nickel


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
B - John E. Bartmess

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Individual Reactions

Nickel tetracarbonyl (g) = 4Carbon monoxide (g) + nickel (cr)

By formula: C4NiO4 (g) = 4CO (g) + Ni (cr)

Quantity Value Units Method Reference Comment
Δr38.34 ± 0.60kcal/molEqGMonteil, Raffin, et al., 1988The reaction enthalpy is the average of several 2nd and 3rd law results Monteil, Raffin, et al., 1988; MS

CNiO (g) = Carbon monoxide (g) + nickel (g)

By formula: CNiO (g) = CO (g) + Ni (g)

Quantity Value Units Method Reference Comment
Δr40.6 ± 5.8kcal/molFA-SIFTSunderlin, Wang, et al., 1992MS
Δr25.8kcal/molN/AMcQuaid, Morris, et al., 1988Method: Chemiluminescence spectroscopy.; MS
Δr29. ± 15.kcal/molN/AStevens, Feigerle, et al., 1982Please also see Compton and Stockdale, 1976. Method: LPS and collision with low energy electrons.; MS

4Carbon monoxide (g) + nickel (cr) = Nickel tetracarbonyl (g)

By formula: 4CO (g) + Ni (cr) = C4NiO4 (g)

Quantity Value Units Method Reference Comment
Δr-36.5 ± 1.0kcal/molEqGSykes and Townshend, 1955Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970. Temperatures: 398 and 409 K. The reaction enthalpy was obtained by the 3rd law method and refers to 298 K; MS

Nickel, bis[(1,2,5,6-η)-1,5-cyclooctadiene]- (solution) = 21,5-Cyclooctadiene, (Z,Z)- (solution) + nickel (cr)

By formula: (Ni(C8H12)2) (solution) = 2C8H12 (solution) + Ni (cr)

Quantity Value Units Method Reference Comment
Δr-3.0 ± 1.0kcal/molRSCTolman, Reutter D.W., et al., 1976solvent: Toluene; The toluene solution contained catalytic amounts of carbon tetrachloride.; MS

(Nickel ion (1+) • 10nickel) + nickel = (Nickel ion (1+) • 11nickel)

By formula: (Ni+ • 10Ni) + Ni = (Ni+ • 11Ni)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
80.1 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Nickel ion (1+) • 11nickel) + nickel = (Nickel ion (1+) • 12nickel)

By formula: (Ni+ • 11Ni) + Ni = (Ni+ • 12Ni)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
84.1 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Nickel ion (1+) • 12nickel) + nickel = (Nickel ion (1+) • 13nickel)

By formula: (Ni+ • 12Ni) + Ni = (Ni+ • 13Ni)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
71.5 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Nickel ion (1+) • 13nickel) + nickel = (Nickel ion (1+) • 14nickel)

By formula: (Ni+ • 13Ni) + Ni = (Ni+ • 14Ni)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
79.8 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Nickel ion (1+) • 14nickel) + nickel = (Nickel ion (1+) • 15nickel)

By formula: (Ni+ • 14Ni) + Ni = (Ni+ • 15Ni)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
80.8 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Nickel ion (1+) • 15nickel) + nickel = (Nickel ion (1+) • 16nickel)

By formula: (Ni+ • 15Ni) + Ni = (Ni+ • 16Ni)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
84.6 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Nickel ion (1+) • 16nickel) + nickel = (Nickel ion (1+) • 17nickel)

By formula: (Ni+ • 16Ni) + Ni = (Ni+ • 17Ni)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
81.5 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Nickel ion (1+) • 9nickel) + nickel = (Nickel ion (1+) • 10nickel)

By formula: (Ni+ • 9Ni) + Ni = (Ni+ • 10Ni)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
70.0 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Nickel ion (1+) • 2nickel) + nickel = (Nickel ion (1+) • 3nickel)

By formula: (Ni+ • 2Ni) + Ni = (Ni+ • 3Ni)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
47.6 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Nickel ion (1+) • 3nickel) + nickel = (Nickel ion (1+) • 4nickel)

By formula: (Ni+ • 3Ni) + Ni = (Ni+ • 4Ni)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
53.2 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Nickel ion (1+) • 4nickel) + nickel = (Nickel ion (1+) • 5nickel)

By formula: (Ni+ • 4Ni) + Ni = (Ni+ • 5Ni)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
65.7 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Nickel ion (1+) • 5nickel) + nickel = (Nickel ion (1+) • 6nickel)

By formula: (Ni+ • 5Ni) + Ni = (Ni+ • 6Ni)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
70.8 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Nickel ion (1+) • 6nickel) + nickel = (Nickel ion (1+) • 7nickel)

By formula: (Ni+ • 6Ni) + Ni = (Ni+ • 7Ni)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
63.4 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Nickel ion (1+) • 7nickel) + nickel = (Nickel ion (1+) • 8nickel)

By formula: (Ni+ • 7Ni) + Ni = (Ni+ • 8Ni)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
67.6 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Nickel ion (1+) • 8nickel) + nickel = (Nickel ion (1+) • 9nickel)

By formula: (Ni+ • 8Ni) + Ni = (Ni+ • 9Ni)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
67.6 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Nickel ion (1+) • nickel) + nickel = (Nickel ion (1+) • 2nickel)

By formula: (Ni+ • Ni) + Ni = (Ni+ • 2Ni)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
56.2 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

Nickel ion (1+) + nickel = (Nickel ion (1+) • nickel)

By formula: Ni+ + Ni = (Ni+ • Ni)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
48.8 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(CAS Reg. No. 64899-92-9 • 4294967295nickel) + nickel = CAS Reg. No. 64899-92-9

By formula: (CAS Reg. No. 64899-92-9 • 4294967295Ni) + Ni = CAS Reg. No. 64899-92-9

Quantity Value Units Method Reference Comment
Δr45.79 ± 0.73kcal/molN/AMiller, Feigerle, et al., 1987gas phase; B

(CAS Reg. No. 71736-54-4 • 4294967295nickel) + nickel = CAS Reg. No. 71736-54-4

By formula: (CAS Reg. No. 71736-54-4 • 4294967295Ni) + Ni = CAS Reg. No. 71736-54-4

Quantity Value Units Method Reference Comment
Δr50.1 ± 5.1kcal/molN/AHo, Polak, et al., 1993gas phase; B

tetrakis(trifluorophosphine)nickel (l) = nickel (cr) + 4Phosphorus trifluoride (g)

By formula: F12NiP4 (l) = Ni (cr) + 4F3P (g)

Quantity Value Units Method Reference Comment
Δr46.4 ± 2.0kcal/molHAL-HFCBrown and Connor, 1974MS

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Monteil, Raffin, et al., 1988
Monteil, Y.; Raffin, P.; Bouix, J., Thermochim. Acta, 1988, 125, 327. [all data]

Sunderlin, Wang, et al., 1992
Sunderlin, L.S.; Wang, D.; Squires, R.R., Metal Carbonyl Bond Strengths in Fe(CO)n- and Ni(CO)n-, J. Am. Chem. Soc., 1992, 114, 8, 2788, https://doi.org/10.1021/ja00034a004 . [all data]

McQuaid, Morris, et al., 1988
McQuaid, M.J.; Morris, K.; Gole, J.L., J. Am. Chem. Soc., 1988, 110, 5280. [all data]

Stevens, Feigerle, et al., 1982
Stevens, A.E.; Feigerle, C.S.; Lineberger, W.C., Laser Photoelectron Spectrometry of Ni(CO)n-, n=1-3, J. Am. Chem. Soc., 1982, 104, 19, 5026, https://doi.org/10.1021/ja00383a004 . [all data]

Compton and Stockdale, 1976
Compton, R.N.; Stockdale, J.A.D., Formation of gas phase negative ions in Fe(CO)5 and Ni(CO)4, Int. J. Mass Spectrom. Ion Phys., 1976, 22, 47. [all data]

Sykes and Townshend, 1955
Sykes, K.W.; Townshend, S.C., J. Chem. Soc., 1955, 2528.. [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds in Academic Press, New York, 1970. [all data]

Tolman, Reutter D.W., et al., 1976
Tolman, C.A.; Reutter D.W.; Seidel, W.C., J. Organometal. Chem., 1976, 117, C30. [all data]

Armentrout and Kickel, 1994
Armentrout, P.B.; Kickel, B.L., Gas Phase Thermochemistry of Transition Metal Ligand Systems: Reassessment of Values and Periodic Trends, in Organometallic Ion Chemistry, B. S. Freiser, ed, 1994. [all data]

Miller, Feigerle, et al., 1987
Miller, A.E.S.; Feigerle, C.S.; Lineberger, W.C., Laser photoelectron spectroscopy of CrH-, CoH-, and NiH-: Periodic trends in the electronic structure of the transition-metal hydrides, J. Chem. Phys., 1987, 86, 1549. [all data]

Ho, Polak, et al., 1993
Ho, J.; Polak, M.L.; Ervin, K.M.; Lineberger, W.C., Photoelectron Spectroscopy of Nickel Group Dimers - Ni2(-), Pd2(-), and Pt2(-), J. Chem. Phys., 1993, 99, 11, 8542, https://doi.org/10.1063/1.465577 . [all data]

Brown and Connor, 1974
Brown, D.L.S.; Connor, J.A., Skinner, H. A. J. Chem. Soc., Faraday Trans. I, 1974, 70, 1649. [all data]


Notes

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