1-Methoxydecane

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Gas phase thermochemistry data

Go To: Top, Condensed phase thermochemistry data, Phase change data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfgas-91.08 ± 0.51kcal/molCcbFenwick, Harrop, et al., 1975 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfliquid-105.97 ± 0.51kcal/molCcbFenwick, Harrop, et al., 1975ALS
Quantity Value Units Method Reference Comment
Δcliquid-1748.37kcal/molCcbFenwick, Harrop, et al., 1975Corresponding Δfliquid = -105.97 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
Quantity Value Units Method Reference Comment
liquid117.2cal/mol*KN/AAndon and Martin, 1975DH

Constant pressure heat capacity of liquid

Cp,liquid (cal/mol*K) Temperature (K) Reference Comment
88.62298.15Andon and Martin, 1975T = 12 to 350 K.; DH
88.55298.15Fenwick, Harrop, et al., 1975, 2DH

Phase change data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Ttriple243.42KN/AAndon and Martin, 1975, 2Uncertainty assigned by TRC = 0.07 K; TRC
Quantity Value Units Method Reference Comment
Δvap14.9kcal/molN/AMajer and Svoboda, 1985 
Δvap15.0kcal/molN/AAmbrose, Ellender, et al., 1976Based on data from 341. to 471. K.; AC
Δvap14.89 ± 0.07kcal/molCFenwick, Harrop, et al., 1975ALS
Δvap14.9 ± 0.07kcal/molCFenwick, Harrop, et al., 1975AC

Enthalpy of vaporization

ΔvapH (kcal/mol) Temperature (K) Method Reference Comment
13.6356.AStephenson and Malanowski, 1987Based on data from 341. to 429. K.; AC
13.6356.AStephenson and Malanowski, 1987Based on data from 341. to 471. K. See also Ambrose, Ellender, et al., 1976.; AC
10.9489.N/AAmbrose, Ellender, et al., 1976Based on data from 341. to 471. K.; AC

Enthalpy of fusion

ΔfusH (kcal/mol) Temperature (K) Reference Comment
7.5813243.47Andon and Martin, 1975DH
7.579243.5Domalski and Hearing, 1996AC

Entropy of fusion

ΔfusS (cal/mol*K) Temperature (K) Reference Comment
31.145243.47Andon and Martin, 1975DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Fenwick, Harrop, et al., 1975
Fenwick, J.O.; Harrop, D.; Head, A.J., Thermodynamic properties of organic oxygen compounds. 41. Enthalpies of formation of eight ethers, J. Chem. Thermodyn., 1975, 7, 943-954. [all data]

Andon and Martin, 1975
Andon, R.J.L.; Martin, J.F., Thermodynamic properties of organic oxygen compounds. 40. Heat capacity and entropy of six ethers, J. Chem. Thermodynam., 1975, 7, 593-606. [all data]

Fenwick, Harrop, et al., 1975, 2
Fenwick, J.O.; Harrop, D.; Head, A.J., Thermodynamic properties of organic oxygen compounds. 41. Enthalpies of formation of eight ethers, J. Chem. Thermodynam., 1975, 7, 944-954. [all data]

Andon and Martin, 1975, 2
Andon, R.J.L.; Martin, J.F., Thermodynamic Properties of Organic Oxygen Compounds 40. Heat Capacity and Entropy of Six Ethers, J. Chem. Thermodyn., 1975, 7, 593. [all data]

Majer and Svoboda, 1985
Majer, V.; Svoboda, V., Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]

Ambrose, Ellender, et al., 1976
Ambrose, D.; Ellender, J.H.; Sprake, C.H.S.; Townsend, R., Thermodynamic properties of organic oxygen compounds XLIII. Vapour pressures of some ethers, The Journal of Chemical Thermodynamics, 1976, 8, 2, 165-178, https://doi.org/10.1016/0021-9614(76)90090-2 . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, References