Propanamide, 2,2-dimethyl-
- Formula: C5H11NO
- Molecular weight: 101.1469
- IUPAC Standard InChIKey: XIPFMBOWZXULIA-UHFFFAOYSA-N
- CAS Registry Number: 754-10-9
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Pivalamide; Trimethylacetamide
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Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tboil | 485.2 | K | N/A | Aldrich Chemical Company Inc., 1990 | BS |
Quantity | Value | Units | Method | Reference | Comment |
ΔsubH° | 89. ± 2.0 | kJ/mol | TE | Brunetti, Gatta, et al., 2000 | Based on data from 298. to 359. K.; AC |
ΔsubH° | 86.6 ± 0.4 | kJ/mol | C | Abboud, Jimenez, et al., 1989 | ALS |
ΔsubH° | 86.6 ± 0.4 | kJ/mol | N/A | Abboud, Jimenez, et al., 1989 | Based on data from 288. to 306. K.; AC |
Enthalpy of sublimation
ΔsubH (kJ/mol) | Temperature (K) | Reference | Comment |
---|---|---|---|
86.600 | 298.15 | Abboud, Jimenez, et al., 1989 | DH |
Entropy of sublimation
ΔsubS (J/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
290.5 | 298.15 | Abboud, Jimenez, et al., 1989 | DH |
Enthalpy of fusion
ΔfusH (kJ/mol) | Temperature (K) | Reference | Comment |
---|---|---|---|
24.1 | 425.4 | Abate, Badea, et al., 2008 | AC |
References
Go To: Top, Phase change data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc.,
Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]
Brunetti, Gatta, et al., 2000
Brunetti, Bruno; Gatta, Giuseppe Della; Piacente, Vincenzo,
Enthalpies and Entropies of Sublimation of Some Primary Alkylamides,
J. Chem. Eng. Data, 2000, 45, 2, 237-241, https://doi.org/10.1021/je9902701
. [all data]
Abboud, Jimenez, et al., 1989
Abboud, J.-L.M.; Jimenez, P.; Roux, M.V.; Turrion, C.; Lopez-Mardomingo, C.,
Structural effects on the thermochemical properties of carbonyl compounds. I. Enthalpies of combustion, vapour pressures and enthalpies of sublimation, and enthalpies of formation of 2-methylpropanamide, 2,2-dimethylpropanamide, and 1-adamantyl carboxamide,
J. Chem. Thermodyn., 1989, 21, 859-865. [all data]
Abate, Badea, et al., 2008
Abate, Lorenzo; Badea, Elena; Blanco, Ignazio; Della Gatta, Giuseppe,
Heat Capacities and Enthalpies of Solid-Solid Transitions and Fusion of a Series of Eleven Primary Alkylamides by Differential Scanning Calorimetry,
J. Chem. Eng. Data, 2008, 53, 4, 959-965, https://doi.org/10.1021/je700662a
. [all data]
Notes
Go To: Top, Phase change data, References
- Symbols used in this document:
Tboil Boiling point ΔfusH Enthalpy of fusion ΔsubH Enthalpy of sublimation ΔsubH° Enthalpy of sublimation at standard conditions ΔsubS Entropy of sublimation - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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