nickel


Gas phase thermochemistry data

Go To: Top, Condensed phase thermochemistry data, Phase change data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Δfgas102.80kcal/molReviewChase, 1998Data last reviewed in December, 1976
Quantity Value Units Method Reference Comment
gas,1 bar43.544cal/mol*KReviewChase, 1998Data last reviewed in December, 1976

Gas Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

View plot Requires a JavaScript / HTML 5 canvas capable browser.

View table.

Temperature (K) 3156.584 to 6000.
A 6.484530
B -0.618442
C 0.070533
D 0.003633
E 0.009998
F 100.7310
G 51.18650
H 102.8000
ReferenceChase, 1998
Comment Data last reviewed in December, 1976

Condensed phase thermochemistry data

Go To: Top, Gas phase thermochemistry data, Phase change data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Δfliquid4.178kcal/molReviewChase, 1998Data last reviewed in December, 1976
Quantity Value Units Method Reference Comment
liquid,1 bar9.916cal/mol*KReviewChase, 1998Data last reviewed in December, 1976
Quantity Value Units Method Reference Comment
solid7.139cal/mol*KReviewChase, 1998Data last reviewed in December, 1976

Liquid Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

View plot Requires a JavaScript / HTML 5 canvas capable browser.

View table.

Temperature (K) 1728. to 3156.584
A 9.299960
B 0.000000
C 0.000000
D 0.000000
E 0.000000
F -0.650724
G 17.79910
H 4.177591
ReferenceChase, 1998
Comment Data last reviewed in December, 1976

Solid Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

View plot Requires a JavaScript / HTML 5 canvas capable browser.

View table.

Temperature (K) 298. to 600.600. to 700.700. to 1728.
A 3.272371298.28993.943210
B 19.71680-300.55214.481150
C -41.815200.000000-1.586961
D 38.623590.0000000.410439
E -0.022088-39.466210.447431
F -1.633281-188.5340-0.111777
G 6.613050289.887912.35080
H 0.0000000.0000000.000000
ReferenceChase, 1998Chase, 1998Chase, 1998
Comment Data last reviewed in December, 1976 Data last reviewed in December, 1976 Data last reviewed in December, 1976

Phase change data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (atm)
    T = temperature (K)

View plot Requires a JavaScript / HTML 5 canvas capable browser.

Temperature (K) A B C Reference Comment
2083. to 3005.5.9761216808.435-188.717Stull, 1947Coefficents calculated by NIST from author's data.

Ion clustering data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Nickel ion (1+) + nickel = (Nickel ion (1+) • nickel)

By formula: Ni+ + Ni = (Ni+ • Ni)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
48.8 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID

(Nickel ion (1+) • nickel) + nickel = (Nickel ion (1+) • 2nickel)

By formula: (Ni+ • Ni) + Ni = (Ni+ • 2Ni)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
56.2 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID

(Nickel ion (1+) • 2nickel) + nickel = (Nickel ion (1+) • 3nickel)

By formula: (Ni+ • 2Ni) + Ni = (Ni+ • 3Ni)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
47.6 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID

(Nickel ion (1+) • 3nickel) + nickel = (Nickel ion (1+) • 4nickel)

By formula: (Ni+ • 3Ni) + Ni = (Ni+ • 4Ni)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
53.2 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID

(Nickel ion (1+) • 4nickel) + nickel = (Nickel ion (1+) • 5nickel)

By formula: (Ni+ • 4Ni) + Ni = (Ni+ • 5Ni)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
65.7 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID

(Nickel ion (1+) • 5nickel) + nickel = (Nickel ion (1+) • 6nickel)

By formula: (Ni+ • 5Ni) + Ni = (Ni+ • 6Ni)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
70.8 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID

(Nickel ion (1+) • 6nickel) + nickel = (Nickel ion (1+) • 7nickel)

By formula: (Ni+ • 6Ni) + Ni = (Ni+ • 7Ni)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
63.4 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID

(Nickel ion (1+) • 7nickel) + nickel = (Nickel ion (1+) • 8nickel)

By formula: (Ni+ • 7Ni) + Ni = (Ni+ • 8Ni)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
67.6 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID

(Nickel ion (1+) • 8nickel) + nickel = (Nickel ion (1+) • 9nickel)

By formula: (Ni+ • 8Ni) + Ni = (Ni+ • 9Ni)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
67.6 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID

(Nickel ion (1+) • 9nickel) + nickel = (Nickel ion (1+) • 10nickel)

By formula: (Ni+ • 9Ni) + Ni = (Ni+ • 10Ni)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
70.0 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID

(Nickel ion (1+) • 10nickel) + nickel = (Nickel ion (1+) • 11nickel)

By formula: (Ni+ • 10Ni) + Ni = (Ni+ • 11Ni)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
80.1 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID

(Nickel ion (1+) • 11nickel) + nickel = (Nickel ion (1+) • 12nickel)

By formula: (Ni+ • 11Ni) + Ni = (Ni+ • 12Ni)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
84.1 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID

(Nickel ion (1+) • 12nickel) + nickel = (Nickel ion (1+) • 13nickel)

By formula: (Ni+ • 12Ni) + Ni = (Ni+ • 13Ni)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
71.5 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID

(Nickel ion (1+) • 13nickel) + nickel = (Nickel ion (1+) • 14nickel)

By formula: (Ni+ • 13Ni) + Ni = (Ni+ • 14Ni)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
79.8 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID

(Nickel ion (1+) • 14nickel) + nickel = (Nickel ion (1+) • 15nickel)

By formula: (Ni+ • 14Ni) + Ni = (Ni+ • 15Ni)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
80.8 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID

(Nickel ion (1+) • 15nickel) + nickel = (Nickel ion (1+) • 16nickel)

By formula: (Ni+ • 15Ni) + Ni = (Ni+ • 16Ni)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
84.6 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID

(Nickel ion (1+) • 16nickel) + nickel = (Nickel ion (1+) • 17nickel)

By formula: (Ni+ • 16Ni) + Ni = (Ni+ • 17Ni)

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
81.5 CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Stull, 1947
Stull, Daniel R., Vapor Pressure of Pure Substances. Organic and Inorganic Compounds, Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022 . [all data]

Armentrout and Kickel, 1994
Armentrout, P.B.; Kickel, B.L., Gas Phase Thermochemistry of Transition Metal Ligand Systems: Reassessment of Values and Periodic Trends, in Organometallic Ion Chemistry, B. S. Freiser, ed, 1994. [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Ion clustering data, References