Fluorodichloromethane
- Formula: CHCl2F
- Molecular weight: 102.923
- IUPAC Standard InChIKey: UMNKXPULIDJLSU-UHFFFAOYSA-N
- CAS Registry Number: 75-43-4
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Methane, dichlorofluoro-; Algofrene Type 5; Arcton 7; Dichlorofluoromethane; Dichloromonofluoromethane; F 21; Freon F 21; Freon 21; FC 21; Genetron 21; Monofluorodichloromethane; CHFCl2; R 21; Dwuchlorofluorometan; UN 1029; CHCl2F; Refrigerant 21; Halon 112; Fluorocarbon-21; R 21 (refrigerant)
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Phase change data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tboil | 282.0 | K | N/A | PCR Inc., 1990 | BS |
Quantity | Value | Units | Method | Reference | Comment |
Tc | 451.65 | K | N/A | Benning and McHarness, 1940 | Uncertainty assigned by TRC = 0.4 K; visual observation of the meniscus; TRC |
Quantity | Value | Units | Method | Reference | Comment |
ρc | 5.07 | mol/l | N/A | Benning and McHarness, 1940 | Uncertainty assigned by TRC = 0.02 mol/l; by extrapolation of rectilinear diameter to critical temp.; TRC |
Enthalpy of vaporization
ΔvapH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
26.1 | 267. | A | Stephenson and Malanowski, 1987 | Based on data from 225. to 282. K.; AC |
25.3 | 294. | A | Stephenson and Malanowski, 1987 | Based on data from 279. to 344. K.; AC |
24.2 | 356. | A | Stephenson and Malanowski, 1987 | Based on data from 341. to 399. K.; AC |
24.1 | 412. | A | Stephenson and Malanowski, 1987 | Based on data from 397. to 450. K.; AC |
26.2 | 267. | N/A | Stull, 1947 | Based on data from 181. to 282. K.; AC |
36.7 | 259. | N/A | Benning and McHarness, 1940, 2 | Based on data from 244. to 317. K.; AC |
Antoine Equation Parameters
log10(P) = A − (B / (T + C))
P = vapor pressure (bar)
T = temperature (K)
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Temperature (K) | A | B | C | Reference | Comment |
---|---|---|---|---|---|
181.8 to 282.1 | 4.10065 | 996.267 | -38.978 | Stull, 1947 | Coefficents calculated by NIST from author's data. |
282.1 to 450.7 | 4.29721 | 1105.42 | -24.479 | Stull, 1947 | Coefficents calculated by NIST from author's data. |
References
Go To: Top, Phase change data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
PCR Inc., 1990
PCR Inc.,
Research Chemicals Catalog 1990-1991, PCR Inc., Gainesville, FL, 1990, 1. [all data]
Benning and McHarness, 1940
Benning, A.F.; McHarness, R.C.,
Thermodynamic Properties of Fluorochloromethanes and -Ethanes densities and critical constants of three fluorochloromethanes and trifluorotrichloroethane,
Ind. Eng. Chem., 1940, 32, 814. [all data]
Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw,
Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2
. [all data]
Stull, 1947
Stull, Daniel R.,
Vapor Pressure of Pure Substances. Organic and Inorganic Compounds,
Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022
. [all data]
Benning and McHarness, 1940, 2
Benning, A.F.; McHarness, R.C.,
Thermodynamic Properties of Fluorochloromethanes and -Ethanes Vapor Pressure of Three Fluorochloromethanes and Trifluorotichloroethane,
Ind. Eng. Chem., 1940, 32, 4, 497-499, https://doi.org/10.1021/ie50364a011
. [all data]
Notes
Go To: Top, Phase change data, References
- Symbols used in this document:
Tboil Boiling point Tc Critical temperature ΔvapH Enthalpy of vaporization ρc Critical density - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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