rubidium

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Δfgas80.9 ± 0.8kJ/molReviewCox, Wagman, et al., 1984CODATA Review value
Δfgas80.90kJ/molReviewChase, 1998Data last reviewed in December, 1983
Quantity Value Units Method Reference Comment
gas,1 bar170.094 ± 0.003J/mol*KReviewCox, Wagman, et al., 1984CODATA Review value
gas,1 bar170.09J/mol*KReviewChase, 1998Data last reviewed in December, 1983

Gas Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 970.385 to 1800.1800. to 6000.
A 20.6396374.13588
B 0.461826-39.23458
C -0.4948179.907546
D 0.173669-0.679452
E 0.004386-35.14100
F 74.744654.967789
G 194.9782214.2995
H 80.9001580.90015
ReferenceChase, 1998Chase, 1998
Comment Data last reviewed in December, 1983 Data last reviewed in December, 1983

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Δfliquid2.18kJ/molReviewChase, 1998Data last reviewed in December, 1983
Quantity Value Units Method Reference Comment
liquid,1 bar83.76J/mol*KReviewChase, 1998Data last reviewed in December, 1983
Quantity Value Units Method Reference Comment
solid,1 bar76.78 ± 0.30J/mol*KReviewCox, Wagman, et al., 1984CODATA Review value
Quantity Value Units Method Reference Comment
solid76.78J/mol*KReviewChase, 1998Data last reviewed in December, 1983

Liquid Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 312.65 to 970.385
A 35.49727
B -12.87341
C 8.550047
D -0.002827
E -0.000119
F -7.902990
G 130.1797
H 2.184003
ReferenceChase, 1998
Comment Data last reviewed in December, 1983

Solid Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 298. to 312.65
A 9.446260
B 65.31182
C 45.51230
D -26.78961
E -0.107730
F -6.429511
G 66.34569
H 0.000000
ReferenceChase, 1998
Comment Data last reviewed in December, 1983

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

(Bromine anion • 4294967295rubidium) + rubidium = Bromine anion

By formula: (Br- • 4294967295Rb) + Rb = Br-

Quantity Value Units Method Reference Comment
Δr111. ± 4.2kJ/molTherMiller, Leopold, et al., 1986gas phase; Extrapolated by polarizability and radius from experimental data.

(CAS Reg. No. 106070-95-5 • 4294967295rubidium) + rubidium = CAS Reg. No. 106070-95-5

By formula: (CAS Reg. No. 106070-95-5 • 4294967295Rb) + Rb = CAS Reg. No. 106070-95-5

Quantity Value Units Method Reference Comment
Δr134.8 ± 1.0kJ/molN/AMiller, Leopold, et al., 1986gas phase

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Cox, Wagman, et al., 1984
Cox, J.D.; Wagman, D.D.; Medvedev, V.A., CODATA Key Values for Thermodynamics, Hemisphere Publishing Corp., New York, 1984, 1. [all data]

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Miller, Leopold, et al., 1986
Miller, T.M.; Leopold, D.G.; Murray, K.K.; Lineberger, W.C., Electron Affinities of the Alkali Halides and the Structure of their Negative Ions, J. Chem. Phys., 1986, 85, 5, 2368, https://doi.org/10.1063/1.451091 . [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, References