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Titanium tetrachloride

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil407.95KN/ANeff and Hickman, 1955Uncertainty assigned by TRC = 1. K; not certain that this was measured; TRC
Quantity Value Units Method Reference Comment
Tfus248.64KN/ANeff and Hickman, 1955Uncertainty assigned by TRC = 0.2 K; TRC
Quantity Value Units Method Reference Comment
Tc639.1KN/ATeja and Anselme, 1990Uncertainty assigned by TRC = 0.6 K; TRC
Quantity Value Units Method Reference Comment
rhoc3.01mol/lN/ATeja and Anselme, 1990Uncertainty assigned by TRC = 0.04 mol/l; TRC

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
37.5265.N/ALuchinskii, 1966Based on data from 250. - 423. K.; AC
37.9378.N/APike and Foster, 1959Based on data from 363. - 415. K.; AC
39.8335.ISch«65533»fer and Zeppernick, 1953Based on data from 313. - 357. K.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
249.93 - 423.4.849691990.2352.0Luchinskii, 1966, 2Coefficents calculated by NIST from author's data.

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Neff and Hickman, 1955
Neff, J.A.; Hickman, J.B., Total Pressure of Certain Binary Liquid Mixtures, J. Phys. Chem., 1955, 59, 42-5. [all data]

Teja and Anselme, 1990
Teja, A.S.; Anselme, M.J., The critical properties of thermally stable and unstable fluids. II. 1986 results, AIChE Symp. Ser., 1990, 86, 279, 122-7. [all data]

Luchinskii, 1966
Luchinskii, G.P., Zh. Fiz. Khim., 1966, 40, 3, 593. [all data]

Pike and Foster, 1959
Pike, F.P.; Foster, C.T., Vapor Pressure and Boiling Point of Titanium Tetrachloride., J. Chem. Eng. Data, 1959, 4, 4, 305-306, https://doi.org/10.1021/je60004a006 . [all data]

Sch«65533»fer and Zeppernick, 1953
Sch«65533»fer, Harald; Zeppernick, Friedrich, Die S«65533»ttigungsdrucke «65533»ber fl«65533»ssigem Titan(IV)-chlorid, Z. Anorg. Allg. Chem., 1953, 272, 5-6, 274-278, https://doi.org/10.1002/zaac.19532720506 . [all data]

Luchinskii, 1966, 2
Luchinskii, G.P., Physico-Chemical Study of Titanium Halides. 1. Parameters of Phase Transitions of Titanium Tetrachloride, Zh. Fiz. Khim., 1966, 40, 593-598. [all data]


Notes

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