Cesium
- Formula: Cs
- Molecular weight: 132.9054519
- IUPAC Standard InChIKey: TVFDJXOCXUVLDH-UHFFFAOYSA-N
- CAS Registry Number: 7440-46-2
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Caesium
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Condensed phase thermochemistry data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°liquid | 0.500 | kcal/mol | Review | Chase, 1998 | Data last reviewed in June, 1968 |
Quantity | Value | Units | Method | Reference | Comment |
S°liquid,1 bar | 22.01 | cal/mol*K | Review | Chase, 1998 | Data last reviewed in June, 1968 |
Quantity | Value | Units | Method | Reference | Comment |
S°solid,1 bar | 20.37 ± 0.096 | cal/mol*K | Review | Cox, Wagman, et al., 1984 | CODATA Review value |
Quantity | Value | Units | Method | Reference | Comment |
S°solid | 20.35 | cal/mol*K | Review | Chase, 1998 | Data last reviewed in June, 1968 |
Liquid Phase Heat Capacity (Shomate Equation)
Cp° = A + B*t + C*t2 + D*t3 +
E/t2
H° − H°298.15= A*t + B*t2/2 +
C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 −
E/(2*t2) + G
Cp = heat capacity (cal/mol*K)
H° = standard enthalpy (kcal/mol)
S° = standard entropy (cal/mol*K)
t = temperature (K) / 1000.
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Temperature (K) | 301.55 to 947.967 |
---|---|
A | 7.181250 |
B | 0.121007 |
C | 0.083068 |
D | -0.023772 |
E | 0.047110 |
F | -1.490001 |
G | 30.92180 |
H | 0.498805 |
Reference | Chase, 1998 |
Comment | Data last reviewed in June, 1968 |
Solid Phase Heat Capacity (Shomate Equation)
Cp° = A + B*t + C*t2 + D*t3 +
E/t2
H° − H°298.15= A*t + B*t2/2 +
C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 −
E/(2*t2) + G
Cp = heat capacity (cal/mol*K)
H° = standard enthalpy (kcal/mol)
S° = standard entropy (cal/mol*K)
t = temperature (K) / 1000.
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Temperature (K) | 298. to 301.55 |
---|---|
A | 13.63390 |
B | -11.95110 |
C | 11.60600 |
D | -3.998141 |
E | -0.292496 |
F | -4.608980 |
G | 38.28901 |
H | 0.000000 |
Reference | Chase, 1998 |
Comment | Data last reviewed in June, 1968 |
References
Go To: Top, Condensed phase thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Chase, 1998
Chase, M.W., Jr.,
NIST-JANAF Themochemical Tables, Fourth Edition,
J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]
Cox, Wagman, et al., 1984
Cox, J.D.; Wagman, D.D.; Medvedev, V.A.,
CODATA Key Values for Thermodynamics, Hemisphere Publishing Corp., New York, 1984, 1. [all data]
Notes
Go To: Top, Condensed phase thermochemistry data, References
- Symbols used in this document:
S°liquid,1 bar Entropy of liquid at standard conditions (1 bar) S°solid Entropy of solid at standard conditions S°solid,1 bar Entropy of solid at standard conditions (1 bar) ΔfH°liquid Enthalpy of formation of liquid at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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