Propanamide, 2,2-dimethyl-

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tboil485.2KN/AAldrich Chemical Company Inc., 1990BS
Quantity Value Units Method Reference Comment
Δsub89. ± 2.0kJ/molTEBrunetti, Gatta, et al., 2000Based on data from 298. to 359. K.; AC
Δsub86.6 ± 0.4kJ/molCAbboud, Jimenez, et al., 1989ALS
Δsub86.6 ± 0.4kJ/molN/AAbboud, Jimenez, et al., 1989Based on data from 288. to 306. K.; AC

Enthalpy of sublimation

ΔsubH (kJ/mol) Temperature (K) Reference Comment
86.600298.15Abboud, Jimenez, et al., 1989DH

Entropy of sublimation

ΔsubS (J/mol*K) Temperature (K) Reference Comment
290.5298.15Abboud, Jimenez, et al., 1989DH

Enthalpy of fusion

ΔfusH (kJ/mol) Temperature (K) Reference Comment
24.1425.4Abate, Badea, et al., 2008AC

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc., Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]

Brunetti, Gatta, et al., 2000
Brunetti, Bruno; Gatta, Giuseppe Della; Piacente, Vincenzo, Enthalpies and Entropies of Sublimation of Some Primary Alkylamides, J. Chem. Eng. Data, 2000, 45, 2, 237-241, https://doi.org/10.1021/je9902701 . [all data]

Abboud, Jimenez, et al., 1989
Abboud, J.-L.M.; Jimenez, P.; Roux, M.V.; Turrion, C.; Lopez-Mardomingo, C., Structural effects on the thermochemical properties of carbonyl compounds. I. Enthalpies of combustion, vapour pressures and enthalpies of sublimation, and enthalpies of formation of 2-methylpropanamide, 2,2-dimethylpropanamide, and 1-adamantyl carboxamide, J. Chem. Thermodyn., 1989, 21, 859-865. [all data]

Abate, Badea, et al., 2008
Abate, Lorenzo; Badea, Elena; Blanco, Ignazio; Della Gatta, Giuseppe, Heat Capacities and Enthalpies of Solid-Solid Transitions and Fusion of a Series of Eleven Primary Alkylamides by Differential Scanning Calorimetry, J. Chem. Eng. Data, 2008, 53, 4, 959-965, https://doi.org/10.1021/je700662a . [all data]


Notes

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