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Liquid Phase Heat Capacity (Shomate Equation)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 1809. - 3133.345
A 11.00000
B -4.504460×10-9
C 1.456680×10-9
D -1.587071×10-10
E -1.970870×10-9
F -2.582560
G 17.33770
H 2.962481
ReferenceChase, 1998
Comment Data last reviewed in March, 1978
Temperature
(K)
Cp
(cal/mol*K)

(cal/mol*K)
-(G° - H°298.15)/T
(cal/mol*K)
H° - H°298.15
(kcal/mol)
1809.11.0023.8615.9214.35
1900.11.0024.4016.3215.35
2000.11.0024.9616.7316.45
2100.11.0025.5017.1417.55
2200.11.0026.0117.5318.65
2300.11.0026.5017.9119.75
2400.11.0026.9718.2820.85
2500.11.0027.4218.6321.95
2600.11.0027.8518.9823.05
2700.11.0028.2619.3224.15
2800.11.0028.6619.6425.25
2900.11.0029.0519.9626.35
3000.11.0029.4220.2727.45
3100.11.0029.7820.5728.55

References

Go To: Top, Liquid Phase Heat Capacity (Shomate Equation), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]


Notes

Go To: Top, Liquid Phase Heat Capacity (Shomate Equation), References