Ethylene
- Formula: C2H4
- Molecular weight: 28.0532
- IUPAC Standard InChIKey: VGGSQFUCUMXWEO-UHFFFAOYSA-N
- CAS Registry Number: 74-85-1
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Isotopologues:
- Other names: Ethene; Acetene; Bicarburretted hydrogen; Elayl; Olefiant gas; C2H4; Athylen; Liquid ethyene; UN 1038; UN 1962
- Permanent link for this species. Use this link for bookmarking this species for future reference.
- Information on this page:
- Other data available:
- Gas phase thermochemistry data
- Condensed phase thermochemistry data
- Phase change data
- Reaction thermochemistry data: reactions 51 to 54
- Henry's Law data
- Gas phase ion energetics data
- Ion clustering data
- IR Spectrum
- Mass spectrum (electron ionization)
- UV/Visible spectrum
- Vibrational and/or electronic energy levels
- Gas Chromatography
- Fluid Properties
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Reaction thermochemistry data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
B - John E. Bartmess
MS - José A. Martinho Simões
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Reactions 1 to 50
C2H3- + =
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1704. ± 9. | kJ/mol | AVG | N/A | Average of 5 out of 6 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 1677.8 ± 2.1 | kJ/mol | IMRE | Ervin, Gronert, et al., 1990 | gas phase; B |
ΔrG° | 1670. ± 8.8 | kJ/mol | H-TS | DePuy, Gronert, et al., 1989 | gas phase; B |
ΔrG° | 1668. ± 21. | kJ/mol | H-TS | Peerboom, Rademaker, et al., 1992 | gas phase; B |
ΔrG° | >1661.0 | kJ/mol | IMRB | Froelicher, Freiser, et al., 1986 | gas phase; B |
C7H4CrO5 (g) = C5CrO5 (g) + (g)
By formula: C7H4CrO5 (g) = C5CrO5 (g) + C2H4 (g)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 105. ± 4. | kJ/mol | KinG | McNamara, Becher, et al., 1994 | The reaction enthalpy was identified with the activation energy.; MS |
ΔrH° | 103. ± 10. | kJ/mol | KinG | Wells, House, et al., 1994 | The reaction enthalpy relies on the measured activation energy and on the assumption of a negligible barrier for product recombination Wells, House, et al., 1994.; MS |
By formula: Ag+ + C2H4 = (Ag+ • C2H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 141. | kJ/mol | HPMS | Guo and Castleman, 1991 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 92.5 | J/mol*K | N/A | Guo and Castleman, 1991 | gas phase; Entropy change calculated or estimated; M |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
71.5 | 750. | HPMS | Guo and Castleman, 1991 | gas phase; Entropy change calculated or estimated; M |
By formula: H4N+ + C2H4 = (H4N+ • C2H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 42. | kJ/mol | PHPMS | Deakyne and Meot-Ner (Mautner), 1985 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 84. | J/mol*K | N/A | Deakyne and Meot-Ner (Mautner), 1985 | gas phase; Entropy change calculated or estimated; M |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
15. | 294. | PHPMS | Deakyne and Meot-Ner (Mautner), 1985 | gas phase; Entropy change calculated or estimated; M |
By formula: Co+ + C2H4 = (Co+ • C2H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 186. ± 9.2 | kJ/mol | CIDT | Sievers, Jarvis, et al., 1998 | RCD |
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
179. (+7.1,-0.) | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M | |
27. (+13.,-0.) | CID | Haynes and Armentrout, 1994 | gas phase; ΔrH>=, guided ion beam CID; M |
By formula: C2H5Cl = C2H4 + HCl
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 92.0 | kJ/mol | Eqk | Levanova, Bushneva, et al., 1979 | liquid phase; ALS |
ΔrH° | 71.5 | kJ/mol | Eqk | Levanova, Bushneva, et al., 1979 | gas phase; ALS |
ΔrH° | 72.6 ± 2.1 | kJ/mol | Eqk | Howlett, 1955 | gas phase; ALS |
ΔrH° | 71.5 | kJ/mol | Eqk | Lane, Linnett, et al., 1953 | gas phase; ALS |
By formula: Cr+ + C2H4 = (Cr+ • C2H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 96. ± 11. | kJ/mol | CIDT | Sievers, Jarvis, et al., 1998 | RCD |
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
125. (+19.,-0.) | CID | Armentrout and Kickel, 1994 | gas phase; ΔrH>=, guided ion beam CID; M |
By formula: Ni+ + C2H4 = (Ni+ • C2H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 182. ± 11. | kJ/mol | CIDT | Sievers, Jarvis, et al., 1998 | RCD |
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
138. (+19.,-0.) | CID | Armentrout and Kickel, 1994 | gas phase; ΔrH>=, guided ion beam CID; M |
By formula: Cu+ + C2H4 = (Cu+ • C2H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 176. ± 14. | kJ/mol | CIDT | Sievers, Jarvis, et al., 1998 | RCD |
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
95. (+11.,-0.) | CID | Armentrout and Kickel, 1994 | gas phase; ΔrH>=, guided ion beam CID; M |
By formula: Sc+ + C2H4 = (Sc+ • C2H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 220. ± 10. | kJ/mol | PDiss | Ranashinge and Freiser, 1992 | gas phase; M |
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
131. | CID | Armentrout and Kickel, 1994 | gas phase; ΔrH >=, guided ion beam CID; M |
By formula: La+ + C2H4 = (La+ • C2H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 220. ± 10. | kJ/mol | PDiss | Ranashinge and Freiser, 1992 | gas phase; M |
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
90.0 | CID | Armentrout and Kickel, 1994 | gas phase; ΔrH>=, guided ion beam CID; M |
By formula: Y+ + C2H4 = (Y+ • C2H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 220. ± 10. | kJ/mol | PDiss | Ranashinge and Freiser, 1992 | gas phase; M |
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
109. | CID | Armentrout and Kickel, 1994 | gas phase; ΔrH>=, guided ion beam CID; M |
By formula: Ti+ + C2H4 = (Ti+ • C2H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 146. ± 11. | kJ/mol | CIDT | Sievers, Jarvis, et al., 1998 | RCD |
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
119. | CID | Armentrout and Kickel, 1994 | gas phase; ΔrH>=, guided ion beam CID; M |
By formula: V+ + C2H4 = (V+ • C2H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 125. ± 7.9 | kJ/mol | CIDT | Sievers, Jarvis, et al., 1998 | RCD |
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
117. | CID | Armentrout and Kickel, 1994 | gas phase; ΔrH>=, guided ion beam CID; M |
By formula: Fe+ + C2H4 = (Fe+ • C2H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 145. ± 11. | kJ/mol | CIDT | Sievers, Jarvis, et al., 1998 | RCD |
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
145. (+5.9,-0.) | CID | Armentrout and Kickel, 1994 | gas phase; guided ion beam CID; M |
By formula: C2H4 + Br2 = C2H4Br2
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -120.9 ± 1.3 | kJ/mol | Cm | Conn, Kistiakowsky, et al., 1938 | gas phase; Reanalyzed by Cox and Pilcher, 1970, Original value = -121.6 ± 1.3 kJ/mol; At 355 °K; ALS |
By formula: C2H4 + I2 = C2H4I2
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -48.1 ± 0.8 | kJ/mol | Eqk | Abrams and Davis, 1954 | gas phase; ALS |
ΔrH° | -56. ± 2. | kJ/mol | Eqk | Cutherbertson and Kistiakowsky, 1935 | gas phase; Heat of dissociation; ALS |
By formula: (Ag+ • C2H4) + C2H4 = (Ag+ • 2C2H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 136. | kJ/mol | HPMS | Guo and Castleman, 1991 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 126. | J/mol*K | HPMS | Guo and Castleman, 1991 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -136. ± 2. | kJ/mol | Chyd | Kistiakowsky and Nickle, 1951 | gas phase; ALS |
ΔrH° | -136.3 ± 0.3 | kJ/mol | Chyd | Kistiakowsky, Romeyn, et al., 1935 | gas phase; ALS |
By formula: C2H5Br = HBr + C2H4
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 80.3 ± 2.1 | kJ/mol | Eqk | Lane, Linnett, et al., 1953 | gas phase; Reanalyzed by Cox and Pilcher, 1970, Original value = 79.9 kJ/mol; ALS |
By formula: C3H9Si+ + C2H4 = (C3H9Si+ • C2H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 98.7 | kJ/mol | PHPMS | Li and Stone, 1989 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 161. | J/mol*K | PHPMS | Li and Stone, 1989 | gas phase; M |
By formula: C2H4+ + C2H4 = (C2H4+ • C2H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 66.1 | kJ/mol | PI | Ono, Linn, et al., 1984 | gas phase; M |
ΔrH° | 76.1 | kJ/mol | PI | Ceyer, Tiedemann, et al., 1979 | gas phase; M |
C6H4FeO4 (l) = 4 (g) + (cr) + (g)
By formula: C6H4FeO4 (l) = 4CO (g) + Fe (cr) + C2H4 (g)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 192.5 ± 8.4 | kJ/mol | HAL-HFC | Brown, Connor, et al., 1976 | MS |
ΔrH° | 185.4 | kJ/mol | TD-HFC | Brown, Connor, et al., 1976 | MS |
By formula: C8H12 = C6H8 + C2H4
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 136. | kJ/mol | Kin | Huybrechts, Rigaux, et al., 1980 | gas phase; Diels-Alder addition at 560°K, see Van Mele, Boon, et al., 1986; ALS |
By formula: F- + C2H4 = (F- • C2H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 25. ± 13. | kJ/mol | IMRB | Sullivan and Beauchamp, 1976 | gas phase; Structure: Roy and McMahon, 1985; B |
By formula: Rh+ + C2H4 = (Rh+ • C2H4)
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
161. (+3.,-0.) | CID | Chen and Armetrout, 1995 | gas phase; guided ion beam CID; M |
C7H9Cl2NPd (solution) + (l) = (PdCl2(C5H5N)2) (solution) + (solution)
By formula: C7H9Cl2NPd (solution) + C4H4N2 (l) = (PdCl2(C5H5N)2) (solution) + C2H4 (solution)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -57.7 ± 1.7 | kJ/mol | RSC | Partenheimer and Durham, 1974 | solvent: Dichloromethane; MS |
(solution) + (solution) = C13H19O2Rh (solution) + 2 (solution)
By formula: C9H15O2Rh (solution) + C8H12 (solution) = C13H19O2Rh (solution) + 2C2H4 (solution)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -9.0 ± 0.4 | kJ/mol | RSC | Jesse, Cordfunke, et al., 1979 | solvent: n-Heptane; MS |
(g) + C2H3BrMg (solution) = (solution) + Br2Mg (solution)
By formula: HBr (g) + C2H3BrMg (solution) = C2H4 (solution) + Br2Mg (solution)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -294.1 ± 2.2 | kJ/mol | RSC | Holm, 1981 | solvent: Tetrahydrofuran; MS |
By formula: C6HCrO6+ + C2H4 = (C6HCrO6+ • C2H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 59.8 ± 5.0 | kJ/mol | ICRCD | Hop and McMahon, 1991 | gas phase; Ar collision gas; M |
By formula: Al+ + C2H4 = (Al+ • C2H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 54.4 ± 8.4 | kJ/mol | CIDC,EqG | Stockigt, Schwarz, et al., 1996 | Anchored to theory; RCD |
(CAS Reg. No. 25013-41-6 • 4294967295) + = CAS Reg. No. 25013-41-6
By formula: (CAS Reg. No. 25013-41-6 • 4294967295C2H4) + C2H4 = CAS Reg. No. 25013-41-6
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 54.0 ± 8.8 | kJ/mol | N/A | DePuy, Gronert, et al., 1989 | gas phase; B |
By formula: H2 + C2H3Cl = C2H4 + HCl
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -76.94 | kJ/mol | Chyd | Lacher, Kianpour, et al., 1956 | gas phase; At 298 K; ALS |
By formula: C2H4 + Cl2 = C2H4Cl2
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -182.6 ± 0.63 | kJ/mol | Cm | Conn, Kistiakowsky, et al., 1938 | gas phase; At 355 °K; ALS |
By formula: C2H4ClI = I + Cl + C2H4
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 320. ± 4.2 | kJ/mol | Kin | Minton, Felder, et al., 1984 | gas phase; ALS |
By formula: (C2H4+ • C2H4) + C2H4 = (C2H4+ • 2C2H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 18. | kJ/mol | PI | Ceyer, Tiedemann, et al., 1979 | gas phase; M |
C12H14Mo (cr) + (cr) = C10H10I2Mo (cr) + (g)
By formula: C12H14Mo (cr) + I2 (cr) = C10H10I2Mo (cr) + C2H4 (g)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -163.0 ± 2.1 | kJ/mol | RSC | Calhorda, Carrondo, et al., 1991 | MS |
By formula: C9H15O2Rh (cr) + 2CO (g) = C7H7O4Rh (cr) + 2C2H4 (g)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -53.6 ± 1.7 | kJ/mol | DSC | Jesse, Baks, et al., 1978 | MS |
C9H15IrO2 (cr) + 2 (g) = C7H7IrO4 (cr) + 2 (g)
By formula: C9H15IrO2 (cr) + 2CO (g) = C7H7IrO4 (cr) + 2C2H4 (g)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -74.1 ± 4.6 | kJ/mol | DSC | Jesse, Baks, et al., 1978 | MS |
By formula: (Fe+ • C2H4) + C2H4 = (Fe+ • 2C2H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 151. ± 15. | kJ/mol | CIDT | Sievers, Jarvis, et al., 1998 | RCD |
By formula: (Cr+ • C2H4) + C2H4 = (Cr+ • 2C2H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 108. ± 11. | kJ/mol | CIDT | Sievers, Jarvis, et al., 1998 | RCD |
By formula: (Mn+ • C2H4) + C2H4 = (Mn+ • 2C2H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 88. ± 14. | kJ/mol | CIDT | Sievers, Jarvis, et al., 1998 | RCD |
By formula: (V+ • C2H4) + C2H4 = (V+ • 2C2H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 127. ± 14. | kJ/mol | CIDT | Sievers, Jarvis, et al., 1998 | RCD |
By formula: (Ni+ • C2H4) + C2H4 = (Ni+ • 2C2H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 173. ± 14. | kJ/mol | CIDT | Sievers, Jarvis, et al., 1998 | RCD |
By formula: (Co+ • C2H4) + C2H4 = (Co+ • 2C2H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 152. ± 14. | kJ/mol | CIDT | Sievers, Jarvis, et al., 1998 | RCD |
By formula: (Cu+ • C2H4) + C2H4 = (Cu+ • 2C2H4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 174. ± 13. | kJ/mol | CIDT | Sievers, Jarvis, et al., 1998 | RCD |
By formula: C7H10 = C5H6 + C2H4
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 97.2 ± 2.5 | kJ/mol | Eqk | Walsh and Wells, 1976 | gas phase; ALS |
By formula: 2C2H4 = C4H8
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -86.6 ± 4.2 | kJ/mol | Eqk | Quick, Knecht, et al., 1972 | gas phase; At 750 K; ALS |
By formula: C2H4I2 = C2H4 + I2
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 48.1 ± 0.8 | kJ/mol | Eqk | Benson and Amano, 1962 | gas phase; ALS |
By formula: C4H8 + C2H4 = C6H12
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -69.9 | kJ/mol | Eqk | Scacchi and Back, 1977 | liquid phase; ALS |
References
Go To: Top, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Ervin, Gronert, et al., 1990
Ervin, K.M.; Gronert, S.; Barlow, S.E.; Gilles, M.K.; Harrison, A.G.; Bierbaum, V.M.; DePuy, C.H.; Lin, W.C.,
Bonds Strengths of Ethylene and Acetylene,
J. Am. Chem. Soc., 1990, 112, 15, 5750, https://doi.org/10.1021/ja00171a013
. [all data]
DePuy, Gronert, et al., 1989
DePuy, C.H.; Gronert, S.; Barlow, S.E.; Bierbaum, V.M.; Damrauer, R.,
The Gas Phase Acidities of the Alkanes,
J. Am. Chem. Soc., 1989, 111, 6, 1968, https://doi.org/10.1021/ja00188a003
. [all data]
Peerboom, Rademaker, et al., 1992
Peerboom, R.A.L.; Rademaker, G.J.; Dekoning, L.J.; Nibbering, N.M.M.,
Stabilization of Cycloalkyl Carbanions in the Gas Phase,
Rapid Commun. Mass Spectrom., 1992, 6, 6, 394, https://doi.org/10.1002/rcm.1290060608
. [all data]
Froelicher, Freiser, et al., 1986
Froelicher, S.W.; Freiser, B.S.; Squires, R.R.,
The C3H5- isomers. Experimental and theoretical studies of the tautomeric propenyl ions and the cyclopropyl anion in the gas phase,
J. Am. Chem. Soc., 1986, 108, 2853. [all data]
McNamara, Becher, et al., 1994
McNamara, B.; Becher, D.M.; Towns, M.H.; Grant, E.R.,
J. Phys. Chem., 1994, 98, 4622. [all data]
Wells, House, et al., 1994
Wells, J.R.; House, P.G.; Weitz, E.,
J. Phys. Chem., 1994, 98, 8343. [all data]
Guo and Castleman, 1991
Guo, B.C.; Castleman, A.W.,
The Bonding Strength of Ag+(C2H4) and Ag+(C2H4)2 Complexes,
Chem. Phys. Lett., 1991, 181, 1, 16, https://doi.org/10.1016/0009-2614(91)90214-T
. [all data]
Deakyne and Meot-Ner (Mautner), 1985
Deakyne, C.A.; Meot-Ner (Mautner), M.,
Unconventional Ionic Hydrogen Bonds. 2. NH+ pi. Complexes of Onium Ions with Olefins and Benzene Derivatives,
J. Am. Chem. Soc., 1985, 107, 2, 474, https://doi.org/10.1021/ja00288a034
. [all data]
Sievers, Jarvis, et al., 1998
Sievers, M.R.; Jarvis, L.M.; Armentrout, P.B.,
Transition Metal Ethene Bonds: Thermochemistry of M+(C2H4)n (M=Ti-Cu, n=1 and 2) Complexes,
J. Am. Chem. Soc., 1998, 120, 8, 1891, https://doi.org/10.1021/ja973834z
. [all data]
Armentrout and Kickel, 1994
Armentrout, P.B.; Kickel, B.L.,
Gas Phase Thermochemistry of Transition Metal Ligand Systems: Reassessment of Values and Periodic Trends, in Organometallic Ion Chemistry, B. S. Freiser, ed, 1994. [all data]
Haynes and Armentrout, 1994
Haynes, C.L.; Armentrout, P.B.,
Thermochemistry and Structures of CoC3H6+: Metallacyclic and Metal-Alkene Isomers,
Organomettalics, 1994, 13, 9, 3480, https://doi.org/10.1021/om00021a022
. [all data]
Levanova, Bushneva, et al., 1979
Levanova, s.V.; Bushneva, I.I.; Rodova, R.M.; Rozhnov, A.M.; Treger, Yu.A.; Aprelkin, A.S.,
Thermodynamic stability of chloroethanes in dehydrochlorination reactions,
J. Appl. Chem. USSR, 1979, 52, 1439-1442. [all data]
Howlett, 1955
Howlett, K.E.,
The use of equilibrium constants to calculate thermodynamic quantities. Part II,
J. Chem. Soc., 1955, 1784-17. [all data]
Lane, Linnett, et al., 1953
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Notes
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- Symbols used in this document:
T Temperature ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions ΔrS° Entropy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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