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Trimethylaluminum

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Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Hydrogen anion + Trimethylaluminum = (Hydrogen anion bullet Trimethylaluminum)

By formula: H- + C3H9Al = (H- bullet C3H9Al)

Quantity Value Units Method Reference Comment
Deltar>354.8 ± 2.1kJ/molIMRBden Berg, Ingemann, et al., 1992gas phase; Hydride affinity > (CF3)2CO. Computations indicate HOF(A-) ca. -46 kcal/mol, dHaff ca. 74 kcal/mol

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

den Berg, Ingemann, et al., 1992
den Berg, K.J. van; Ingemann, S.; Nibbering, N.M.M., Gas Phase Reactions of Negative Ions with Trimethylaluminum: Formation and Reactivity of the Me3AlH- Ion., Org. Mass Spectrom., 1992, 27, 4, 523, https://doi.org/10.1002/oms.1210270427 . [all data]


Notes

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