 6693. [all data]

Rodgers, Golden, et al., 1966
Rodgers, A.S.; Golden, D.M.; Benson, S.W., The thermochemistry of the gas phase equilibrium I2 + C3H6 = C3H5I + HI, J. Am. Chem. Soc., 1966, 88, 3194-3196. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Golden, Walsh, et al., 1965
Golden, D.M.; Walsh, R.; Benson, S.W., The thermochemistry of the gas phase equilibrium I2 + CH4 «=» CH3I + HI and the heat of formation of the methyl radical, J. Am. Chem. Soc., 1965, 87, 4053-4057. [all data]

Goy and Pritchard, 1965
Goy, C.A.; Pritchard, H.O., Kinetics and thermodynamics of the reaction between iodine and methane and the heat of formation of methyl iodide, J. Phys. Chem., 1965, 69, 3040-3041. [all data]

Nichol and Ubbelohde, 1952
Nichol, R.J.; Ubbelohde, A.R., A thermochemical evaluation of bond strengths in some carbon compounds. part II. Bond strengths based on the reaction CH3I + HI = CH4 + I2, J. Am. Chem. Soc., 1952, 415-421. [all data]

Diogo, Simoni, et al., 1993
Diogo, H.P.; Simoni, J.A.; Minas da Piedade, M.E.; Dias, A.R.; Martinho Simões, J.A., J. Am. Chem. Soc., 1993, 115, 2764. [all data]

Toscano, Seligson, et al., 1989
Toscano, P.J.; Seligson, A.L.; Curran, M.T.; Skrobutt, A.T.; Sonnenberger, D.C., Inorg. Chem., 1989, 28, 166; ibid. 1989. [all data]

Connor, Zafarani-Moattar, et al., 1982
Connor, J.A.; Zafarani-Moattar, M.T.; Bickerton, J.; El-Saied, N.I.; Suradi, S.; Carson, R.; Al Takkhin, G.; Skinner, H.A., Organomet., 1982, 1, 1166. [all data]

Abrams and Davis, 1954
Abrams, A.; Davis, T.W., Use of radioactive iodine to determine equilibrium constants in ethylene-iodine-1,2-diiodoethane systems, J. Am. Chem. Soc., 1954, 76, 5993-59. [all data]

Cutherbertson and Kistiakowsky, 1935
Cutherbertson, G.R.; Kistiakowsky, G.B., The thermal equilibrium between ethylene iodide, ethylene and iodine, J. Chem. Phys., 1935, 3, 631-634. [all data]

Lord, Goy, et al., 1967
Lord, A.; Goy, C.A.; Pritchard, H.O., The heats of formation of trifluoromethyl chloride and bromide, J. Phys. Chem., 1967, 71, 2705-2707. [all data]

Brennan and Ubbelohde, 1956
Brennan, D.; Ubbelohde, A.R., A thermochemical evaluation of bond strengths in some carbon compounds. Part IV. Bond-strength differences based on the reaction: RI + HI = RH + I2, where R = p-methoxyphenyl and cyclohexyl, J. Chem. Soc., 1956, 3011-3016. [all data]

Wu and Rodgers, 1974
Wu, E.; Rodgers, A.S., Thermochemistry of gas-phase equilibrium CF3CH3 + I2 = CF3CH2I + HI. The carbon-hydrogen bond dissociation energy in 1,1,1-trifluoroethane and the heat of formation of the 2,2,2-trifluoroethyl radical, J. Phys. Chem., 1974, 78, 2315-2317. [all data]

Buckley, Ford, et al., 1980
Buckley, G.S.; Ford, W.G.F.; Rodgers, A.S., The thermochemistry of the gas phase reaction: CF3CH2Br + I2 = CF3CH2I + IBr. Polarity effects in thermochemistry, Thermochim. Acta, 1980, 42, 349-355. [all data]

Kolesov and Papina, 1983
Kolesov, V.P.; Papina, T.S., Thermochemistry of Haloethanes, Russ. Chem. Rev., 1983, 52, 425. [all data]

Hartley, Pritchard, et al., 1950
Hartley, K.; Pritchard, H.O.; Skinner, H.A., Thermochemistry of metallic alkyls. III.?mercury dimethyl and mercury methyl halides, Trans. Faraday Soc., 1950, 46, 1019, https://doi.org/10.1039/tf9504601019 . [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Cox and Pilcher, 1970, 2
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds in Academic Press, New York, 1970. [all data]

Adamson, Vogler, et al., 1978
Adamson, A.W.; Vogler, A.; Kunkely, H.; Wachter, R., J. Am. Chem. Soc., 1978, 100, 1298. [all data]

Fowell and Mortimer, 1958
Fowell, P.A.; Mortimer, C.T., J. Chem. Soc., 1958, 3734.. [all data]

Pedley, Skinner, et al., 1957
Pedley, J.B.; Skinner, H.A.; Chernick, C.L., Thermochemistry of metallic alkyls. Part 8.?Tin tetramethyl, and hexamethyl distannane, Trans. Faraday Soc., 1957, 53, 1612, https://doi.org/10.1039/tf9575301612 . [all data]

Cline and Kistiakowsky, 1937
Cline, J.E.; Kistiakowsky, G.B., The gaseous equilibrium of 1,2-diiodobutane, butene-1 and iodine, J. Chem. Phys., 1937, 5, 990. [all data]

Landrum and Hoff, 1985
Landrum, J.T.; Hoff, C.D., J. Organometal. Chem., 1985, 282, 215. [all data]

Nolan, de la Vega, et al., 1988
Nolan, S.P.; de la Vega, R.L.; Mukerjee, S.L.; Gonzalez, A.A.; Zhang, K.; Hoff, C., Polyhedron, 1988, 7, 1491. [all data]

Nolan, López de la Vega, et al., 1986
Nolan, S.P.; López de la Vega, R.; Hoff, C.D., J. Organometal. Chem., 1986, 315, 187. [all data]

Wu, Pickard, et al., 1975
Wu, E.C.; Pickard, J.M.; Rodgers, A.S., Thermochemistry of the gas-phase reaction tetrafluoroethylene + iodine = 1,2-diiodoperfluoroethane. Heat of formation of 1,2-diiodoperfluoroethane and of iodoperfluoroethane, J. Phys. Chem., 1975, 79, 1078-1081. [all data]

Sunner, 1955
Sunner, S., Strain in 6,8-thioctic acid, Nature (London), 1955, 176, 217. [all data]

Schock and Marks, 1988
Schock, L.E.; Marks, T.J., J. Am. Chem. Soc., 1988, 110, 7701. [all data]

Drago, Nozari, et al., 1979
Drago, R.S.; Nozari, M.S.; Klinger, R.J.; Chamberlain, C.S., Inorg. Chem., 1979, 18, 1254. [all data]

Graham, Nichol, et al., 1955
Graham, W.S.; Nichol, R.J.; Ubbelohde, A.R., A thermochemical evaluation of bond strengths in some carbon compounds. Part III. Bond strengths based on the reactions: (a) Ph·CH2I + HI=Ph·CH3 + I2 and (b) PhI + HI=PhH + I2, J. Chem. Soc., 1955, 115-121. [all data]

Carson, Carter, et al., 1961
Carson, A.S.; Carter, W.; Pedley, J.B., The thermochemistry of reductions caused by lithium aluminium hydride I. The C-I bond dissociation energy in CH3I, Proc. Roy. Soc. London A, 1961, 260, 550-557. [all data]

Downs and Adams, 1973
Downs, A.J.; Adams, G.J., Comprehensive Inorganic Chemistry, J. C. Bailar, H. J. Emeleus, R. Nyholm and A. F. Trotman - Dickerson, ed(s)., Pergamon Press, New York, 1973, 1543. [all data]

Ashcroft, Carson, et al., 1965
Ashcroft, S.J.; Carson, A.S.; Carter, W.; Laye, P.G., Thermochemistry of reductions caused by lithium aluminium hydride. Part 3.- The C-halogen bond dissociation energies in ethyl iodine and ethyl bromide, Trans. Faraday Soc., 1965, 61, 225-229. [all data]

Mortimer, Pritchard, et al., 1952
Mortimer, C.T.; Pritchard, H.O.; Skinner, H.A., Thermochemistry of metallic alkyls. Part V - Mercury di-propyl and mercury di-isopropyl, Trans. Faraday Soc., 1952, 48, 220-229. [all data]

Shum and Benson, 1983
Shum, L.G.S.; Benson, S.W., Thermochemnistry and kinetics of the reaction of methyl mercaptan with iodine, Int. J. Chem. Kinet., 1983, 15, 433-453. [all data]

Solly, Golden, et al., 1970
Solly, R.K.; Golden, D.M.; Benson, S.W., Thermochemical properties of iodoacetone. Intramolecular electrostatic interactions in polar molecules, J. Am. Chem. Soc., 1970, 92, 4653-4656. [all data]


Notes

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