sodium
- Formula: Na
- Molecular weight: 22.98976928
- IUPAC Standard InChIKey: KEAYESYHFKHZAL-UHFFFAOYSA-N
- CAS Registry Number: 7440-23-5
- Chemical structure:
This structure is also available as a 2d Mol file - Permanent link for this species. Use this link for bookmarking this species for future reference.
- Information on this page:
- Other data available:
- Data at other public NIST sites:
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- NIST Atomic Spectra Database - Levels Holdings (on physics web site)
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- Gas Phase Kinetics Database
- X-ray Photoelectron Spectroscopy Database, version 5.0
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Gas phase thermochemistry data
Go To: Top, Condensed phase thermochemistry data, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°gas | 107.5 ± 0.7 | kJ/mol | Review | Cox, Wagman, et al., 1984 | CODATA Review value |
ΔfH°gas | 107.30 | kJ/mol | Review | Chase, 1998 | Data last reviewed in June, 1962 |
Quantity | Value | Units | Method | Reference | Comment |
S°gas,1 bar | 153.718 ± 0.003 | J/mol*K | Review | Cox, Wagman, et al., 1984 | CODATA Review value |
S°gas,1 bar | 153.65 | J/mol*K | Review | Chase, 1998 | Data last reviewed in June, 1962 |
Gas Phase Heat Capacity (Shomate Equation)
Cp° = A + B*t + C*t2 + D*t3 +
E/t2
H° − H°298.15= A*t + B*t2/2 +
C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 −
E/(2*t2) + G
Cp = heat capacity (J/mol*K)
H° = standard enthalpy (kJ/mol)
S° = standard entropy (J/mol*K)
t = temperature (K) / 1000.
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Temperature (K) | 1170.525 to 6000. |
---|---|
A | 20.80573 |
B | 0.277206 |
C | -0.392086 |
D | 0.119634 |
E | -0.008879 |
F | 101.0386 |
G | 178.7095 |
H | 107.2999 |
Reference | Chase, 1998 |
Comment | Data last reviewed in June, 1962 |
Condensed phase thermochemistry data
Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°liquid | 2.41 | kJ/mol | Review | Chase, 1998 | Data last reviewed in June, 1962 |
Quantity | Value | Units | Method | Reference | Comment |
S°liquid,1 bar | 57.86 | J/mol*K | Review | Chase, 1998 | Data last reviewed in June, 1962 |
Quantity | Value | Units | Method | Reference | Comment |
S°solid,1 bar | 51.30 ± 0.20 | J/mol*K | Review | Cox, Wagman, et al., 1984 | CODATA Review value |
Quantity | Value | Units | Method | Reference | Comment |
S°solid | 51.46 | J/mol*K | Review | Chase, 1998 | Data last reviewed in June, 1962 |
Liquid Phase Heat Capacity (Shomate Equation)
Cp° = A + B*t + C*t2 + D*t3 +
E/t2
H° − H°298.15= A*t + B*t2/2 +
C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 −
E/(2*t2) + G
Cp = heat capacity (J/mol*K)
H° = standard enthalpy (kJ/mol)
S° = standard entropy (J/mol*K)
t = temperature (K) / 1000.
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Temperature (K) | 370.98 to 1170.525 |
---|---|
A | 40.25707 |
B | -28.23849 |
C | 20.69402 |
D | -3.641872 |
E | -0.079874 |
F | -8.782300 |
G | 113.6646 |
H | 2.406001 |
Reference | Chase, 1998 |
Comment | Data last reviewed in June, 1962 |
Solid Phase Heat Capacity (Shomate Equation)
Cp° = A + B*t + C*t2 + D*t3 +
E/t2
H° − H°298.15= A*t + B*t2/2 +
C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 −
E/(2*t2) + G
Cp = heat capacity (J/mol*K)
H° = standard enthalpy (kJ/mol)
S° = standard entropy (J/mol*K)
t = temperature (K) / 1000.
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Temperature (K) | 298. to 370. |
---|---|
A | 72.63675 |
B | -9.491572 |
C | -730.9322 |
D | 1414.518 |
E | -1.259377 |
F | -21.79467 |
G | 155.0963 |
H | 0.000000 |
Reference | Chase, 1998 |
Comment | Data last reviewed in June, 1962 |
Reaction thermochemistry data
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
MS - José A. Martinho Simões
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
0.5 (solution) + (cr) = C8H5CrNaO3 (solution)
By formula: 0.5C16H10Cr2O6 (solution) + Na (cr) = C8H5CrNaO3 (solution)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -285.1 ± 3.6 | kJ/mol | RSC | Kiss, Nolan, et al., 1994 | solvent: Tetrahydrofuran; The reaction enthalpy was calculated from the enthalpies of the following reactions: 0.5[Cr(Cp)(CO)3]2(solution) + (Na)[Cr(Cp)(CO)2(PPh3)](solution) = (Na)[Cr(Cp)(CO)3](solution) + Cr(Cp)(CO)2(PPh3)(solution), -34.9 ± 0.4 kJ/mol, Cr(Cp)(CO)2(PPh3)(solution) + (Na)(Ph2CO)(solution) = (Na)[Cr(Cp)(CO)2(PPh3)](solution) + Ph2CO(solution), -89.1 ± 2.5 kJ/mol, and Ph2CO(solution) + Na(cr) = (Na)(Ph2CO)(solution), -161.1 ± 2.5 kJ/mol Kiss, Nolan, et al., 1994.; MS |
0.5C16H10Mo2O6 (solution) + (cr) = C8H5MoNaO3 (solution)
By formula: 0.5C16H10Mo2O6 (solution) + Na (cr) = C8H5MoNaO3 (solution)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -265.5 ± 3.6 | kJ/mol | RSC | Kiss, Nolan, et al., 1994 | solvent: Tetrahydrofuran; The reaction enthalpy was calculated from the enthalpies of the following reactions: 0.5[Mo(Cp)(CO)3]2(solution) + (Na)[Cr(Cp)(CO)2(PPh3)](solution) = (Na)[Mo(Cp)(CO)3](solution) + Cr(Cp)(CO)2(PPh3)(solution), -15.3 ± 0.4 kJ/mol, Cr(Cp)(CO)2(PPh3)(solution) + (Na)(Ph2CO)(solution) = (Na)[Cr(Cp)(CO)2(PPh3)](solution) + Ph2CO(solution), -89.1 ± 2.5 kJ/mol, and Ph2CO(solution) + Na(cr) = (Na)(Ph2CO)(solution), -161.1 ± 2.5 kJ/mol Kiss, Nolan, et al., 1994.; MS |
0.5C26H30Mo2O6 (solution) + (cr) = C13H15MoNaO3 (solution)
By formula: 0.5C26H30Mo2O6 (solution) + Na (cr) = C13H15MoNaO3 (solution)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -250.6 ± 6.0 | kJ/mol | RSC | Kiss, Nolan, et al., 1994 | solvent: Tetrahydrofuran; The reaction enthalpy was calculated from the enthalpies of the following reactions: 0.5[Mo(Cp*)(CO)3]2(solution) + (Na)[Cr(Cp)(CO)2(PPh3)](solution) = (Na)[Mo(Cp*)(CO)3](solution) + Cr(Cp)(CO)2(PPh3)(solution), Cr(Cp)(CO)2(PPh3)(solution) + (Na)(Ph2CO)(solution) = (Na)[Cr(Cp)(CO)2(PPh3)](solution) + Ph2CO(solution), -89.1 ± 2.5 kJ/mol, and Ph2CO(solution) + Na(cr) = (Na)(Ph2CO)(solution), -161.1 ± 2.5 kJ/mol Kiss, Nolan, et al., 1994.; MS |
0.5C16H10O6W2 (solution) + (cr) = C8H5NaO3W (solution)
By formula: 0.5C16H10O6W2 (solution) + Na (cr) = C8H5NaO3W (solution)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -258.2 ± 6.0 | kJ/mol | RSC | Kiss, Nolan, et al., 1994 | solvent: Tetrahydrofuran; The reaction enthalpy was calculated from the enthalpies of the following reactions: 0.5[W(Cp)(CO)3]2(solution) + (Na)[Cr(Cp)(CO)2(PPh3)](solution) = (Na)[W(Cp)(CO)3](solution) + Cr(Cp)(CO)2(PPh3)(solution), Cr(Cp)(CO)2(PPh3)(solution) + (Na)(Ph2CO)(solution) = (Na)[Cr(Cp)(CO)2(PPh3)](solution) + Ph2CO(solution), -89.1 ± 2.5 kJ/mol, and Ph2CO(solution) + Na(cr) = (Na)(Ph2CO)(solution), -161.1 ± 2.5 kJ/mol Kiss, Nolan, et al., 1994.; MS |
0.5 (solution) + (cr) = C4CoNaO4 (solution)
By formula: 0.5C8Co2O8 (solution) + Na (cr) = C4CoNaO4 (solution)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -318. ± 11. | kJ/mol | RSC | Kiss, Nolan, et al., 1994 | solvent: Tetrahydrofuran; The reaction enthalpy was calculated from the enthalpies of the following reactions: 0.5Co2(CO)8(solution) + (Na)(Ph2CO)(solution) = (Na)[Co(CO)4](solution) + Ph2CO(solution), -157. ± 11. kJ/mol, and Ph2CO(solution) + Na(cr) = (Na)(Ph2CO)(solution), -161.1 ± 2.5 kJ/mol Kiss, Nolan, et al., 1994.; MS |
By formula: 4Na + C2ClF3 = 2C + ClNa + 3FNa
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -1576.1 ± 5.4 | kJ/mol | Cm | Kolesov, Zenkov, et al., 1963 | gas phase; Reanalyzed by Cox and Pilcher, 1970, Original value = -1543. ± 5.4 kJ/mol; ALS |
(CAS Reg. No. 58799-98-7 • 4294967295) + = CAS Reg. No. 58799-98-7
By formula: (CAS Reg. No. 58799-98-7 • 4294967295Na) + Na = CAS Reg. No. 58799-98-7
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 58.7 ± 3.0 | kJ/mol | N/A | McHugh, Eaton, et al., 1989 | gas phase; Vertical Detachment Energy: 0.543±0.010 eV; B |
By formula: C4F8 + 4Na = 4C + 8FNa
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -2989. ± 9.2 | kJ/mol | Ccb | Kolesov, Talakin, et al., 1968 | gas phase; Correction of Kolesov, Talakin, et al., 1964; ALS |
By formula: (Na+ • 8Na) + Na = (Na+ • 9Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 75.3 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; ΔrH<; M |
(CAS Reg. No. 67291-87-6 • 4294967295) + = CAS Reg. No. 67291-87-6
By formula: (CAS Reg. No. 67291-87-6 • 4294967295Na) + Na = CAS Reg. No. 67291-87-6
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 126.8 ± 2.5 | kJ/mol | N/A | Miller, Leopold, et al., 1986 | gas phase; B |
(CAS Reg. No. 71892-04-1 • 4294967295) + = CAS Reg. No. 71892-04-1
By formula: (CAS Reg. No. 71892-04-1 • 4294967295Na) + Na = CAS Reg. No. 71892-04-1
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 199.9 ± 1.3 | kJ/mol | N/A | Miller, Leopold, et al., 1986 | gas phase; B |
(solution) + (cr) = C13H10NaO (solution)
By formula: C13H10O (solution) + Na (cr) = C13H10NaO (solution)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -161.1 ± 2.5 | kJ/mol | RSC | Kiss, Nolan, et al., 1994 | solvent: Tetrahydrofuran; MS |
By formula: (I- • 4294967295Na) + Na = I-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 82.0 ± 9.6 | kJ/mol | N/A | Miller, Leopold, et al., 1986 | gas phase; B |
(CAS Reg. No. 70377-22-9 • 4294967295) + = CAS Reg. No. 70377-22-9
By formula: (CAS Reg. No. 70377-22-9 • 4294967295Na) + Na = CAS Reg. No. 70377-22-9
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 114. ± 8.4 | kJ/mol | N/A | Miller, Leopold, et al., 1986 | gas phase; B |
By formula: (Na+ • 10Na) + Na = (Na+ • 11Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 65.7 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: (Na+ • 11Na) + Na = (Na+ • 12Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 87.0 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: (Na+ • 12Na) + Na = (Na+ • 13Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 69.5 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: (Na+ • 13Na) + Na = (Na+ • 14Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 76.1 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: (Na+ • 14Na) + Na = (Na+ • 15Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 66.5 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: (Na+ • 15Na) + Na = (Na+ • 16Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 79.1 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: (Na+ • 16Na) + Na = (Na+ • 17Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 82.8 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: (Na+ • 17Na) + Na = (Na+ • 18Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 87.0 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: (Na+ • 18Na) + Na = (Na+ • 19Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 82.0 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: (Na+ • 19Na) + Na = (Na+ • 20Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 89.5 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: (Na+ • 22Na) + Na = (Na+ • 23Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 71.5 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: (Na+ • 23Na) + Na = (Na+ • 24Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 79.1 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: (Na+ • 24Na) + Na = (Na+ • 25Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 76.1 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: (Na+ • 25Na) + Na = (Na+ • 26Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 81.2 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: (Na+ • 26Na) + Na = (Na+ • 27Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 76.1 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: (Na+ • 27Na) + Na = (Na+ • 28Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 84.1 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: (Na+ • 28Na) + Na = (Na+ • 29Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 82.8 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: (Na+ • 29Na) + Na = (Na+ • 30Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 85.8 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: (Na+ • 30Na) + Na = (Na+ • 31Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 81.2 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: (Na+ • 31Na) + Na = (Na+ • 32Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 87.9 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: (Na+ • 32Na) + Na = (Na+ • 33Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 88.7 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: (Na+ • 33Na) + Na = (Na+ • 34Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 91.6 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: (Na+ • 34Na) + Na = (Na+ • 35Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 82.0 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: (Na+ • 35Na) + Na = (Na+ • 36Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 87.0 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: (Na+ • 9Na) + Na = (Na+ • 10Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 75.3 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: (Na+ • 2Na) + Na = (Na+ • 3Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 56.1 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: (Na+ • 3Na) + Na = (Na+ • 4Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 84.1 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: (Na+ • 4Na) + Na = (Na+ • 5Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 57.7 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: (Na+ • 5Na) + Na = (Na+ • 6Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 110. | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: (Na+ • 6Na) + Na = (Na+ • 7Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 73.2 | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: (Na+ • 7Na) + Na = (Na+ • 8Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 126. | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: (Na+ • Na) + Na = (Na+ • 2Na)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 133. | kJ/mol | PDiss | Brechignac, Cahuzac, et al., 1989 | gas phase; M |
By formula: 4Na + CF4 = C + 4FNa
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -1362. ± 9.2 | kJ/mol | Ccb | Vorob'ev and Skuratov, 1960 | gas phase; ALS |
By formula: C2F4 + 4Na = 4FNa + 2C
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -1611. ± 4.6 | kJ/mol | Cm | Kolesov, Zenkov, et al., 1962 | gas phase; ALS |
By formula: 8Na + C3F8 = 3C + 8FNa
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -2761. ± 7.1 | kJ/mol | Ccb | Kolesov, Talakin, et al., 1967 | gas phase; ALS |
References
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Cox, Wagman, et al., 1984
Cox, J.D.; Wagman, D.D.; Medvedev, V.A.,
CODATA Key Values for Thermodynamics, Hemisphere Publishing Corp., New York, 1984, 1. [all data]
Chase, 1998
Chase, M.W., Jr.,
NIST-JANAF Themochemical Tables, Fourth Edition,
J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]
Kiss, Nolan, et al., 1994
Kiss, G.; Nolan, S.P.; Hoff, C.D.,
Inorg. Chim. Acta, 1994, 227, 285. [all data]
Kolesov, Zenkov, et al., 1963
Kolesov, V.P.; Zenkov, I.D.; Skuratov, S.M.,
Standard enthalpy of formation of chlorotrifluoroethylene,
Russ. J. Phys. Chem. (Engl. Transl.), 1963, 37, 115-116. [all data]
Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G.,
Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]
McHugh, Eaton, et al., 1989
McHugh, K.M.; Eaton, J.G.; Lee, G.H.; Sarkas, H.W.; Kidder, L.H.; Snodgrass, J.T.; Manaa, M.R.; Bowen, K.H.,
Photoelectron Spectra of the alkali metal cluster Anions: Na-,n=2-5, K-,n=2-7, Rb-,n=2-3, and Cs-,n=2-3,
J. Chem. Phys., 1989, 91, 6, 3792, https://doi.org/10.1063/1.456861
. [all data]
Kolesov, Talakin, et al., 1968
Kolesov, V.P.; Talakin, O.G.; Skuratov, S.M.,
Enthalpy of formation of some specimens of amorphous carbon,
Russ. J. Phys. Chem. (Engl. Transl.), 1968, 42, 1218-1220. [all data]
Kolesov, Talakin, et al., 1964
Kolesov, V.P.; Talakin, O.G.; Skuratov, S.M.,
Standard enthalpy of formation of perfluorocyclobutane,
Russ. J. Phys. Chem. (Engl. Transl.), 1964, 38, 930-931. [all data]
Brechignac, Cahuzac, et al., 1989
Brechignac, C.; Cahuzac, P.; Leygnier, J.; Weiner, J.,
Dynamics of Unimolecular Dissociation of Sodium Cluster Ions,
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. [all data]
Miller, Leopold, et al., 1986
Miller, T.M.; Leopold, D.G.; Murray, K.K.; Lineberger, W.C.,
Electron Affinities of the Alkali Halides and the Structure of their Negative Ions,
J. Chem. Phys., 1986, 85, 5, 2368, https://doi.org/10.1063/1.451091
. [all data]
Vorob'ev and Skuratov, 1960
Vorob'ev, A.F.; Skuratov, S.M.,
Standard enthalpies of formation of CF4,
Zh. Neorg. Khim., 1960, 5, 1398-1401. [all data]
Kolesov, Zenkov, et al., 1962
Kolesov, V.P.; Zenkov, I.D.; Skuratov, S.M.,
The standard enthalpy of formation of tetrafluoroethylene,
Russ. J. Phys. Chem. (Engl. Transl.), 1962, 36, 45-47. [all data]
Kolesov, Talakin, et al., 1967
Kolesov, V.P.; Talakin, O.G.; Skuratov, S.M.,
Standard enthalpy of formation of perfluoropropane and enthalpies of formation of normal perfluoroalkanes,
Vestn. Mosk. Univ. Khim., 1967, 22, 38-42. [all data]
Notes
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- Symbols used in this document:
S°gas,1 bar Entropy of gas at standard conditions (1 bar) S°liquid,1 bar Entropy of liquid at standard conditions (1 bar) S°solid Entropy of solid at standard conditions S°solid,1 bar Entropy of solid at standard conditions (1 bar) ΔfH°gas Enthalpy of formation of gas at standard conditions ΔfH°liquid Enthalpy of formation of liquid at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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