boron


Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Δfliquid11.69kcal/molReviewChase, 1998Data last reviewed in June, 1983
Quantity Value Units Method Reference Comment
liquid,1 bar6.343cal/mol*KReviewChase, 1998Data last reviewed in June, 1983
Quantity Value Units Method Reference Comment
solid,1 bar1.41 ± 0.02cal/mol*KReviewCox, Wagman, et al., 1984 rhombic phase; CODATA Review value

Liquid Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 2350. to 4137.895
A 7.588440
B 6.109410×10-8
C -1.543211×10-8
D 1.342410×10-9
E 6.467422×10-8
F 6.678311
G 11.22070
H 11.69380
ReferenceChase, 1998
Comment Data last reviewed in June, 1983

Solid Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 298. to 1800.1800. to 2350.
A 2.4344516.005412
B 6.9895200.472154
C -4.3072110.080878
D 1.006771-0.009568
E -0.131692-0.629918
F -1.442711-3.450280
G 1.6943316.118380
H 0.0000000.000000
ReferenceChase, 1998Chase, 1998
Comment β-rhombohedral phase; Data last reviewed in June, 1983 β-rhombohedral phase; Data last reviewed in June, 1983

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Cox, Wagman, et al., 1984
Cox, J.D.; Wagman, D.D.; Medvedev, V.A., CODATA Key Values for Thermodynamics, Hemisphere Publishing Corp., New York, 1984, 1. [all data]


Notes

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