2-Dodecene, (Z)-


Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin D.HENNEBERG, MAX-PLANCK INSTITUTE, MULHEIM, WEST GERMANY
NIST MS number 61838

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Gas Chromatography

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Kovats' RI, non-polar column, isothermal

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Column type Active phase Temperature (C) I Reference Comment
CapillarySqualane100.1202.Heinzen, Soares, et al., 1999 
CapillarySE-30120.1211.Gusev, Sokolov, et al., 1989H2; Column length: 40. m; Column diameter: 0.30 mm
CapillaryOV-101110.1211.Rang, Kuningas, et al., 1987He; Column length: 50. m; Column diameter: 0.25 mm
CapillaryOV-160.1222.Nijs and Jacobs, 1981He; Column length: 150. m; Column diameter: 0.50 mm
CapillarySqualane100.1202.Sojak, Hrivnak, et al., 1973 
CapillarySqualane115.1202.Sojak, Hrivnak, et al., 1973 
CapillarySqualane130.1203.Sojak, Hrivnak, et al., 1973 
CapillarySqualane86.1202.Sojak, Hrivnak, et al., 1973 
CapillaryApiezon L120.1210.5Eisen, Orav, et al., 1972Column length: 45. m; Column diameter: 0.25 mm
CapillarySqualane100.1201.7Soják and Hrivnák, 1972H2; Column length: 200. m; Column diameter: 0.2 mm
CapillarySqualane115.1202.3Soják and Hrivnák, 1972H2; Column length: 200. m; Column diameter: 0.2 mm
CapillarySqualane130.1202.8Soják and Hrivnák, 1972H2; Column length: 200. m; Column diameter: 0.2 mm
CapillarySqualane86.1201.1Soják and Hrivnák, 1972H2; Column length: 200. m; Column diameter: 0.2 mm

Kovats' RI, polar column, isothermal

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Column type Active phase Temperature (C) I Reference Comment
CapillaryPEG-20M80.1262.3Orav, Kuningas, et al., 199450. m/0.2 mm/0.13 μm, He
CapillaryPEG-20M80.1265.7Orav, Kuningas, et al., 199450. m/0.2 mm/0.19 μm, He
CapillaryPEG-20M80.1267.2Orav, Kuningas, et al., 199450. m/0.2 mm/0.22 μm, He
CapillaryPEG 4000100.1279.Rang, Orav, et al., 1988 
CapillaryPEG 4000110.1280.Rang, Orav, et al., 1988 
CapillaryPEG 4000120.1281.Rang, Orav, et al., 1988 
CapillaryPEG 4000140.1283.Rang, Orav, et al., 1988 
CapillaryPEG 4000160.1285.Rang, Orav, et al., 1988 
CapillaryPEG-20M100.1274.Rang, Orav, et al., 1988 
CapillaryPEG-20M110.1275.Rang, Orav, et al., 1988 
CapillaryPEG-20M120.1275.Rang, Orav, et al., 1988 
CapillaryPEG-20M130.1276.Rang, Orav, et al., 1988 
CapillaryPEG-20M140.1278.Rang, Orav, et al., 1988 
CapillaryPEG-20M90.1272.Rang, Orav, et al., 1988 
CapillaryPEG 4000100.1279.Rang, Kuningas, et al., 1977Column diameter: 0.25 mm
CapillaryPEG 4000120.1281.Rang, Kuningas, et al., 1977Column diameter: 0.25 mm
CapillaryPEG 4000140.1283.Rang, Kuningas, et al., 1977Column diameter: 0.25 mm
CapillaryPEG 4000160.1285.Rang, Kuningas, et al., 1977Column diameter: 0.25 mm
CapillaryPolyethylene Glycol 4000100.1281.5Eisen, Orav, et al., 1972Column length: 80. m; Column diameter: 0.25 mm
CapillaryPolyethylene Glycol 4000120.1283.3Eisen, Orav, et al., 1972Column length: 80. m; Column diameter: 0.25 mm
CapillaryPEG 4000100.1281.5Orav and Eisen, 1972Column length: 80. m; Column diameter: 0.25 mm
CapillaryPEG 4000120.1283.3Orav and Eisen, 1972Column length: 80. m; Column diameter: 0.25 mm

Van Den Dool and Kratz RI, non-polar column, custom temperature program

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Column type Active phase I Reference Comment
CapillaryDB-51213.Zaikin and Borisov, 2002He; Column length: 30. m; Column diameter: 0.25 mm; Program: 30C => 5K/min=120C => 10C/min => 270C

Normal alkane RI, non-polar column, temperature ramp

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Column type Active phase I Reference Comment
CapillaryPetrocol DH1212.Sojak, Kubinec, et al., 2006150. m/0.25 mm/1.0 μm, 1. K/min; Tstart: 40. C; Tend: 300. C

Normal alkane RI, non-polar column, custom temperature program

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Column type Active phase I Reference Comment
CapillaryPolydimethyl siloxane1202.Junkes, Castanho, et al., 2003Program: not specified

References

Go To: Top, Mass spectrum (electron ionization), Gas Chromatography, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Heinzen, Soares, et al., 1999
Heinzen, V.E.F.; Soares, M.F.; Yunes, R.A., Semi-empirical topological method for the prediction of the chromatographic retention of cis- and trans-alkene isomers and alkanes, J. Chromatogr. A, 1999, 849, 2, 495-506, https://doi.org/10.1016/S0021-9673(99)00530-0 . [all data]

Gusev, Sokolov, et al., 1989
Gusev, G.M.; Sokolov, V.P.; Yurov, V.V.; Kuznetsov, A.V.; Potatuev, A.A., Identification of olefins during hydrocarboxylation, Zh. Anal. Khim., 1989, 44, 551-555. [all data]

Rang, Kuningas, et al., 1987
Rang, S.; Kuningas, K.; Strenze, T.; Orav, A.; Eisen, O., Retention and Thermodynamics of Solution of n-Alkenes in OV-101, J. Chromatogr., 1987, 406, 75-80, https://doi.org/10.1016/S0021-9673(00)94018-4 . [all data]

Nijs and Jacobs, 1981
Nijs, H.H.; Jacobs, P.A., On-Line Single Run Analysis of Effluents from a Fischer-Tropsch Reactor, J. Chromatogr. Sci., 1981, 19, 1, 40-45, https://doi.org/10.1093/chromsci/19.1.40 . [all data]

Sojak, Hrivnak, et al., 1973
Sojak, L.; Hrivnak, J.; Majer, P.; Janak, J., Capillary Gas Chromatography of Linear Alkenes on Squalane, Anal. Chem., 1973, 45, 2, 293-302, https://doi.org/10.1021/ac60324a039 . [all data]

Eisen, Orav, et al., 1972
Eisen, O.; Orav, A.; Rang, S., Identifizierung von Normal-Alkenen, Cyclopentenen und -Hexenen mittels Kapillar-Gas-Chromatographie. Identification des alcènes, cyclopentènes et -hexènes à l'aide de la chromatogrpahie en phase gazeuse sur colonne capillaire, Chromatographia, 1972, 5, 11, 229-239, https://doi.org/10.1007/BF02270600 . [all data]

Soják and Hrivnák, 1972
Soják, L.; Hrivnák, J., Open tubular column gas chromatography of the catalytic dehydrogenation products of n-dodecane, J. Chromatogr. Sci., 1972, 10, 11, 701-704, https://doi.org/10.1093/chromsci/10.11.701 . [all data]

Orav, Kuningas, et al., 1994
Orav, A.; Kuningas, K.; Kailas, T.; Koplimets, E.; Rang, S., Effect of adsorption on the retention values in capillary columns coated with OV-225 and PEG 20M, J. Chromatogr. A, 1994, 659, 1, 143-150, https://doi.org/10.1016/0021-9673(94)85016-X . [all data]

Rang, Orav, et al., 1988
Rang, S.A.; Orav, A.E.; Kuningas, K.R.; Meister, A.E.; Strense, T.V.; Eisen, O.G., Gas-Chromatographic Characteristics of unsaturated hydrocarbons, Academy of Sciences of Estonia SSR, Tallinn, Estonia SSR, 1988, 208. [all data]

Rang, Kuningas, et al., 1977
Rang, S.; Kuningas, K.; Orav, A.; Eisen, O., Capillary Gas Chromatography of C6-C14 n-Alkenes on Polyphenyl Ether and Polyethylene Glycol 4000, Chromatographia, 1977, 10, 2, 55-64, https://doi.org/10.1007/BF02274460 . [all data]

Orav and Eisen, 1972
Orav, A.; Eisen, O., The retention indexes for alkenes, alkynes and cyclenes on capillary columns, Izv. Akad. Nauk Est. SSR, Khim. Geol., 1972, 21, 1, 39-47. [all data]

Zaikin and Borisov, 2002
Zaikin, V.G.; Borisov, R.S., Chromatographic-mass spectrometric analysis of Fishcer-Tropsch synthesis products, J. Anal. Chem. USSR (Engl. Transl.), 2002, 57, 6, 544-551. [all data]

Sojak, Kubinec, et al., 2006
Sojak, L.; Kubinec, R.; Jurdakova, H.; Hajekova, E.; Bajus, M., GC-MS of polyethylene and polypropylene thermal cracking produxts, Petroleum Coal, 2006, 48, 1, 1-14. [all data]

Junkes, Castanho, et al., 2003
Junkes, B.S.; Castanho, R.D.M.; Amboni, C.; Yunes, R.A.; Heinzen, V.E.F., Semiempirical Topological Index: A Novel Molecular Descriptor for Quantitative Structure-Retention Relationship Studies, Internet Electronic Journal of Molecular Design, 2003, 2, 1, 33-49. [all data]


Notes

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