boron


Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Δfliquid48.93kJ/molReviewChase, 1998Data last reviewed in June, 1983
Quantity Value Units Method Reference Comment
liquid,1 bar26.54J/mol*KReviewChase, 1998Data last reviewed in June, 1983
Quantity Value Units Method Reference Comment
solid,1 bar5.90 ± 0.08J/mol*KReviewCox, Wagman, et al., 1984 rhombic phase; CODATA Review value

Liquid Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 2350. to 4137.895
A 31.75003
B 2.556177×10-7
C -6.456792×10-8
D 5.616644×10-9
E 2.705970×10-7
F 27.94205
G 46.94741
H 48.92686
ReferenceChase, 1998
Comment Data last reviewed in June, 1983

Solid Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 298. to 1800.1800. to 2350.
A 10.1857425.12664
B 29.244151.975493
C -18.021370.338395
D 4.212326-0.040032
E -0.550999-2.635578
F -6.036299-14.43597
G 7.08907725.59930
H 0.0000000.000000
ReferenceChase, 1998Chase, 1998
Comment β-rhombohedral phase; Data last reviewed in June, 1983 β-rhombohedral phase; Data last reviewed in June, 1983

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Cox, Wagman, et al., 1984
Cox, J.D.; Wagman, D.D.; Medvedev, V.A., CODATA Key Values for Thermodynamics, Hemisphere Publishing Corp., New York, 1984, 1. [all data]


Notes

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