Methane, nitro-
- Formula: CH3NO2
- Molecular weight: 61.0400
- IUPAC Standard InChIKey: LYGJENNIWJXYER-UHFFFAOYSA-N
- CAS Registry Number: 75-52-5
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Nitromethane; Nitrocarbol; CH3NO2; Nitrometan; UN 1261; NM; NSC 428
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Gas phase thermochemistry data
Go To: Top, Phase change data, Reaction thermochemistry data, Henry's Law data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°gas | -19.3 ± 0.3 | kcal/mol | Ccb | Knobel, Miroshnichenko, et al., 1971 |
Phase change data
Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Henry's Law data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tboil | 374.1 ± 0.8 | K | AVG | N/A | Average of 17 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
Tfus | 244.6 | K | N/A | Toops, 1956 | Uncertainty assigned by TRC = 0.05 K; TRC |
Tfus | 244.55 | K | N/A | Timmermans, 1952 | Uncertainty assigned by TRC = 0.4 K; TRC |
Tfus | 243.11 | K | N/A | Dreisbach and Martin, 1949 | Uncertainty assigned by TRC = 0.05 K; TRC |
Tfus | 244. | K | N/A | Joukovsky, 1934 | Uncertainty assigned by TRC = 2. K; TRC |
Tfus | 243.95 | K | N/A | Timmermans, 1921 | Uncertainty assigned by TRC = 0.3 K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
Ttriple | 244.77 | K | N/A | Jones and Giauque, 1947 | Uncertainty assigned by TRC = 0.02 K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
Tc | 588. | K | N/A | Majer and Svoboda, 1985 | |
Tc | 588. | K | N/A | Griffin, 1949 | Uncertainty assigned by TRC = 3. K; taken from a plot of total P vs 1/T; TRC |
Quantity | Value | Units | Method | Reference | Comment |
Pc | 57.93 | atm | N/A | Ambrose, Counsell, et al., 1978 | Uncertainty assigned by TRC = 0.5788 atm; TRC |
Pc | 62.27 | atm | N/A | Griffin, 1949 | Uncertainty assigned by TRC = 1.0207 atm; from value pf vapor pressure at Tc, based on unpublished measurements; TRC |
Quantity | Value | Units | Method | Reference | Comment |
ρc | 5.77 | mol/l | N/A | Griffin, 1949 | Uncertainty assigned by TRC = 0.05 mol/l; deduced from a series of P vs 1/T plots for various sample sizes in a fixed volume bomb; TRC |
Quantity | Value | Units | Method | Reference | Comment |
ΔvapH° | 9.0 ± 0.6 | kcal/mol | AVG | N/A | Average of 7 values; Individual data points |
Enthalpy of vaporization
ΔvapH (kcal/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
8.124 | 374.4 | N/A | Majer and Svoboda, 1985 | |
9.1470 | 298.15 | N/A | Jones and Giauque, 1947, 2 | P = 4.89 kPA; DH |
8.41 | 420. | A | Stephenson and Malanowski, 1987 | Based on data from 405. to 476. K. See also Berman and West, 1967.; AC |
8.80 | 343. | A | Stephenson and Malanowski, 1987 | Based on data from 328. to 410. K. See also McCullough, Scott, et al., 1954.; AC |
8.89 ± 0.02 | 318. | C | McCullough, Scott, et al., 1954 | AC |
8.68 ± 0.02 | 335. | C | McCullough, Scott, et al., 1954 | AC |
8.41 ± 0.02 | 353. | C | McCullough, Scott, et al., 1954 | AC |
8.13 ± 0.02 | 374. | C | McCullough, Scott, et al., 1954 | AC |
Enthalpy of vaporization
ΔvapH =
A exp(-βTr) (1 − Tr)β
ΔvapH =
Enthalpy of vaporization (at saturation pressure)
(kcal/mol)
Tr = reduced temperature (T / Tc)
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Temperature (K) | A (kcal/mol) | β | Tc (K) | Reference | Comment |
---|---|---|---|---|---|
318. to 374. | 12.75 | 0.2732 | 588. | Majer and Svoboda, 1985 |
Entropy of vaporization
ΔvapS (cal/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
30.679 | 298.15 | Jones and Giauque, 1947, 2 | P; DH |
Antoine Equation Parameters
log10(P) = A − (B / (T + C))
P = vapor pressure (atm)
T = temperature (K)
View plot Requires a JavaScript / HTML 5 canvas capable browser.
Temperature (K) | A | B | C | Reference | Comment |
---|---|---|---|---|---|
405.0 to 476. | 4.1078 | 1229.574 | -76.221 | Berman and West, 1967 | Coefficents calculated by NIST from author's data. |
328.86 to 409.6 | 4.39971 | 1446.196 | -45.633 | McCullough, Scott, et al., 1954 | Coefficents calculated by NIST from author's data. |
Enthalpy of fusion
ΔfusH (kcal/mol) | Temperature (K) | Reference | Comment |
---|---|---|---|
2.319 | 244.77 | Jones and Giauque, 1947, 2 | DH |
2.3 | 244.8 | Domalski and Hearing, 1996 | AC |
Entropy of fusion
ΔfusS (cal/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
9.474 | 244.77 | Jones and Giauque, 1947, 2 | DH |
Reaction thermochemistry data
Go To: Top, Gas phase thermochemistry data, Phase change data, Henry's Law data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
CH2NO2- + =
By formula: CH2NO2- + H+ = CH3NO2
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 358.0 ± 5.0 | kcal/mol | D-EA | Metz, Cyr, et al., 1991 | gas phase; B |
ΔrH° | 356.4 ± 2.2 | kcal/mol | G+TS | Bartmess, Scott, et al., 1979 | gas phase; value altered from reference due to change in acidity scale; B |
ΔrH° | 357.4 ± 2.9 | kcal/mol | G+TS | Cumming and Kebarle, 1978 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 349.7 ± 2.0 | kcal/mol | IMRE | Bartmess, Scott, et al., 1979 | gas phase; value altered from reference due to change in acidity scale; B |
ΔrG° | 350.7 ± 2.0 | kcal/mol | IMRE | Cumming and Kebarle, 1978 | gas phase; B |
ΔrG° | 350.7 ± 2.0 | kcal/mol | IMRE | MacKay and Bohme, 1978 | gas phase; EA: < NO2; B |
By formula: Cl- + CH3NO2 = (Cl- • CH3NO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 15.60 ± 0.60 | kcal/mol | TDAs | Wincel, 2003 | gas phase; B |
ΔrH° | 16.70 ± 0.10 | kcal/mol | TDAs | Sieck, 1985 | gas phase; B,M |
ΔrH° | 16.3 ± 3.0 | kcal/mol | IMRB | Riveros, Breda, et al., 1973 | gas phase; Anchored: Larson and McMahon, 1984; B |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 17.1 | cal/mol*K | PHPMS | Sieck, 1985 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 9.20 | kcal/mol | TDAs | Wincel, 2003 | gas phase; B |
ΔrG° | 11.60 ± 0.10 | kcal/mol | TDAs | Sieck, 1985 | gas phase; B |
By formula: (Cl- • CH3NO2) + CH3NO2 = (Cl- • 2CH3NO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 13.00 ± 0.50 | kcal/mol | TDAs | Wincel, 2003 | gas phase; B |
ΔrH° | 13.10 ± 0.10 | kcal/mol | TDAs | Sieck, 1985 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 18.3 | cal/mol*K | PHPMS | Sieck, 1985 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 5.70 | kcal/mol | TDAs | Wincel, 2003 | gas phase; B |
ΔrG° | 7.60 ± 0.30 | kcal/mol | TDAs | Sieck, 1985 | gas phase; B |
By formula: NO2- + CH3NO2 = (NO2- • CH3NO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 14.50 ± 0.50 | kcal/mol | TDAs | Wincel, 2003 | gas phase; B |
ΔrH° | 14.30 ± 0.10 | kcal/mol | TDAs | Sieck, 1985 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 15.5 | cal/mol*K | PHPMS | Sieck, 1985 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 7.80 | kcal/mol | TDAs | Wincel, 2003 | gas phase; B |
ΔrG° | 9.70 ± 0.20 | kcal/mol | TDAs | Sieck, 1985 | gas phase; B |
By formula: C6H7N+ + CH3NO2 = (C6H7N+ • CH3NO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 14.4 | kcal/mol | PHPMS | Meot-Ner (Mautner) and El-Shall, 1986 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 18. | cal/mol*K | N/A | Meot-Ner (Mautner) and El-Shall, 1986 | gas phase; Entropy change calculated or estimated; M |
Free energy of reaction
ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
8.2 | 343. | PHPMS | Meot-Ner (Mautner) and El-Shall, 1986 | gas phase; Entropy change calculated or estimated; M |
(CH3NO2- • ) +
= (CH3NO2- • 2
)
By formula: (CH3NO2- • CH3NO2) + CH3NO2 = (CH3NO2- • 2CH3NO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 13. ± 35. | kcal/mol | N/A | Compton, Carman Jr., et al., 1996 | gas phase; shift in electron detachment from less solvated ion; B |
ΔrH° | 12.80 ± 0.30 | kcal/mol | TDAs | Wincel, 2003 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 5.90 | kcal/mol | TDAs | Wincel, 2003 | gas phase; B |
By formula: CH6N+ + CH3NO2 = (CH6N+ • CH3NO2)
Bond type: Hydrogen bonds of the type NH+-O between organics
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 20.5 | kcal/mol | PHPMS | Meot-Ner, 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 23.0 | cal/mol*K | PHPMS | Meot-Ner, 1984 | gas phase; M |
By formula: CH2NO2- + CH3NO2 = C2H5N2O4-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 15.90 ± 0.50 | kcal/mol | TDAs | Wincel, 2003 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 8.40 | kcal/mol | TDAs | Wincel, 2003 | gas phase; B |
C3H9N3O6- + 3 = C4H12N4O8-
By formula: C3H9N3O6- + 3CH3NO2 = C4H12N4O8-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 10.40 ± 0.50 | kcal/mol | TDAs | Wincel, 2003 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 3.80 | kcal/mol | TDAs | Wincel, 2003 | gas phase; B |
By formula: C2H5N2O4- + 2CH3NO2 = C3H8N3O6-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 13.30 ± 0.70 | kcal/mol | TDAs | Wincel, 2003 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 5.80 | kcal/mol | TDAs | Wincel, 2003 | gas phase; B |
C3H8N3O6- + 3 = C4H11N4O8-
By formula: C3H8N3O6- + 3CH3NO2 = C4H11N4O8-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 12.60 ± 0.50 | kcal/mol | TDAs | Wincel, 2003 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 3.10 | kcal/mol | TDAs | Wincel, 2003 | gas phase; B |
C4H11N4O8- + 4 = C5H14N5O10-
By formula: C4H11N4O8- + 4CH3NO2 = C5H14N5O10-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 11.40 ± 0.20 | kcal/mol | TDAs | Wincel, 2003 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 1.60 | kcal/mol | TDAs | Wincel, 2003 | gas phase; B |
By formula: C2H6N2O6- + 2CH3NO2 = C3H9N3O8-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 10.90 ± 0.60 | kcal/mol | TDAs | Wincel, 2003 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 3.70 | kcal/mol | TDAs | Wincel, 2003 | gas phase; B |
C4H12N4O8- + 4 = C5H15N5O10-
By formula: C4H12N4O8- + 4CH3NO2 = C5H15N5O10-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 8.40 ± 0.20 | kcal/mol | TDAs | Wincel, 2003 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 2.40 | kcal/mol | TDAs | Wincel, 2003 | gas phase; B |
C3H9N3O8- + 3 = C4H12N4O10-
By formula: C3H9N3O8- + 3CH3NO2 = C4H12N4O10-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 9.50 ± 0.90 | kcal/mol | TDAs | Wincel, 2003 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 2.30 | kcal/mol | TDAs | Wincel, 2003 | gas phase; B |
By formula: CH3N2O4- + 2CH3NO2 = C2H6N3O6-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 12.40 ± 0.50 | kcal/mol | N/A | Wincel, 2003 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 5.40 | kcal/mol | TDAs | Wincel, 2003 | gas phase; B |
C2H6ClN2O4- + 3 = C3H9ClN3O6-
By formula: C2H6ClN2O4- + 3CH3NO2 = C3H9ClN3O6-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 11.10 ± 0.50 | kcal/mol | N/A | Wincel, 2003 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 3.70 | kcal/mol | TDAs | Wincel, 2003 | gas phase; B |
By formula: C11H10+ + CH3NO2 = (C11H10+ • CH3NO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 11.2 | kcal/mol | PHPMS | El-Shall and Meot-Ner (Mautner), 1987 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 22.3 | cal/mol*K | PHPMS | El-Shall and Meot-Ner (Mautner), 1987 | gas phase; M |
By formula: C2H6N3O6- + 3CH3NO2 = C3H9N4O8-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 11.30 ± 0.80 | kcal/mol | N/A | Wincel, 2003 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 3.30 | kcal/mol | TDAs | Wincel, 2003 | gas phase; B |
C3H9N4O8- + 4 = C4H12N5O10-
By formula: C3H9N4O8- + 4CH3NO2 = C4H12N5O10-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 9.70 ± 0.30 | kcal/mol | N/A | Wincel, 2003 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 1.60 | kcal/mol | TDAs | Wincel, 2003 | gas phase; B |
By formula: C5H10NO2+ + CH3NO2 = (C5H10NO2+ • CH3NO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 17.5 | kcal/mol | HPMS | Meot-Ner and Field, 1974 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 21.6 | cal/mol*K | HPMS | Meot-Ner and Field, 1974 | gas phase; M |
By formula: C5H12NO2+ + CH3NO2 = (C5H12NO2+ • CH3NO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 19.8 | kcal/mol | HPMS | Meot-Ner and Field, 1974 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 27.8 | cal/mol*K | HPMS | Meot-Ner and Field, 1974 | gas phase; M |
C3H9ClN3O6- + 4 = C4H12ClN4O8-
By formula: C3H9ClN3O6- + 4CH3NO2 = C4H12ClN4O8-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 9.6 ± 1.0 | kcal/mol | N/A | Wincel, 2003 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 2.70 | kcal/mol | TDAs | Wincel, 2003 | gas phase; B |
C4H12N4O10- + 4 = C5H15N5O12-
By formula: C4H12N4O10- + 4CH3NO2 = C5H15N5O12-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 6.00 | kcal/mol | TDAs | Wincel, 2003 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 0.60 | kcal/mol | TDAs | Wincel, 2003 | gas phase; B |
By formula: Li+ + CH3NO2 = (Li+ • CH3NO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 39.5 | kcal/mol | ICR | Staley and Beauchamp, 1975 | gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970; M |
By formula: CH3NO2- + CH3NO2 = (CH3NO2- • CH3NO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 15.20 ± 0.20 | kcal/mol | N/A | Compton, Carman Jr., et al., 1996 | gas phase; Shift in electron detachment from non-solvated ion; B |
+
= CH3BrNO2-
By formula: Br- + CH3NO2 = CH3BrNO2-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrG° | 9.6 ± 2.0 | kcal/mol | IMRE | Tanabe, Morgon, et al., 1996 | gas phase; Anchored to H2O..Br- of Hiraoka, Mizure, et al., 19882; B |
By formula: I- + CH3NO2 = (I- • CH3NO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 12.2 ± 1.0 | kcal/mol | TDAs | Caldwell, Masucci, et al., 1989 | gas phase; B,M |
Henry's Law data
Go To: Top, Gas phase thermochemistry data, Phase change data, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Rolf Sander
Henry's Law constant (water solution)
kH(T) = k°H exp(d(ln(kH))/d(1/T) ((1/T) - 1/(298.15 K)))
k°H = Henry's law constant for solubility in water at 298.15 K (mol/(kg*bar))
d(ln(kH))/d(1/T) = Temperature dependence constant (K)
k°H (mol/(kg*bar)) | d(ln(kH))/d(1/T) (K) | Method | Reference | Comment |
---|---|---|---|---|
3.6 | Q | N/A | missing citation give several references for the Henry's law constants but don't assign them to specific species. | |
35. | X | N/A | Value given here as quoted by missing citation. | |
45. | M | N/A |
References
Go To: Top, Gas phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Knobel, Miroshnichenko, et al., 1971
Knobel, Y.K.; Miroshnichenko, E.A.; Lebedev, Y.A.,
Heats of combustion of nitromethane and dinitromethane: enthalpies of formation of nitromethyl radicals and energies of dissociation of bonds in nitro derivatives of methane,
Bull. Acad. Sci. USSR, Div. Chem. Sci., 1971, 425-428. [all data]
Toops, 1956
Toops, E.E.,
Physical Properties of High Purity Nitroparaffins,
J. Phys. Chem., 1956, 60, 304-6. [all data]
Timmermans, 1952
Timmermans, J.,
Freezing points of organic compounds. VVI New determinations.,
Bull. Soc. Chim. Belg., 1952, 61, 393. [all data]
Dreisbach and Martin, 1949
Dreisbach, R.R.; Martin, R.A.,
Physical Data on Some Organic Compounds,
Ind. Eng. Chem., 1949, 41, 2875-8. [all data]
Joukovsky, 1934
Joukovsky, N.I.,
Experimental Study of the Theory of Concentrated Solutions. XI. Thermodynamic Properties of Concentrated Solutions of Aliphatic Organic Compounds Containing Nitrogen.,
Bull. Soc. Chim. Belg., 1934, 43, 397. [all data]
Timmermans, 1921
Timmermans, J.,
The Freezing Points of Organic Substances IV. New Exp. Determinations,
Bull. Soc. Chim. Belg., 1921, 30, 62. [all data]
Jones and Giauque, 1947
Jones, W.M.; Giauque, W.F.,
The Entropy of Nitromethane. Heat Capacity of Solid and Liquid. Vapor Pressure, Heats of Fusion and Vaporizaion,
J. Am. Chem. Soc., 1947, 69, 983-7. [all data]
Majer and Svoboda, 1985
Majer, V.; Svoboda, V.,
Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]
Griffin, 1949
Griffin, D.N.,
The Critical Point of Nitromethane.,
J. Am. Chem. Soc., 1949, 71, 1423. [all data]
Ambrose, Counsell, et al., 1978
Ambrose, D.; Counsell, J.F.; Hicks, C.P.,
The correlation and estimation of vapour pressures: II a new procedure for estimation and extrapolation,
J. Chem. Thermodyn., 1978, 10, 771. [all data]
Jones and Giauque, 1947, 2
Jones, W.M.; Giauque, W.F.,
The entropy of nitromethane. Heat capacity of solid and liquid. Vapor pressure, heats of fusion and vaporization,
J. Am. Chem. Soc., 1947, 69, 983-987. [all data]
Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw,
Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2
. [all data]
Berman and West, 1967
Berman, Horace A.; West, Estal Dale,
Density and vapor pressure of nitromethane 26.degree. to 200.degree.,
J. Chem. Eng. Data, 1967, 12, 2, 197-199, https://doi.org/10.1021/je60033a011
. [all data]
McCullough, Scott, et al., 1954
McCullough, J.P.; Scott, D.W.; Pennington, R.E.; Hossenlopp, I.A.; Waddington, Guy,
Nitromethane: The Vapor Heat Capacity, Heat of Vaporization, Vapor Pressure and Gas Imperfection; the Chemical Thermodynamic Properties from 0 to 1500°K.,
J. Am. Chem. Soc., 1954, 76, 19, 4791-4796, https://doi.org/10.1021/ja01648a008
. [all data]
Domalski and Hearing, 1996
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Notes
Go To: Top, Gas phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, References
- Symbols used in this document:
Pc Critical pressure T Temperature Tboil Boiling point Tc Critical temperature Tfus Fusion (melting) point Ttriple Triple point temperature d(ln(kH))/d(1/T) Temperature dependence parameter for Henry's Law constant k°H Henry's Law constant at 298.15K ΔfH°gas Enthalpy of formation of gas at standard conditions ΔfusH Enthalpy of fusion ΔfusS Entropy of fusion ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions ΔrS° Entropy of reaction at standard conditions ΔvapH Enthalpy of vaporization ΔvapH° Enthalpy of vaporization at standard conditions ΔvapS Entropy of vaporization ρc Critical density - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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