iron


Gas phase thermochemistry data

Go To: Top, Condensed phase thermochemistry data, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Δfgas415.47kJ/molReviewChase, 1998Data last reviewed in March, 1978
Quantity Value Units Method Reference Comment
gas,1 bar180.49J/mol*KReviewChase, 1998Data last reviewed in March, 1978

Gas Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

View plot Requires a JavaScript / HTML 5 canvas capable browser.

View table.

Temperature (K) 3133.345 to 6000.
A 11.29253
B 6.989707
C -1.110305
D 0.122354
E 5.689278
F 423.5380
G 206.3591
H 415.4716
ReferenceChase, 1998
Comment Data last reviewed in March, 1978

Condensed phase thermochemistry data

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Δfliquid12.40kJ/molReviewChase, 1998Data last reviewed in March, 1978
Quantity Value Units Method Reference Comment
liquid,1 bar34.76J/mol*KReviewChase, 1998Data last reviewed in March, 1978

Liquid Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

View plot Requires a JavaScript / HTML 5 canvas capable browser.

View table.

Temperature (K) 1809. to 3133.345
A 46.02400
B -1.884667×10-8
C 6.094750×10-9
D -6.640301×10-10
E -8.246121×10-9
F -10.80543
G 72.54094
H 12.39502
ReferenceChase, 1998
Comment Data last reviewed in March, 1978

Solid Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

View plot Requires a JavaScript / HTML 5 canvas capable browser.

View table.

Temperature (K) 298. to 700.700. to 1042.1042. to 1100.1100. to 1809.298. to 1809.
A 18.42868-57767.65-325.8859-776.738723.97449
B 24.64301137919.728.92876919.40058.367750
C -8.913720-122773.20.000000-383.71840.000277
D 9.66470638682.420.00000057.08148-0.000086
E -0.0126433993.080411.9629242.1369-0.000005
F -6.57302224078.67745.8231697.62340.268027
G 42.51488-87364.01241.8766-558.367462.06336
H 0.0000000.0000000.0000000.0000007.788015
ReferenceChase, 1998Chase, 1998Chase, 1998Chase, 1998Chase, 1998
Comment α-δ phase; Data last reviewed in March, 1978 α-δ phase; Data last reviewed in March, 1978 α-δ phase; Data last reviewed in March, 1978 α-δ phase; Data last reviewed in March, 1978 γ phase; Data last reviewed in March, 1978

Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
B - John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

CFeO (g) = Carbon monoxide (g) + iron (g)

By formula: CFeO (g) = CO (g) + Fe (g)

Quantity Value Units Method Reference Comment
Δr35. ± 15.kJ/molFA-SIFTSunderlin, Wang, et al., 1992MS
Δr<163.kJ/molN/AVenkataraman, Bandukwalla, et al., 1989Method: Velocity distributions of photofragments from Fe(CO)5.; MS
Δr87. ± 29.kJ/molN/AEngelking and Lineberger, 1979Please also see Compton and Stockdale, 1976. Method: LPS and collision with low energy electrons.; MS

Iron ion (1+) + iron = (Iron ion (1+) • iron)

By formula: Fe+ + Fe = (Fe+ • Fe)

Quantity Value Units Method Reference Comment
Δr260.kJ/molCIDLoh, Lian, et al., 1988gas phase; M
Δr261.kJ/molPDissTecklenberg, Bricker, et al., 1988gas phase; ΔrH>; M

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
268. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) • iron) + iron = (Iron ion (1+) • 2iron)

By formula: (Fe+ • Fe) + Fe = (Fe+ • 2Fe)

Quantity Value Units Method Reference Comment
Δr233.kJ/molPDissTecklenberg, Bricker, et al., 1988gas phase; ΔrH<; M

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
169. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) • 2iron) + iron = (Iron ion (1+) • 3iron)

By formula: (Fe+ • 2Fe) + Fe = (Fe+ • 3Fe)

Quantity Value Units Method Reference Comment
Δr174.kJ/molCIDLoh, Lian, et al., 1988gas phase; M

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
216. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(FeO- • 4294967295iron) + iron = FeO-

By formula: (FeO- • 4294967295Fe) + Fe = FeO-

Quantity Value Units Method Reference Comment
Δr395. ± 17.kJ/molN/ADrechsler, Boesl, et al., 1997gas phase; B
Δr395. ± 29.kJ/molTherEngelking and Lineberger, 1977gas phase; B

C12Fe3O12 (cr) = 12Carbon monoxide (g) + 3iron (cr)

By formula: C12Fe3O12 (cr) = 12CO (g) + 3Fe (cr)

Quantity Value Units Method Reference Comment
Δr516. ± 12.kJ/molTD-HFCConnor, Skinner, et al., 1973MS
Δr526. ± 13.kJ/molHAL-HFCConnor, Skinner, et al., 1973MS

C6H4FeO4 (l) = 4Carbon monoxide (g) + iron (cr) + Ethylene (g)

By formula: C6H4FeO4 (l) = 4CO (g) + Fe (cr) + C2H4 (g)

Quantity Value Units Method Reference Comment
Δr192.5 ± 8.4kJ/molHAL-HFCBrown, Connor, et al., 1976MS
Δr185.4kJ/molTD-HFCBrown, Connor, et al., 1976MS

C9Fe2O9 (cr) = 9Carbon monoxide (g) + 2iron (cr)

By formula: C9Fe2O9 (cr) = 9CO (g) + 2Fe (cr)

Quantity Value Units Method Reference Comment
Δr415.9 ± 4.3kJ/molTD-HFCConnor, Skinner, et al., 1973MS
Δr413.4 ± 4.9kJ/molHAL-HFCConnor, Skinner, et al., 1973MS

(Iron ion (1+) • 3Carbon monoxide • 2iron) + Carbon monoxide = (Iron ion (1+) • 4Carbon monoxide • 2iron)

By formula: (Fe+ • 3CO • 2Fe) + CO = (Fe+ • 4CO • 2Fe)

Quantity Value Units Method Reference Comment
Δr238.kJ/molPDissTecklenberg, Bricker, et al., 1988gas phase; ΔrH<; M

(Iron ion (1+) • 10iron) + iron = (Iron ion (1+) • 11iron)

By formula: (Fe+ • 10Fe) + Fe = (Fe+ • 11Fe)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
334. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) • 11iron) + iron = (Iron ion (1+) • 12iron)

By formula: (Fe+ • 11Fe) + Fe = (Fe+ • 12Fe)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
408. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) • 12iron) + iron = (Iron ion (1+) • 13iron)

By formula: (Fe+ • 12Fe) + Fe = (Fe+ • 13Fe)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
281. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) • 13iron) + iron = (Iron ion (1+) • 14iron)

By formula: (Fe+ • 13Fe) + Fe = (Fe+ • 14Fe)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
377. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) • 14iron) + iron = (Iron ion (1+) • 15iron)

By formula: (Fe+ • 14Fe) + Fe = (Fe+ • 15Fe)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
319. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) • 15iron) + iron = (Iron ion (1+) • 16iron)

By formula: (Fe+ • 15Fe) + Fe = (Fe+ • 16Fe)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
323. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) • 16iron) + iron = (Iron ion (1+) • 17iron)

By formula: (Fe+ • 16Fe) + Fe = (Fe+ • 17Fe)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
311. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) • 17iron) + iron = (Iron ion (1+) • 18iron)

By formula: (Fe+ • 17Fe) + Fe = (Fe+ • 18Fe)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
373. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) • 9iron) + iron = (Iron ion (1+) • 10iron)

By formula: (Fe+ • 9Fe) + Fe = (Fe+ • 10Fe)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
308. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) • 3iron) + iron = (Iron ion (1+) • 4iron)

By formula: (Fe+ • 3Fe) + Fe = (Fe+ • 4Fe)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
260. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) • 4iron) + iron = (Iron ion (1+) • 5iron)

By formula: (Fe+ • 4Fe) + Fe = (Fe+ • 5Fe)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
315. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) • 5iron) + iron = (Iron ion (1+) • 6iron)

By formula: (Fe+ • 5Fe) + Fe = (Fe+ • 6Fe)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
320. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) • 6iron) + iron = (Iron ion (1+) • 7iron)

By formula: (Fe+ • 6Fe) + Fe = (Fe+ • 7Fe)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
252. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) • 7iron) + iron = (Iron ion (1+) • 8iron)

By formula: (Fe+ • 7Fe) + Fe = (Fe+ • 8Fe)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
281. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) • 8iron) + iron = (Iron ion (1+) • 9iron)

By formula: (Fe+ • 8Fe) + Fe = (Fe+ • 9Fe)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
284. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Iron ion (1+) • iron) + Carbon monoxide = (Iron ion (1+) • Carbon monoxide • iron)

By formula: (Fe+ • Fe) + CO = (Fe+ • CO • Fe)

Quantity Value Units Method Reference Comment
Δr245.kJ/molPDissTecklenberg, Bricker, et al., 1988gas phase; ΔrH<; M

(CAS Reg. No. 64899-88-3 • 4294967295iron) + iron = CAS Reg. No. 64899-88-3

By formula: (CAS Reg. No. 64899-88-3 • 4294967295Fe) + Fe = CAS Reg. No. 64899-88-3

Quantity Value Units Method Reference Comment
Δr180. ± 29.kJ/molN/AStevens, Feigerle, et al., 1983gas phase; B

C12FeO12Ru2 (cr) = 12Carbon monoxide (g) + iron (cr) + 2ruthenium (cr)

By formula: C12FeO12Ru2 (cr) = 12CO (g) + Fe (cr) + 2Ru (cr)

Quantity Value Units Method Reference Comment
Δr565. ± 10.kJ/molTD-HFCBaev, Connor, et al., 1981MS

C12Fe2O12Ru (cr) = 12Carbon monoxide (g) + 2iron (cr) + ruthenium (cr)

By formula: C12Fe2O12Ru (cr) = 12CO (g) + 2Fe (cr) + Ru (cr)

Quantity Value Units Method Reference Comment
Δr494. ± 7.kJ/molTD-HFCBaev, Connor, et al., 1981MS

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Sunderlin, Wang, et al., 1992
Sunderlin, L.S.; Wang, D.; Squires, R.R., Metal Carbonyl Bond Strengths in Fe(CO)n- and Ni(CO)n-, J. Am. Chem. Soc., 1992, 114, 8, 2788, https://doi.org/10.1021/ja00034a004 . [all data]

Venkataraman, Bandukwalla, et al., 1989
Venkataraman, B.K.; Bandukwalla, G.; Zhang, Z.; Vernon, M., J. Chem. Phys., 1989, 90, 5510. [all data]

Engelking and Lineberger, 1979
Engelking, P.C.; Lineberger, W.C., Laser photoelectron spectrometry of the negative ions of iron and iron carbonyls. Electron affinity determination for the series Fe(CO)n,n=0,1,2,3,4, J. Am. Chem. Soc., 1979, 101, 5569. [all data]

Compton and Stockdale, 1976
Compton, R.N.; Stockdale, J.A.D., Formation of gas phase negative ions in Fe(CO)5 and Ni(CO)4, Int. J. Mass Spectrom. Ion Phys., 1976, 22, 47. [all data]

Loh, Lian, et al., 1988
Loh, S.K.; Lian, L.; Hales, D.A.; Armentrout, P.B., Collision - Induced Dissociation Processes of Nb4+ and Fe4+: Fission vs Evaporation, J. Chem. Phys., 1988, 89, 1, 610, https://doi.org/10.1063/1.455455 . [all data]

Tecklenberg, Bricker, et al., 1988
Tecklenberg, R.E.; Bricker, D.L.; Russel, D.H., Laser - Ion Beam Photodissociation Studies of Ionic Cluster Fragments of Iron Carbonyls: Fe(x)(CO)y+ (x = 1 - 3; y = 0 - 6), Organometallics, 1988, 7, 12, 2506, https://doi.org/10.1021/om00102a013 . [all data]

Armentrout and Kickel, 1994
Armentrout, P.B.; Kickel, B.L., Gas Phase Thermochemistry of Transition Metal Ligand Systems: Reassessment of Values and Periodic Trends, in Organometallic Ion Chemistry, B. S. Freiser, ed, 1994. [all data]

Drechsler, Boesl, et al., 1997
Drechsler, G.; Boesl, U.; Bassmann, C.; Schlag, E.W., Mass selected anion-zero kinetic energy photoelectron spectroscopy (anion-ZEKE): Ground and low excited states of FeO, J. Chem. Phys., 1997, 107, 7, 2284-2291, https://doi.org/10.1063/1.474622 . [all data]

Engelking and Lineberger, 1977
Engelking, P.C.; Lineberger, W.C., Laser photoelecton spectrometry of FeO-: Electron affinity, electronic state separations, and ground state vibrations of iron oxide, and a new ground state assignment, J. Chem. Phys., 1977, 66, 5054. [all data]

Connor, Skinner, et al., 1973
Connor, J.A.; Skinner, H.A.; Virmani, Y., High temperature microcalorimetric studies of the thermal decomposition and iodination of polynuclear carbonyls of Fe, Co, Ru, Rh, Re, Os and Ir, Faraday Symp. Chem. Soc., 1973, 8, 18, https://doi.org/10.1039/fs9730800018 . [all data]

Brown, Connor, et al., 1976
Brown, D.L.S.; Connor, J.A.; Leung, M.L.; Paz-Andrade, M.I.; Skinner, H.A., J. Organometal. Chem., 1976, 110, 79. [all data]

Stevens, Feigerle, et al., 1983
Stevens, A.E.; Feigerle, C.S.; Lineberger, W.C., Laser photoelectron spectroscopy of MnH- and FeH-: Electronic structures of the metal hydrides, identification of a low spin excited state of MnH, J. Chem. Phys., 1983, 78, 5420. [all data]

Baev, Connor, et al., 1981
Baev, A.K.; Connor, J.A.; El-Saied, N.I.; Skinner H.A., J. Organometal. Chem., 1981, 213, 151. [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, References