aluminium chloride

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Δfgas-584.59kJ/molReviewChase, 1998Data last reviewed in September, 1979
Quantity Value Units Method Reference Comment
gas,1 bar314.44J/mol*KReviewChase, 1998Data last reviewed in September, 1979

Gas Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 1500. to 6000.
A 81.58926
B 1.320091
C -0.356670
D 0.030382
E -0.917861
F -612.0481
G 407.6350
H -584.5885
ReferenceChase, 1998
Comment Data last reviewed in September, 1979

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director

Quantity Value Units Method Reference Comment
Tc625.7KN/ADenisova and Baskova, 1968 
Quantity Value Units Method Reference Comment
Pc26.00barN/ADenisova and Baskova, 1968 
Quantity Value Units Method Reference Comment
ρc3.82mol/lN/ADenisova and Baskova, 1968Uncertainty assigned by TRC = 0.04 mol/l; Vis, rect, TE

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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
MS - José A. Martinho Simões

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Fluorine anion + AlCl3 = (Fluorine anion • AlCl3)

By formula: F- + AlCl3 = (F- • AlCl3)

Quantity Value Units Method Reference Comment
Δr506. ± 13.kJ/molTDAsPervova, Korobov, et al., 1992gas phase; Thermo at 0K, experiments at 800-1100 K; value altered from reference due to conversion from electron convention to ion convention; B

Chlorine anion + AlCl3 = (Chlorine anion • AlCl3)

By formula: Cl- + AlCl3 = (Cl- • AlCl3)

Quantity Value Units Method Reference Comment
Δr321. ± 12.kJ/molTDAsPervova, Korobov, et al., 1992gas phase; Thermo at 0K, experiments at 800-1100 K; value altered from reference due to conversion from electron convention to ion convention; B

2Hydrogen chloride (g) + Aluminum, chlorodiethyl- (l) = AlCl3 (cr) + 2Ethane (g)

By formula: 2HCl (g) + C4H10AlCl (l) = AlCl3 (cr) + 2C2H6 (g)

Quantity Value Units Method Reference Comment
Δr-265.0 ± 3.3kJ/molRSCShaulov and Shmyreva, 1968The reaction enthalpy was derived from data in Shaulov and Shmyreva, 1968.; MS

AlCl3 (cr) + 2Aluminum, triethyl- (l) = 3Aluminum, chlorodiethyl- (l)

By formula: AlCl3 (cr) + 2C6H15Al (l) = 3C4H10AlCl (l)

Quantity Value Units Method Reference Comment
Δr-66.8 ± 1.3kJ/molRSCSmith, 1974Please also see Pedley and Rylance, 1977.; MS

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Denisova and Baskova, 1968
Denisova, N.D.; Baskova, A.P., Vapor Pressure and Critical Parameters of ALluminum Chloride, Russ. J. Phys. Chem., 1968, 43, 1317-8. [all data]

Pervova, Korobov, et al., 1992
Pervova, Y.U.; Korobov, M.V.; Sidorov, L.N., Enthalpies of Bonds Rupture in AlClnF4-n(-) Anions, Russ. J. Phys. Chem., 1992, 66, 635. [all data]

Shaulov and Shmyreva, 1968
Shaulov, Yu.Kh.; Shmyreva, G.O., Russ. J. Phys. Chem., 1968, 42, 1008. [all data]

Smith, 1974
Smith, M.B., J. Organometal. Chem., 1974, 76, 171. [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]


Notes

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