Aluminum

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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

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Individual Reactions

C72H100CoN18O17P (solution) = Cyanocobalamin (solution) + Aluminum (solution)

By formula: C72H100CoN18O17P (solution) = C63H88CoN14O14P (solution) + Al (solution)

Quantity Value Units Method Reference Comment
Δr124. ± 20.kJ/molAVGN/AAverage of 5 out of 6 values; Individual data points

(CAS Reg. No. 158445-17-1 • 4294967295Aluminum) + Aluminum = CAS Reg. No. 158445-17-1

By formula: (CAS Reg. No. 158445-17-1 • 4294967295Al) + Al = CAS Reg. No. 158445-17-1

Quantity Value Units Method Reference Comment
Δr426.3 ± 7.5kJ/molN/ANakajima, Taguwa, et al., 1995gas phase; Vertical Detachment Energy: 2.75±0.04 eV; B

(CAS Reg. No. 161173-70-2 • 4294967295Aluminum) + Aluminum = CAS Reg. No. 161173-70-2

By formula: (CAS Reg. No. 161173-70-2 • 4294967295Al) + Al = CAS Reg. No. 161173-70-2

Quantity Value Units Method Reference Comment
Δr168. ± 22.kJ/molN/ANakajima, Taguwa, et al., 1995gas phase; Vertical Detachment Energy: 2.14±0.11 eV; B

(Aluminum ion (1+) • 10Aluminum) + Aluminum = (Aluminum ion (1+) • 11Aluminum)

By formula: (Al+ • 10Al) + Al = (Al+ • 11Al)

Quantity Value Units Method Reference Comment
Δr300.kJ/molPDissJarrold, Ray, et al., 1990gas phase; from graph; M

(Aluminum ion (1+) • 11Aluminum) + Aluminum = (Aluminum ion (1+) • 12Aluminum)

By formula: (Al+ • 11Al) + Al = (Al+ • 12Al)

Quantity Value Units Method Reference Comment
Δr340.kJ/molPDissJarrold, Ray, et al., 1990gas phase; from graph; M

(Aluminum ion (1+) • 12Aluminum) + Aluminum = (Aluminum ion (1+) • 13Aluminum)

By formula: (Al+ • 12Al) + Al = (Al+ • 13Al)

Quantity Value Units Method Reference Comment
Δr300.kJ/molPDissJarrold, Ray, et al., 1990gas phase; from graph; M

(Aluminum ion (1+) • 13Aluminum) + Aluminum = (Aluminum ion (1+) • 14Aluminum)

By formula: (Al+ • 13Al) + Al = (Al+ • 14Al)

Quantity Value Units Method Reference Comment
Δr250.kJ/molPDissJarrold, Ray, et al., 1990gas phase; from graph; M

(Aluminum ion (1+) • 14Aluminum) + Aluminum = (Aluminum ion (1+) • 15Aluminum)

By formula: (Al+ • 14Al) + Al = (Al+ • 15Al)

Quantity Value Units Method Reference Comment
Δr280.kJ/molPDissJarrold, Ray, et al., 1990gas phase; from graph; M

(Aluminum ion (1+) • 15Aluminum) + Aluminum = (Aluminum ion (1+) • 16Aluminum)

By formula: (Al+ • 15Al) + Al = (Al+ • 16Al)

Quantity Value Units Method Reference Comment
Δr290.kJ/molPDissJarrold, Ray, et al., 1990gas phase; from graph; M

(Aluminum ion (1+) • 9Aluminum) + Aluminum = (Aluminum ion (1+) • 10Aluminum)

By formula: (Al+ • 9Al) + Al = (Al+ • 10Al)

Quantity Value Units Method Reference Comment
Δr280.kJ/molPDissJarrold, Ray, et al., 1990gas phase; from graph; M

(Aluminum ion (1+) • 6Aluminum) + Aluminum = (Aluminum ion (1+) • 7Aluminum)

By formula: (Al+ • 6Al) + Al = (Al+ • 7Al)

Quantity Value Units Method Reference Comment
Δr180.kJ/molPDissJarrold, Ray, et al., 1990gas phase; from graph; M

(Aluminum ion (1+) • 8Aluminum) + Aluminum = (Aluminum ion (1+) • 9Aluminum)

By formula: (Al+ • 8Al) + Al = (Al+ • 9Al)

Quantity Value Units Method Reference Comment
Δr270.kJ/molPDissJarrold, Ray, et al., 1990gas phase; from graph; M

(CAS Reg. No. 56448-64-7 • 4294967295Aluminum) + Aluminum = CAS Reg. No. 56448-64-7

By formula: (CAS Reg. No. 56448-64-7 • 4294967295Al) + Al = CAS Reg. No. 56448-64-7

Quantity Value Units Method Reference Comment
Δr305. ± 31.kJ/molN/AVillalta and Leopold, 2009gas phase; B

(CAS Reg. No. 166899-79-2 • 4294967295Aluminum) + Aluminum = CAS Reg. No. 166899-79-2

By formula: (CAS Reg. No. 166899-79-2 • 4294967295Al) + Al = CAS Reg. No. 166899-79-2

Quantity Value Units Method Reference Comment
Δr177. ± 32.kJ/molN/ANakajima, Zhang, et al., 1995gas phase; B

(AlO- • 4294967295Aluminum) + Aluminum = AlO-

By formula: (AlO- • 4294967295Al) + Al = AlO-

Quantity Value Units Method Reference Comment
Δr622. ± 27.kJ/molN/ADesai, Wu, et al., 1996gas phase; B

(Aluminum ion (1+) • 5Aluminum) + Aluminum = (Aluminum ion (1+) • 6Aluminum)

By formula: (Al+ • 5Al) + Al = (Al+ • 6Al)

Quantity Value Units Method Reference Comment
Δr431.4kJ/molCIDHanley, Ruatta, et al., 1987gas phase; M

(Aluminum ion (1+) • 2Aluminum) + Aluminum = (Aluminum ion (1+) • 3Aluminum)

By formula: (Al+ • 2Al) + Al = (Al+ • 3Al)

Quantity Value Units Method Reference Comment
Δr196.kJ/molCIDHanley, Ruatta, et al., 1987gas phase; M

(Aluminum ion (1+) • 3Aluminum) + Aluminum = (Aluminum ion (1+) • 4Aluminum)

By formula: (Al+ • 3Al) + Al = (Al+ • 4Al)

Quantity Value Units Method Reference Comment
Δr248.kJ/molCIDHanley, Ruatta, et al., 1987gas phase; M

(Aluminum ion (1+) • 4Aluminum) + Aluminum = (Aluminum ion (1+) • 5Aluminum)

By formula: (Al+ • 4Al) + Al = (Al+ • 5Al)

Quantity Value Units Method Reference Comment
Δr231.kJ/molCIDHanley, Ruatta, et al., 1987gas phase; M

(Aluminum ion (1+) • Aluminum) + Aluminum = (Aluminum ion (1+) • 2Aluminum)

By formula: (Al+ • Al) + Al = (Al+ • 2Al)

Quantity Value Units Method Reference Comment
Δr108.kJ/molCIDHanley, Ruatta, et al., 1987gas phase; M

Aluminum ion (1+) + Aluminum = (Aluminum ion (1+) • Aluminum)

By formula: Al+ + Al = (Al+ • Al)

Quantity Value Units Method Reference Comment
Δr87.0kJ/molCIDHanley, Ruatta, et al., 1987gas phase; M

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Nakajima, Taguwa, et al., 1995
Nakajima, A.; Taguwa, T.; Nakao, K.; Hoshino, K.; Iwata, S.; Kaya, K., Photoelectron Spectroscopy of AlnS1- Clusters (n=1-9), J. Chem. Phys., 1995, 102, 2, 660, https://doi.org/10.1063/1.469178 . [all data]

Jarrold, Ray, et al., 1990
Jarrold, M.F.; Ray, U.; Bower, J.E.; Creegan, K.M., Photodissociation of Metal Cluster Ions. Dissociation Energies and Optical Spectroscopy, J. Chem. Soc. Faraday Trans., 1990, 86, 13, 2537, https://doi.org/10.1039/ft9908602537 . [all data]

Villalta and Leopold, 2009
Villalta, P.W.; Leopold, D.G., A study of the ground and excited states of Al-3 and Al-3(-). I. 488 nm anion photoelectron spectrum, J. Chem. Phys., 2009, 130, 2, 024303, https://doi.org/10.1063/1.2973625 . [all data]

Nakajima, Zhang, et al., 1995
Nakajima, A.; Zhang, N.; Kawamata, H.; Hayase, T.; Nakao, K.; Kaya, K., Photoelectron spectroscopy and mass distributions of aluminum-sulfur cluster anions (AlnSm-), Chem. Phys. Lett., 1995, 241, 4, 295, https://doi.org/10.1016/0009-2614(95)00653-L . [all data]

Desai, Wu, et al., 1996
Desai, S.R.; Wu, H.; Wang, L.-S., Vibrationally Resolved Photoelectron Spectroscopy of AlO- and AlO2-, Int. J. Mass Spectrom. Ion Proc., 1996, 159, 1-3, 75, https://doi.org/10.1016/S0168-1176(96)04443-6 . [all data]

Hanley, Ruatta, et al., 1987
Hanley, L.; Ruatta, S.A.; Anderson, S.L., Collision - Induced Dissciation of Aluminum Cluster Ions: Fragmentation Patterns, Bond Energies, and Structures for Al2+ - Al7+, J. Chem. Phys., 1987, 87, 1, 260, https://doi.org/10.1063/1.453623 . [all data]


Notes

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