Lithium bromide

• Formula: BrLi
• Molecular weight: 86.845
• IUPAC Standard InChI: InChI=1S/BrH.Li/h1H;/q;+1/p-1 Copy

  
• IUPAC Standard InChIKey: AMXOYNBUYSYVKV-UHFFFAOYSA-M Copy
• CAS Registry Number: 7550-35-8
• Chemical structure:
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• Information on this page:
  • Reaction thermochemistry data
  • References
  • Notes
• Other data available:
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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

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Individual Reactions

C₄H₉Li (l) +  (g) =  (l) +  (cr)

By formula: C₄H₉Li (l) + HBr (g) = C₄H₁₀ (l) + BrLi (cr)

 (g) +  (cr) =  (g) +  (cr)

By formula: HBr (g) + CH₃Li (cr) = CH₄ (g) + BrLi (cr)

 (g) +  (cr) =  (g) +  (cr)

By formula: HBr (g) + C₂H₅Li (cr) = C₂H₆ (g) + BrLi (cr)

 (g) + C₄H₉Li (l) =  (l) +  (cr)

By formula: HBr (g) + C₄H₉Li (l) = C₄H₁₀ (l) + BrLi (cr)

 + C₄H₉Li =  + 

By formula: C₇H₇Br + C₄H₉Li = C₁₁H₁₆ + BrLi

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Holm, 1974
Holm, T., J. Organometal. Chem., 1974, 77, 27. [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Liebman, Martinho Simões, et al., 1995
Liebman, J.F.; Martinho Simões, J.A.; Slayden, S.W., In Lithium Chemistry: A Theoretical and Experimental Overview Wiley: New York, Sapse, A.-M.; Schleyer, P. von Ragué, ed(s)., 1995. [all data]

Fowell and Mortimer, 1961
Fowell, P.A.; Mortimer, C.T., 735. Heats of formation and bond energies. Part V. n-Butyl-lithium, J. Chem. Soc., 1961, 3793-3796. [all data]

Notes

Go To: Top, Reaction thermochemistry data, References

• Symbols used in this document:
  

  ΔrH°	Enthalpy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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