Aluminum

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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C72H100CoN18O17P (solution) = Cyanocobalamin (solution) + Aluminum (solution)

By formula: C72H100CoN18O17P (solution) = C63H88CoN14O14P (solution) + Al (solution)

Quantity Value Units Method Reference Comment
Δr30. ± 4.kcal/molAVGN/AAverage of 5 out of 6 values; Individual data points

(CAS Reg. No. 158445-17-1 • 4294967295Aluminum) + Aluminum = CAS Reg. No. 158445-17-1

By formula: (CAS Reg. No. 158445-17-1 • 4294967295Al) + Al = CAS Reg. No. 158445-17-1

Quantity Value Units Method Reference Comment
Δr101.9 ± 1.8kcal/molN/ANakajima, Taguwa, et al., 1995gas phase; Vertical Detachment Energy: 2.75±0.04 eV; B

(CAS Reg. No. 161173-70-2 • 4294967295Aluminum) + Aluminum = CAS Reg. No. 161173-70-2

By formula: (CAS Reg. No. 161173-70-2 • 4294967295Al) + Al = CAS Reg. No. 161173-70-2

Quantity Value Units Method Reference Comment
Δr40.2 ± 5.2kcal/molN/ANakajima, Taguwa, et al., 1995gas phase; Vertical Detachment Energy: 2.14±0.11 eV; B

(Aluminum ion (1+) • 10Aluminum) + Aluminum = (Aluminum ion (1+) • 11Aluminum)

By formula: (Al+ • 10Al) + Al = (Al+ • 11Al)

Quantity Value Units Method Reference Comment
Δr72.kcal/molPDissJarrold, Ray, et al., 1990gas phase; from graph; M

(Aluminum ion (1+) • 11Aluminum) + Aluminum = (Aluminum ion (1+) • 12Aluminum)

By formula: (Al+ • 11Al) + Al = (Al+ • 12Al)

Quantity Value Units Method Reference Comment
Δr81.kcal/molPDissJarrold, Ray, et al., 1990gas phase; from graph; M

(Aluminum ion (1+) • 12Aluminum) + Aluminum = (Aluminum ion (1+) • 13Aluminum)

By formula: (Al+ • 12Al) + Al = (Al+ • 13Al)

Quantity Value Units Method Reference Comment
Δr72.kcal/molPDissJarrold, Ray, et al., 1990gas phase; from graph; M

(Aluminum ion (1+) • 13Aluminum) + Aluminum = (Aluminum ion (1+) • 14Aluminum)

By formula: (Al+ • 13Al) + Al = (Al+ • 14Al)

Quantity Value Units Method Reference Comment
Δr60.kcal/molPDissJarrold, Ray, et al., 1990gas phase; from graph; M

(Aluminum ion (1+) • 14Aluminum) + Aluminum = (Aluminum ion (1+) • 15Aluminum)

By formula: (Al+ • 14Al) + Al = (Al+ • 15Al)

Quantity Value Units Method Reference Comment
Δr67.kcal/molPDissJarrold, Ray, et al., 1990gas phase; from graph; M

(Aluminum ion (1+) • 15Aluminum) + Aluminum = (Aluminum ion (1+) • 16Aluminum)

By formula: (Al+ • 15Al) + Al = (Al+ • 16Al)

Quantity Value Units Method Reference Comment
Δr69.kcal/molPDissJarrold, Ray, et al., 1990gas phase; from graph; M

(Aluminum ion (1+) • 9Aluminum) + Aluminum = (Aluminum ion (1+) • 10Aluminum)

By formula: (Al+ • 9Al) + Al = (Al+ • 10Al)

Quantity Value Units Method Reference Comment
Δr67.kcal/molPDissJarrold, Ray, et al., 1990gas phase; from graph; M

(Aluminum ion (1+) • 6Aluminum) + Aluminum = (Aluminum ion (1+) • 7Aluminum)

By formula: (Al+ • 6Al) + Al = (Al+ • 7Al)

Quantity Value Units Method Reference Comment
Δr44.kcal/molPDissJarrold, Ray, et al., 1990gas phase; from graph; M

(Aluminum ion (1+) • 8Aluminum) + Aluminum = (Aluminum ion (1+) • 9Aluminum)

By formula: (Al+ • 8Al) + Al = (Al+ • 9Al)

Quantity Value Units Method Reference Comment
Δr65.kcal/molPDissJarrold, Ray, et al., 1990gas phase; from graph; M

(CAS Reg. No. 56448-64-7 • 4294967295Aluminum) + Aluminum = CAS Reg. No. 56448-64-7

By formula: (CAS Reg. No. 56448-64-7 • 4294967295Al) + Al = CAS Reg. No. 56448-64-7

Quantity Value Units Method Reference Comment
Δr72.8 ± 7.5kcal/molN/AVillalta and Leopold, 2009gas phase; B

(CAS Reg. No. 166899-79-2 • 4294967295Aluminum) + Aluminum = CAS Reg. No. 166899-79-2

By formula: (CAS Reg. No. 166899-79-2 • 4294967295Al) + Al = CAS Reg. No. 166899-79-2

Quantity Value Units Method Reference Comment
Δr42.3 ± 7.6kcal/molN/ANakajima, Zhang, et al., 1995gas phase; B

(AlO- • 4294967295Aluminum) + Aluminum = AlO-

By formula: (AlO- • 4294967295Al) + Al = AlO-

Quantity Value Units Method Reference Comment
Δr148.6 ± 6.4kcal/molN/ADesai, Wu, et al., 1996gas phase; B

(Aluminum ion (1+) • 5Aluminum) + Aluminum = (Aluminum ion (1+) • 6Aluminum)

By formula: (Al+ • 5Al) + Al = (Al+ • 6Al)

Quantity Value Units Method Reference Comment
Δr103.1kcal/molCIDHanley, Ruatta, et al., 1987gas phase; M

(Aluminum ion (1+) • 2Aluminum) + Aluminum = (Aluminum ion (1+) • 3Aluminum)

By formula: (Al+ • 2Al) + Al = (Al+ • 3Al)

Quantity Value Units Method Reference Comment
Δr46.8kcal/molCIDHanley, Ruatta, et al., 1987gas phase; M

(Aluminum ion (1+) • 3Aluminum) + Aluminum = (Aluminum ion (1+) • 4Aluminum)

By formula: (Al+ • 3Al) + Al = (Al+ • 4Al)

Quantity Value Units Method Reference Comment
Δr59.3kcal/molCIDHanley, Ruatta, et al., 1987gas phase; M

(Aluminum ion (1+) • 4Aluminum) + Aluminum = (Aluminum ion (1+) • 5Aluminum)

By formula: (Al+ • 4Al) + Al = (Al+ • 5Al)

Quantity Value Units Method Reference Comment
Δr55.3kcal/molCIDHanley, Ruatta, et al., 1987gas phase; M

(Aluminum ion (1+) • Aluminum) + Aluminum = (Aluminum ion (1+) • 2Aluminum)

By formula: (Al+ • Al) + Al = (Al+ • 2Al)

Quantity Value Units Method Reference Comment
Δr25.8kcal/molCIDHanley, Ruatta, et al., 1987gas phase; M

Aluminum ion (1+) + Aluminum = (Aluminum ion (1+) • Aluminum)

By formula: Al+ + Al = (Al+ • Al)

Quantity Value Units Method Reference Comment
Δr20.8kcal/molCIDHanley, Ruatta, et al., 1987gas phase; M

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Nakajima, Taguwa, et al., 1995
Nakajima, A.; Taguwa, T.; Nakao, K.; Hoshino, K.; Iwata, S.; Kaya, K., Photoelectron Spectroscopy of AlnS1- Clusters (n=1-9), J. Chem. Phys., 1995, 102, 2, 660, https://doi.org/10.1063/1.469178 . [all data]

Jarrold, Ray, et al., 1990
Jarrold, M.F.; Ray, U.; Bower, J.E.; Creegan, K.M., Photodissociation of Metal Cluster Ions. Dissociation Energies and Optical Spectroscopy, J. Chem. Soc. Faraday Trans., 1990, 86, 13, 2537, https://doi.org/10.1039/ft9908602537 . [all data]

Villalta and Leopold, 2009
Villalta, P.W.; Leopold, D.G., A study of the ground and excited states of Al-3 and Al-3(-). I. 488 nm anion photoelectron spectrum, J. Chem. Phys., 2009, 130, 2, 024303, https://doi.org/10.1063/1.2973625 . [all data]

Nakajima, Zhang, et al., 1995
Nakajima, A.; Zhang, N.; Kawamata, H.; Hayase, T.; Nakao, K.; Kaya, K., Photoelectron spectroscopy and mass distributions of aluminum-sulfur cluster anions (AlnSm-), Chem. Phys. Lett., 1995, 241, 4, 295, https://doi.org/10.1016/0009-2614(95)00653-L . [all data]

Desai, Wu, et al., 1996
Desai, S.R.; Wu, H.; Wang, L.-S., Vibrationally Resolved Photoelectron Spectroscopy of AlO- and AlO2-, Int. J. Mass Spectrom. Ion Proc., 1996, 159, 1-3, 75, https://doi.org/10.1016/S0168-1176(96)04443-6 . [all data]

Hanley, Ruatta, et al., 1987
Hanley, L.; Ruatta, S.A.; Anderson, S.L., Collision - Induced Dissciation of Aluminum Cluster Ions: Fragmentation Patterns, Bond Energies, and Structures for Al2+ - Al7+, J. Chem. Phys., 1987, 87, 1, 260, https://doi.org/10.1063/1.453623 . [all data]


Notes

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