Silane, ethenyltrimethyl-
- Formula: C5H12Si
- Molecular weight: 100.2343
- IUPAC Standard InChIKey: GCSJLQSCSDMKTP-UHFFFAOYSA-N
- CAS Registry Number: 754-05-2
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Silane, trimethylvinyl-; (Trimethylsilyl)ethylene; Trimethylvinylsilane; Vinyltrimethylsilane; CH2=CHSi(CH3)3; Vinyltrimethysilane
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Phase change data
Go To: Top, Mass spectrum (electron ionization), Gas Chromatography, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tboil | 328. | K | N/A | PCR Inc., 1990 | BS |
Quantity | Value | Units | Method | Reference | Comment |
Ttriple | 141.57 | K | N/A | Lebedev, Lebedev, et al., 1981 | Uncertainty assigned by TRC = 0.02 K; TRC |
Ttriple | 141.65 | K | N/A | Rabinovich, Lebedev, et al., 1975 | Uncertainty assigned by TRC = 0.02 K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
ΔvapH° | 7.9 ± 0.1 | kcal/mol | C | Voronkov, Baryshok, et al., 1988 | AC |
Enthalpy of fusion
ΔfusH (kcal/mol) | Temperature (K) | Reference | Comment |
---|---|---|---|
1.831 | 141.57 | Lebedev, Lebedev, et al., 1981, 2 | DH |
1.830 | 141.65 | Rabinovich, Lebedev, et al., 1975, 2 | DH |
1.83 | 141.7 | Domalski and Hearing, 1996 | AC |
Entropy of fusion
ΔfusS (cal/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
12.9 | 141.57 | Lebedev, Lebedev, et al., 1981, 2 | DH |
12.92 | 141.65 | Rabinovich, Lebedev, et al., 1975, 2 | DH |
Mass spectrum (electron ionization)
Go To: Top, Phase change data, Gas Chromatography, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Spectrum
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Additional Data
View image of digitized spectrum (can be printed in landscape orientation).
Due to licensing restrictions, this spectrum cannot be downloaded.
Owner | NIST Mass Spectrometry Data Center Collection (C) 2014 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
---|---|
Origin | Japan AIST/NIMC Database- Spectrum MS-IW-6976 |
NIST MS number | 238939 |
Gas Chromatography
Go To: Top, Phase change data, Mass spectrum (electron ionization), References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Kovats' RI, non-polar column, isothermal
Column type | Active phase | Temperature (C) | I | Reference | Comment |
---|---|---|---|---|---|
Capillary | OV-101 | 60. | 537. | Blazsó and Garzó, 1974 | Column length: 20. m |
Normal alkane RI, non-polar column, temperature ramp
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | OV-101 | 550. | Zenkevich, 2005 | 25. m/0.20 mm/0.10 μm, N2/He, 6. K/min; Tstart: 50. C; Tend: 250. C |
References
Go To: Top, Phase change data, Mass spectrum (electron ionization), Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
PCR Inc., 1990
PCR Inc.,
Research Chemicals Catalog 1990-1991, PCR Inc., Gainesville, FL, 1990, 1. [all data]
Lebedev, Lebedev, et al., 1981
Lebedev, B.V.; Lebedev, N.K.; Khotimskii, V.S.; Durgar'yan, S.G.; Nametkin, N.S.,
Thermodynamics of polymerization of vinylorganosilanes,
Dokl. Akad. Nauk SSSR, 1981, 259, 629. [all data]
Rabinovich, Lebedev, et al., 1975
Rabinovich, I.B.; Lebedev, B.V.; Tsvetkova, L.Ya.; Nametkin, N.S.; Durgar'yan, S.G.; Khotimskii, V.S.,
Thermodynamics of polymerization of vinyltrimethylsilane,
Vysokomol. Soedin., Ser. A, 1975, 17, 1421. [all data]
Voronkov, Baryshok, et al., 1988
Voronkov, M.G.; Baryshok, V.P.; Klyuchnikov, V.A.; Danilova, T.F.; Pepekin, V.I.; Korchagina, A.N.; Khudobin, Yu.I.,
Thermochemistry of organosilicon compounds,
Journal of Organometallic Chemistry, 1988, 345, 1-2, 27-38, https://doi.org/10.1016/0022-328X(88)80231-6
. [all data]
Lebedev, Lebedev, et al., 1981, 2
Lebedev, B.V.; Lebedev, N.K.; Khotimskii, V.S.; Durgar'yan, S.G.; Nametkin, N.S.,
Thermodynamics of polymerization of vinylorganosilanes,
Dokl. Akad. Nauk, 1981, SSSR 259, 629-633. [all data]
Rabinovich, Lebedev, et al., 1975, 2
Rabinovich, I.B.; Lebedev, B.V.; Tsvetkova, L.Ya.; Nametkin, N.S.; Durgar'yan, S.G.; Khotimskii, V.S.; Kiparisova, Y.G.,
Thermodynamics of polymerization of vinyltrimethylsilane,
Vysokomol. Soedin., 1975, A17, 1421-1425. [all data]
Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D.,
Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III,
J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985
. [all data]
Blazsó and Garzó, 1974
Blazsó, M.; Garzó, G.,
Identification of Isomeric Structures of Phenyl and Trimethylsilyl Substituted 1-Alkenes by Gas Chromatography,
Chromatographia, 1974, 7, 8, 395-398, https://doi.org/10.1007/BF02330942
. [all data]
Zenkevich, 2005
Zenkevich, I.G.,
Experimentally measured retention indices., 2005. [all data]
Notes
Go To: Top, Phase change data, Mass spectrum (electron ionization), Gas Chromatography, References
- Symbols used in this document:
Tboil Boiling point Ttriple Triple point temperature ΔfusH Enthalpy of fusion ΔfusS Entropy of fusion ΔvapH° Enthalpy of vaporization at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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