rhodium
- Formula: Rh
- Molecular weight: 102.90550
- IUPAC Standard InChIKey: MHOVAHRLVXNVSD-UHFFFAOYSA-N
- CAS Registry Number: 7440-16-6
- Chemical structure:
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- Other data available:
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Reaction thermochemistry data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
C16O16Rh6 (cr) = 16 (g) + 6 (cr)
By formula: C16O16Rh6 (cr) = 16CO (g) + 6Rh (cr)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 155.2 ± 4.0 | kcal/mol | TD-HFC | Brown, Connor, et al., 1975 | Please also see Pedley and Rylance, 1977. |
C12O12Rh4 (cr) = 12 (g) + 4 (cr)
By formula: C12O12Rh4 (cr) = 12CO (g) + 4Rh (cr)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 119.0 ± 3.0 | kcal/mol | TD-HFC | Connor, Skinner, et al., 1973 | Please also see Pedley and Rylance, 1977. |
References
Go To: Top, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Brown, Connor, et al., 1975
Brown, D. Lalage S.; Connor, Joseph A.; Skinner, Henry A.,
Microcalorimetric studies. The enthalpy of formation of hexadecacarbonylhexarhodium, Rh6(CO)16,
J. Chem. Soc., Faraday Trans. 1, 1975, 71, 0, 699, https://doi.org/10.1039/f19757100699
. [all data]
Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J.,
Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]
Connor, Skinner, et al., 1973
Connor, J.A.; Skinner, H.A.; Virmani, Y.,
High temperature microcalorimetric studies of the thermal decomposition and iodination of polynuclear carbonyls of Fe, Co, Ru, Rh, Re, Os and Ir,
Faraday Symp. Chem. Soc., 1973, 8, 18, https://doi.org/10.1039/fs9730800018
. [all data]
Notes
Go To: Top, Reaction thermochemistry data, References
- Symbols used in this document:
ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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