rhodium


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

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Individual Reactions

C16O16Rh6 (cr) = 16Carbon monoxide (g) + 6rhodium (cr)

By formula: C16O16Rh6 (cr) = 16CO (g) + 6Rh (cr)

Quantity Value Units Method Reference Comment
Δr155.2 ± 4.0kcal/molTD-HFCBrown, Connor, et al., 1975Please also see Pedley and Rylance, 1977.

C12O12Rh4 (cr) = 12Carbon monoxide (g) + 4rhodium (cr)

By formula: C12O12Rh4 (cr) = 12CO (g) + 4Rh (cr)

Quantity Value Units Method Reference Comment
Δr119.0 ± 3.0kcal/molTD-HFCConnor, Skinner, et al., 1973Please also see Pedley and Rylance, 1977.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Brown, Connor, et al., 1975
Brown, D. Lalage S.; Connor, Joseph A.; Skinner, Henry A., Microcalorimetric studies. The enthalpy of formation of hexadecacarbonylhexarhodium, Rh6(CO)16, J. Chem. Soc., Faraday Trans. 1, 1975, 71, 0, 699, https://doi.org/10.1039/f19757100699 . [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Connor, Skinner, et al., 1973
Connor, J.A.; Skinner, H.A.; Virmani, Y., High temperature microcalorimetric studies of the thermal decomposition and iodination of polynuclear carbonyls of Fe, Co, Ru, Rh, Re, Os and Ir, Faraday Symp. Chem. Soc., 1973, 8, 18, https://doi.org/10.1039/fs9730800018 . [all data]


Notes

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