2,2,5,5-tetramethyl-1-aza-2,5-disilacyclopentane


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

De-protonation reactions

C6H16NSi2- + Hydrogen cation = 2,2,5,5-tetramethyl-1-aza-2,5-disilacyclopentane

By formula: C6H16NSi2- + H+ = C6H17NSi2

Quantity Value Units Method Reference Comment
Δr1536. ± 8.8kJ/molG+TSHiggins, Hinde, et al., 2001gas phase
Quantity Value Units Method Reference Comment
Δr1504. ± 8.4kJ/molIMREHiggins, Hinde, et al., 2001gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Higgins, Hinde, et al., 2001
Higgins, P.R.; Hinde, R.J.; Grimm, D.T.; Bloor, J.E.; Bartmess, J.E., The geometric dependence of acidity: hexamethyldisilazide anion, Int. J. Mass Spectrom., 2001, 210, 231-240, https://doi.org/10.1016/S1387-3806(01)00453-5 . [all data]


Notes

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